• 제목/요약/키워드: diffusion flux

검색결과 340건 처리시간 0.022초

Seawater-driven forward osmosis for direct treatment of municipal wastewater

  • Sun, Yan;Bai, Yang;Tian, Jiayu;Gao, Shanshan;Zhao, Zhiwei;Cui, Fuyi
    • Membrane and Water Treatment
    • /
    • 제8권5호
    • /
    • pp.449-462
    • /
    • 2017
  • Direct treatment of municipal wastewater by forward osmosis (FO) process was evaluated in terms of water flux decline, reverse salt diffusion, pollutants rejection and concentration efficiency by using synthetic seawater as the draw solution. It was found that when operating in PRO mode (active layer facing the draw solution), although the FO membrane exhibited higher osmotic water flux, more severe flux decline and reverse salt diffusion was also observed due to the more severe fouling of pollutants in the membrane support layer and accompanied fouling enhanced concentration polarization. In addition, although the water flux decline was shown to be lower for the FO mode (active layer facing the feed solution), irreversible membrane fouling was identified in both PRO and FO modes as the water flux cannot be restored to the initial value by physical flushing, highlighting the necessity of chemical cleaning in long-term operation. During the 7 cycles of filtration conducted in the experiments, the FO membrane exhibited considerably high rejection for TOC, COD, TP and $NH_4{^+}-N$ present in the wastewater. By optimizing the volume ratio of seawater draw solution/wastewater feed solution, a concentration factor of 3.1 and 3.7 was obtained for the FO and PRO modes, respectively. The results demonstrated the validity of the FO process for direct treatment of municipal wastewater by using seawater as the draw solution, while facilitating the subsequent utilization of concentrated wastewater for bioenergy production, which may have special implications for the coastline areas.

지지체 특성이 정삼투막 성능에 미치는 영향 (Effect of Support Membrane Property on Performance of Forward Osmosis Membrane)

  • 정보름;김종학;김범식;박유인;송두현;김인철
    • 멤브레인
    • /
    • 제20권3호
    • /
    • pp.235-240
    • /
    • 2010
  • 본 연구의 목적은 각기 다른 특성을 갖는 지지체에 따른 정삼투막의 성능을 비교 빛 평가하는 것이다. 계변 중합을 통하여 소수성 지지체인 폴리술폰(PSf)과 상대적으로 친수성 지지체인 폴리에테르술폰(PES)의 표변에 폴리아미드 활성층을 갖는 정삼투막을 제조하여 투과유량과 역확산을 비교하였다. PSf 정삼투막과 PES 정삼투막의 투과유량은 $4.36\;L/m^2hr$$17.8\;L/m^2hr$으로 PES를 지지체로 하는 정삼투막이 투과성능이 더 우수함을 알 수 있었으며, 이를 통해 지지체의 친수성과 정삼투 공정에서의 투과성능 간에 관련성이 존재함을 확인할 수 있었다. 또한 막의 두께가 앓아질수록 정삼투 공정에서 막의 투과유량은 증가하였다.

Percutaneous Absorption and Model Membrane Variations of Melatonin in Aqueous-based Propylene Glycol and 2-Hydroxypropyl-$\beta$-cyclodextrin Vehicles

  • Lee, Beom-Jin;Cui, Jing-Hao;Keith A. Parrott;James W.Ayres;Robert L.Sack
    • Archives of Pharmacal Research
    • /
    • 제21권5호
    • /
    • pp.503-507
    • /
    • 1998
  • Percutaneous absorption and model membrane variations of melationin (MT) in aqueous-based propylene glycol and $2-hydroxypropyl-{\beta}-cyclodextrin $vehicles were investigatted. the excised hairless mouse skin (HMS) and two synthetic ethylene vinyl acetate (EVA) and microporous polyethylene (MPE) were selected as a model membrane. the solubility of MT was determined by phase equilibrium study. the vertical $Franz{\circledR}$ type cell was used for diffusion study. The concentration of MT was determined using reverse phse HPLC system. The MT solubility was the highest in a mixture of PG and $2-HP{\beta}CD$. The percutaneous absorption of MT through excised HMS increased as the solubility increased. However, the permeability coefficient decreased and then slightly increased in mixture of PG and $2-HP{\beta}CD$. On the other hand, both flux and permeability coefficient through EVA membrane decreased as the solubility increased. No MT was detected over 12 h after starting diffusion through MPE membrane. The flux of MT was dependent on the type of membrane selected. Flux of MT was greatest in excised HMS followed by EBA and MPE membrane. Flux of MT through EVA membrane was 5-20 times lower when compared to excised HMS. Interestingly, volumes of donor phase when MPE membrane was used, significantly increased during the study period. the HMS might be applicable to expect plasma concentration of MT in human subjects based on flux and pharmacokinetic parameters as studied previously. the current studies may be applied to deliver MT transdermally using aqueous-based vehicles and to fabricate MT dosage forms.

