• 한국건설순환자원학회논문집
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• 제10권4호
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• pp.475-481
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• 2022

순환골재는 생산과정에서 발생하는 미세균열 및 순환골재 표면에 존재하는 시멘트 페이스트 성분의 존재로 인해, 천연골재에 비해 높은 흡수율을 가지며, 이로 인해 콘크리트에 골재로서 사용할 경우 작업성 저하, 강도의 저하 등의 문제가 발생하게 된다. 골재의 수급이 점점 어려워지고 있는 현 상황에, 골재 수급의 대안이 될 수 있는 순환골재를 적극적으로 활용하기 위한 방법으로, 본 연구에서는 Tam et al.이 제안한 2단계 배합과정을 활용하였고, 이를 이용해 제조한 콘크리트의 압축강도, 탄성계수, 및 염소이온 확산계수를 일반 배합과정을 적용한 천연골재 콘크리트 및 100 % 치환율의 순환골재 콘크리트와 비교 분석하였다. 실험 결과에 따르면, 압축강도와 탄성계수는 물시멘트비에 관계없이, 2단계 배합방법으로 제작한 순환골재 콘크리트가 일반배합과정으로 배합된 순환골재 콘크리트에 비해 높게 나타났으며, 천연골재 콘크리트에 근접하는 역학적 성능을 발휘하였다. 그러나 염소이온 확산계수의 경우 순환골재 콘크리트가 천연골재 콘크리트보다 높게 측정되었으며, 2단계 배합과정의 적용에 따른 염소이온 확산계수의 감소는 확인할 수 없어, 2단계 배합이 내구성에는 크게 기여하지 않는 것으로 판단된다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 추계 학술논문 발표대회
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• pp.148-149
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• 2016

In this paper, the increase in chloride resistance of footing concrete at coastal area was evaluated by replacement of Mineral Admixture. In KBC 2009, the footing concrete's minimum specific concrete strength at coastal area is determined to 35MPa. However, this is criteria only based on the strength aspect. Thus, it is not considered to increase the chloride resistance by replacement of Mineral Admixture. According to the test results of chloride ions penetration resistance, 35MPa class concrete with OPC 100% shown inaccessible state. Low-strength (24~30MPa class) concretes with Mineral Admixture, however, presented better performances. In addition, chloride diffusion coefficient tests showed identical appearance. Therefore, the current KBC's chloride resistance criteria based on only concrete strength has to review for the reason it can cause many problems (ex. cost increases by growing concrete strength and the environmental issues by a lot of cement use).

• Advances in concrete construction
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• 제10권1호
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• pp.13-20
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• 2020

Steel corrosion in embedded steel causes a significant durability problems and this usually propagates to structural degradation. Large-scaled concrete structures, PSC (Pre-stressed Concrete) or RC (Reinforced Concrete) structures, are usually constructed with mass concrete and require quite a long construction period. When they are located near to sea shore, chloride ion penetrates into concrete through direct or indirect exposure to marine environment, and this leads durability problems. Even if the structures are sheltered from chloride ingress outside after construction, the chloride contents which have been penetrated into concrete during the long construction period are differently evaluated from the initially mixed chloride content. In the study, chloride profiles in cores extracted from anchorage concrete block in two large-scaled suspension bridge (K and P structure) are evaluated considering the exposure periods and conditions. Total 21 cores in tendon room and chamber room were obtained, and the acid-soluble chlorides and compressive strength were evaluated for the structures containing construction period around 3 years. The test results like diffusion coefficient and surface chloride content from the construction joint and cracked area were also discussed with the considerations for maintenance.

• 한국구조물진단유지관리공학회 논문집
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• 제18권4호
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• pp.84-91
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• 2014

본 연구에서는 콘크리트 구조물의 강도 향상을 위하여 혼입하고 있는 메타카올린의 내구성능 향상 효과를 규명하기 위하여 염화물이온 확산계수 및 단열온도상승량을 측정하였다. 그 결과, 메타카올린의 혼입으로 인하여 염화물이온 확산계수가 작아짐이 확인되었으며 플라이 애쉬의 첨가를 통하여 유동성의 저하를 억제할 수 있었다. 따라서 염분침투저항성을 확보하면서 물결합재비를 크게 하는 것이 가능하므로 메타카올린의 혼입으로 발생되는 단열온도상승량을 억제할 수 있어 콘크리트의 내구성능이 향상될 수 있음을 확인하였다.

