• 제목/요약/키워드: diffusion coefficients

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Use of Monte Carlo code MCS for multigroup cross section generation for fast reactor analysis

  • Nguyen, Tung Dong Cao;Lee, Hyunsuk;Lee, Deokjung
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2788-2802
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    • 2021
  • Multigroup cross section (MG XS) generation by the UNIST in-house Monte Carlo (MC) code MCS for fast reactor analysis using nodal diffusion codes is reported. The feasibility of the approach is quantified for two sodium fast reactors (SFRs) specified in the OECD/NEA SFR benchmark: a 1000 MWth metal-fueled SFR (MET-1000) and a 3600 MWth oxide-fueled SFR (MOX-3600). The accuracy of a few-group XSs generated by MCS is verified using another MC code, Serpent 2. The neutronic steady-state whole-core problem is analyzed using MCS/RAST-K with a 24-group XS set. Various core parameters of interest (core keff, power profiles, and reactivity feedback coefficients) are obtained using both MCS/RAST-K and MCS. A code-to-code comparison indicates excellent agreement between the nodal diffusion solution and stochastic solution; the error in the core keff is less than 110 pcm, the root-mean-square error of the power profiles is within 1.0%, and the error of the reactivity feedback coefficients is within three standard deviations. Furthermore, using the super-homogenization-corrected XSs improves the prediction accuracy of the control rod worth and power profiles with all rods in. Therefore, the results demonstrate that employing the MCS MG XSs for the nodal diffusion code is feasible for high-fidelity analyses of fast reactors.

Molecular Dynamics Study of the Self-Diffusion Coefficient and Velocity Autocorrelation Function of a Polymer Molecule in Solution

  • Kang, Hong-Seok;Lee, Young-Seek;Ree, Tai-kyue
    • Bulletin of the Korean Chemical Society
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    • v.4 no.5
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    • pp.223-227
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    • 1983
  • A molecular dynamic computer experiment was performed on a system of 108 particles composed of a single polymer chain and solvent molecules. The state considered was in the immediate neighborhood of the triple point of the system. The polymer itself is an analog of a freely jointed chain. The Lennard-Jones potential was used to represent the interactions between all particles except for that between the chain elements forming a bond in the polymer chain, for which the interaction was expressed by a harmonic potential. The self-diffusion coefficient and velocity autocorrelation function (VACF) of a polymer were calculated at various chain lengths $N_p$, and various interaction strengths between solvent molecules and a polymer chain element. For self-diffusion coefficients D, the Einstein relation holds good; as chain length $N_p$ increases the D value decreases, and D also decreases as ${\varepsilon}_{cs}$ (the interaction parameter between the chain element and solvent molecules) increases. The relaxation time of velocity autocorrelation decreases as ${\varepsilon}_{cs}$ increases, and it is constant for various chain lengths. The diffusion coefficients in various conditions reveal that our systems are in a free draining limit as is well known from the behavior of low molecular weight polymers, this also agrees with the Kirkwood-Riesman theory.

Diffused Quantity Prediction Model and Diffusion Coefficient of Gel Food in the Mass Transfer Process (겔 식품의 물질전달공정 중 확산량 예측모델 및 확산계수)

  • Lee, Won-Young;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.23 no.2
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    • pp.217-223
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    • 1991
  • A capillary method was used to evaluate the properties of mass transfer process and diffusion coefficients in the gel food. Amaranth dye was selected as a diffusant material to visualize the degree of diffusion procedure easily. After contacting cylinder containing agar gel with amaramth dye solution for some hours, the gel was cut to five segments by 0.5 cm in length. The diffusant concentration from the segments were measured by the spectrophotometer at 523 nm. Prediction models for the diffused quantities in gel food were established by the regression program of SPSS package program. Generally, diffusion coefficient can be calculated by Fick's second law, however, it will be determined by using numerical analysis method more easily. Finally the diffusion coefficients in this research were calculated by arithmetic mean of the measured values. As raising gel agent concentration, the mean diffusion coefficient tended to decrease because the obstruction effect came to become significant.

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Moisture Absorption Properties of Liquid Type Epoxy Encapsulant with Nano-size Silica for Semiconductor Packaging Materials (나노크기 실리카를 사용한 반도체용 액상 에폭시 수지 성형재료의 흡습성질)