  • PDF

브로민화수은(I)(Hg2Br2) 증착공정에서 자체확산 연구 (Study on self-diffusion transport phenomena during mercurous bromide (Hg2Br2) vapor processes)

  • 김남일;김극태
    • 한국결정성장학회지
    • /
    • 제34권2호
    • /
    • pp.48-54
    • /
    • 2024
  • 브로민화 수은(I)(Hg2Br2) 자체 확산 물리적 증착법 공정에서 자체 확산 전달현상 연구에서 얻어진 결론은 10-3g0 ≤ g ≤ 1g0 영역에서는 열 대류현상이 지배적이며, g = 10-4g0 영역에서는 대류에서 확산영역으로 전이되는 영역이며, 10-6g0 ≤ g ≤ 10-5g0 영역에서는 확산모드가 지배적이다. Hg2Br2의 총 몰플럭스는 중력가속도의 레벌(level)이 1/10 크기로 감소함에 따라 기하급수적으로 감소함을 나타내고 있다는 것이다. 10℃ ≤ ΔT ≤ 50℃의 온도차 범위에서는 온도차(ΔT)와 Hg2Br2의 총 몰플럭스에 대한 관계식은 선형적으로 직선적 비례관계성을 보여주고 있다.

InGaN/GaN 양자우물의 SA-MOVPE에서 표면확산을 고려한 박막성장 해석 (Analysis of Film Growth in InGaN/GaN Quantum Wells Selective Area Metalorganic Vapor Phase Epitaxy including Surface Diffusion)

  • 임익태;윤석범
    • 반도체디스플레이기술학회지
    • /
    • 제10권3호
    • /
    • pp.29-33
    • /
    • 2011
  • Film growth rate and composition variation are numerically analyzed during the selective area growth of InGaN on the GaN triangular stripe microfacet in this study. Both the vapor phase diffusion and the surface diffusion are considered to determine the In composition on the InGaN surface. To obtain the In composition on the surface, flux of In atoms due to the surface diffusion is added to the concentration determined from the Laplace equation which is governing the gas phase diffusion. The solution model is validated by comparing the growth rates from the analyses to the experimental results of GaN and InN films. The In composition and resulting wave length are increased when the surface diffusion is considered. The In content is also increased according to the increasing mask width. The effect of mask width to the In content and wave length is increasing in the case of a small open region.

음향 가진된 충돌 역 확산화염의 화염형상과 열전달 특성에 관한 실험적 연구 (An Experimental Study on the Flame Appearance and Heat Transfer Characteristics of Acoustically Excited Impinging Inverse Diffusion Flames)

  • 강기중;이기만
    • 한국산학기술학회논문지
    • /
    • 제11권10호
    • /
    • pp.3647-3653
    • /
    • 2010
  • 본 오디오 스피커로 음향 가진과 비가진 된 충돌 역 확산화염에서 화염의 형상과 열전달 특성에 관한 실험적 연구를 수행하였다. 가진에 의해 화염은 반응대가 넓어지고 화염 길이는 좀 더 짧아지는 경향을 보이며 충돌판의 정체점에서 열전달 성능인 열유속은 가진에 의해 향상되는 것으로 나타났다. 이러한 가진 효과는 당량비가 높은 과농한 상태 보다 상대적으로 낮은 혼합 상태에서 효과적으로 영향을 미치는 것으로 파악되는데 이는 가진에 의해 주위산화제가 연료 분류로의 유입이 향상되어 나타나는 것으로 판단된다. 이러한 현상으로 본 연구에서는 당량비가 0.8인 경우 정체점에서 총 열유속이 최대 57% 증가되는 것으로 나타났다. 따라서 본 연구를 통해 가진 연소가 충돌 분류 화염에서 열전달 성능을 향상시키는데 효과적인 방법임을 확인하게 되었다.