• 콘크리트학회논문집
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• 제15권2호
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• pp.345-351
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• 2003

The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

• 한국항해항만학회지
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• 제34권10호
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• pp.787-792
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• 2010

콘크리트는 물시멘트비에 상응하는 공극을 가지게 되며, 공극을 통한 염소이온의 확산을 평가하기 위하여 해안가 폭로 및 해수 침지실험이 널리 사용된다. 이상의 실험은 경우에 따라서 다년간의 시간을 요하는 경우도 있어, 최근에는 전기 영동법에 기초한 급속 염소이온 확산시험을 실시하는 경우가 많으나, 그 값이 폭로 및 침지 시험에서 얻은 값과 상이한 경우가 많아 데이터의 실용성을 높이기 위하여 그 원인 규명이 절실한 실정이다. 본 연구에서는 평가 방법으로써 Nernst-Einstein의 식을 통한 염화물 이온 이동계수의 산정방법을 사용하였으며, NT BUILD 492법 및 해수 침지실험을 통한 확산 특성과 비교하여 값의 차이에 대하여 고찰하였다. 그 결과 실험인자의 변화가 염소이온 확산에 미치는 영향은 미비한 것으로 평가되어져 실험조건에서 발생하는 영향은 거의 없는 것으로 규명되었으며, NT BUILD 492법과도 거의 동일한 값이 구해졌다. 침지실험 결과와의 상이는 염소이온 확산에서 경계조건의 차이 및 염소이온의 시멘트 수화물과의 고정화에 의한 것으로 판단되어진다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 추계 학술논문 발표대회
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• pp.149-150
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• 2018

The RC buildings which are constructed on the seaside are followed by KBC(2016) to achieve the minimization of durability damage. To control the corrosion of the reinforced steel bar by salt attack, W/C should be under 0.4 and specified concrete strength is more than 35MPa in the concrete/building construction standard specification. Ready mixed concretes which have usually include the admixtures in Busan were tested to certify the salt attack durability. In the same specified concrete strength, remarkable salt attack durability was evaluated in comparison to OPC.

• Archives of Pharmacal Research
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• 제19권6호
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• pp.435-440
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• 1996

The effect of benzalkonium chloride on skin permeability of partially modified antisense phosphorothioate oligonucleotides (PS-ODN), which are designed as scar formation inhibitor, was investigated using Franz Diffusion Cell. When the concentration ratio of PS-ODN-quarternary ammonium salt complex is more than 1:100, the apparent partition coefficient (APC) of each complex was increased in the following order; tetraphenyl phosphonium chloride (TPP) < cetyltrimethyl ammonium bromide(CTAB) < benzalkonium chloride (BZ). The permeability of PS-ODN through the rat skin increased in the presence of BZ. The fluxs of PS-ODN with BZ were increased by addition of Pluronic F 68 or Triton X-100 to phosphate buffered saline (PBS), respectively. When the mole ratio of PS-ODN to BZ is 1:10, the fluxs penetrated of PS-ODN with BZ was greatest. The increase of the permeability in the presence of BZ might be due to the formation of lipophilic ion-pair complex between PS-ODN and BZ. By regulation of mole ratio of PS-ODN to BZ, the development of topical dosage forms using PS-ODN as scar formation inhibitor will be possible with minimal systemic exposure.

• 복합신소재구조학회 논문집
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• 제6권2호
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• pp.63-69
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• 2015

It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.663-668
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• 2003

In this paper, an environmental factor and a durability resistance factor which adapts the concept of the Load Resistance Factor Design for safety design of RC structures is derived and a basic principle of a durability evaluation for RC structures using the factors is proposed. It is shown that durability of RC structures can be evaluated by comparing predicted value of chloride ion concentration with limit value of concentration for steel corrosion generation in reinforcement steel position and the durability of concrete manufactured for the RC structures can be also evaluated by comparing characteristic diffusion coefficient of concrete with predicted diffusion coefficient during mixture design.