  • Kim, Whan-Gun
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.2
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    • pp.33-39
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    • 2010
  • The moisture absorption properties such as diffusion coefficient and moisture content ratio of liquid type epoxy resin systems with the filler were investigated. Bisphenol A type and Bisphenol F type epoxy resin, Kayahard MCD as hardener and 2-methylimidazole as catalyst were used in these epoxy resin systems. The nano-sized spherical type fused silica as filler were used in order to study the moisture absorption properties of these liquid type epoxy encapsulant according to the change of filler size. The temperature of glass transition (Tg) of these epoxy resin systems was measured using Dynamic Scanning Calorimeter (DSC), and the moisture absorption properties of these epoxy resin systems according to the change of time were observed at $85^{\circ}C$ and 85% relative humidity condition using a thermo-hygrostat. The diffusion coefficients in these systems were calculated in terms of modified Crank equation based on Ficks' law. An increase of Tg and diffusion coefficient with filler size in these systems can be observed, which are attributed to the increase of free volume with Tg. The change of maximum moisture absorption ratio according to the filler size and filler content cannot be observed; however, the diffusion coefficients of these systems decreased with filler content. The diffusion via free volume is dominant in the epoxy resin systems with low nano-sized filler content; however, the diffusion with the interaction of absorption according the increase of the filler surface area is dominant in the liquid type epoxy encapsulant with high nano-sized filler content.

Service life evaluation in RC structure near to sea shore through accelerated chloride diffusion test (촉진 염화물 시험결과를 이용한 비말대 콘크리트 구조물의 내구수명 평가)

  • Kim, Jeong-Su;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.5
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    • pp.30-36
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    • 2019
  • In order to evaluate service life of RC (Reinforced Concrete) structures exposed to chloride attack, chloride penetration analysis is required referred to the chloride diffusion coefficient from the actual mix proportions. In this work, accelerated diffusion coefficients are obtained from NT BUILD 492 and ASTM C 1202 and the related apparent diffusion coefficients are derived via the previously proposed relationship for RC structures near to sea shore. Considering the properties of the mix proportions and the most conservative analysis conditions like critical and surface chloride contents, service lifes in column and exterior wall member are evaluated through conventional program LIFE 365 ver.2. The different built-up period of 10 and 15 years has no significant effect on service life. The results from mix proportions with slag show longer than 75 years of service life with the help of higher time dependent parameter and lower initial diffusion coefficient.

GLOBAL ASYMPTOTIC STABILITY FOR A DIFFUSION LOTKA-VOLTERRA COMPETITION SYSTEM WITH TIME DELAYS

  • Zhang, Jia-Fang;Zhang, Ping-An
    • Bulletin of the Korean Mathematical Society
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    • v.49 no.6
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    • pp.1255-1262
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    • 2012
  • A type of delayed Lotka-Volterra competition reaction-diffusion system is considered. By constructing a new Lyapunov function, we prove that the unique positive steady-state solution is globally asymptotically stable when interspecies competition is weaker than intraspecies competition. Moreover, we show that the stability property does not depend on the diffusion coefficients and time delays.

Determination of Surface Diffusivities of Oxides by the Combined Sintering (소결에 의한 산화물촉매의 표면확산계수의 측정)

  • 문세기;유경옥;김형진
    • Journal of the Korean Ceramic Society
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    • v.14 no.2
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    • pp.73-77
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    • 1977
  • The surface diffusion coefficients for nickel, nickel oxide, cuppric oxide, cobalt oxide, alumina and ferric oxide have been determined at various temperatures using the sintering technique. This investigation is based on the model accounting for the sum of the contribution of volume and surface diffusion to the overall shrinkage rate during the initial stage of sintering. Simultaneous measurements of shrinkages and shrinkage rates of the materials compacts were conducted for various annealing times, the results of which were then correlated to the diffusion coefficient.

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EULER-MARUYAMA METHOD FOR SOME NONLINEAR STOCHASTIC PARTIAL DIFFERENTIAL EQUATIONS WITH JUMP-DIFFUSION

  • Ahmed, Hamdy M.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.18 no.1
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    • pp.43-50
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    • 2014
  • In this paper we discussed Euler-Maruyama method for stochastic differential equations with jump diffusion. We give a convergence result for Euler-Maruyama where the coefficients of the stochastic differential equation are locally Lipschitz and the pth moments of the exact and numerical solution are bounded for some p > 2.

An error- diffusion halftoning technique based on noise spectrum shaping (잡음주파수특성 성형에 의한 오차확산 영상이진화 기법)

  • 이광기;이재천;권용무;김형곤
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.32B no.11
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    • pp.1464-1472
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    • 1995
  • In this paper, we propose an error diffusion image halftoning technique based on the noise spectrum shaping. The new technique can arbitrarily control the shape of the display error spectrum whereas conventional halftoning algorithms have been known to minimize dc errors only in which case edge information cannot be properly rendered. As a method for estimating the error diffusion coefficients, a least mean square (LMS) approach is adopted.

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Effect of Blending Materials on the Durability of Concrete (I) Diffusion of Cl-ions through Hardened Cement Paste (염분환경하 콘크리트 경화체의 내구성에 미치는 혼합재의 영향 (I) 시멘트 경화체중에서의 Cl-이온의 확산)

  • 김남중;최상흘;정재동;한기성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1991.10a
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    • pp.11-14
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    • 1991
  • Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.

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