이산화탄소가 수소 산소부화 화염의 열전달에 미치는 영향 (The Effects of $CO_2$ on Heat Transfer from Hydrogen Oxygen-enriched Flame)

  • 이창엽;최준원;백승욱
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
    • /
    • pp.261-266
    • /
    • 2003
  • An experimental study has been conducted to evaluate the effects of $CO_{2}$ on heat transfer from hydrogen oxygen-enriched flame. Experiments were performed on flames stabilized by a co-flow swirl burner, which mounted on top of the furnace. Five composition conditions of oxidizer were chosen with replacing $N_{2}$ with $CO_{2}$. In a steady state, total and radiative heat flux rates from the flame to the wall of furnace has been measured using heat flux meters. Temperature distribution in furnace also has been checked. Increasing $CO_{2}$ ratio in the oxidizer, the dominant heat transfer mode was changed into convection from radiation. Temperature in the furnace decreased but total heat flux increased.

  • PDF

이산화탄소가 수소 산소부화 화염의 열전달에 미치는 영향 (Effects of CO2 on Heat Transfer from Oxygen-Enriched Hydrogen Flame)

  • 이창엽;최준원;백승욱
    • 대한기계학회논문집B
    • /
    • 제28권8호
    • /
    • pp.937-944
    • /
    • 2004
  • An experimental study has been conducted to evaluate the effects of $CO_2$ on heat transfer from oxygen-enriched hydrogen flame. Experiments were performed on flames stabilized by a co-flow swirl burner, which was mounted on top of the furnace. Five different oxidizer compositions were prepared by replacing $N_2$ with $CO_2$. In a steady state, the total as well as radiative heat flux from the flame to the wall of furnace have been measured using a heat flux meter. Temperature distribution in furnace also has been measured and compared. By increasing $CO_2$ proportion in the oxidizer, the convection played a more significant role rather than radiation. Overall temperature in the furnace was seen to be decreased, while the total heat flux has increased.

중성자 수송경계조건의 확산근사에 대한 연구 (A Study on Diffusion Approximations to Neutron Transport Boundary Conditions)

  • 노태완
    • 방사성폐기물학회지
    • /
    • 제16권2호
    • /
    • pp.203-209
    • /
    • 2018
  • 중성자 수송방정식으로 기술되는 중성자 거동을 중성자 확산방정식으로 계산하기 위해서는 수송경계조건에 대한 정확한 확산근사가 필요하다. 본 연구에서는 수송이론의 반사 및 진공경계조건에 대한 근사로 확산계산에서 광범위하게 사용되는 영중성자류, Marshak 및 Mark, 영중성자속, Albedo 조건 등에 대하여 수송이론의 확산근사 관점에서 유도 분석하여 각 조건의 수학적, 물리적 의미를 이해하고 서로의 상관관계를 보였다. 이러한 경계조건을 갖는 대상 문제를 서로 다른 확산경계조건을 사용하여 풀어 결과를 비교하였고 이들이 수송 경계조건을 비교적 정확히 기술함을 보였다.

An Experimental Study of the Diffusion Flame Characteristics for the Gas Fueled Torch System

  • Choi, Hyun-Kyung;Choi, Seong-Man
    • International Journal of Aeronautical and Space Sciences
    • /
    • 제7권2호
    • /
    • pp.50-55
    • /
    • 2006
  • Currently, a gas fueled diffusion flame is used for the relay torch system. It could be burned cleanly but should be stable at severe weather condition such as rain of up to 55 mm/h, winds of up to 70 km/h and also produce a highly bright yellow visible flame. This paper presents torch diffusion flame characteristics on the various wind speeds and rainfall conditions. From the results, flame lengths are controlled by the momentum flux ratio of fuel and ambient air flow and flame stability is much influenced by the mixing characteristics with air flow. Flame is fluctuated above than 200 mm/h rainfall and blow out is occurred about 300 mm/h rainfall condition.