• Metals and materials international
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• 제24권6호
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• pp.1293-1302
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• 2018

Nanocrystalline (NC) Ni electrodeposits (EDs) with a mean grain size of $34{\pm}12nm$ has been investigated, from room temperature to $800^{\circ}C$ under a purge gas of argon, by both non-isothermal and isothermal differential scanning calorimetry measurements, in combination with characterization of temperature-dependent microstructural evolution. A significant exothermic peak resulting from superimposition of recrystallization and surface oxidation occurs between 340 and $745^{\circ}C$ at a heating rate of $10^{\circ}C/min$ for the NC Ni EDs. The temperatures for recrystallization and oxidation increase with increasing the heating rate. In addition, recrystallization leads to a profound brittle-ductile transition of the Ni EDs in a narrow range around the peak temperature for the recrystallization.

• 한국기계연구소 소보
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• 통권16호
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• pp.3-16
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• 1986

The first specimens were sampled across the depth of roll products processed by rapid heating and cooling of the roll, namely, differential heat treatment. The second samples were taken from the non-heat treated roll at different depths. The samples were heat treated following the same temperature history as that at each corresponding location in the roll where the samples were taken. Consequently, both specimens showed the similar microstructure and mechanical properties (tensile, impact and fatigue strength etc.)

• 한국화재소방학회논문지
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• 제13권4호
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• pp.7-12
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• 1999

석유 화학플랜트에서 다량 부산되는 가연성 고체인 EVA(ethyl vinyl acetate) 분진의 열적특성 및 산화제와의 혼촉 위험성을 조사하였다. 시차주사열량계(DSC, Differential Scanning calorimeter) 및 열중량 분석기(TGA, Thermogavimetric Analysis)를 이용하여 온도에 따른 발열개시온도 및 중량감소를 조사하였고, EVA 분진의 위험성을 살펴보고자 몇 가지 대표적인 산화제와 혼합하여 무게비에 따른 압력용기 내에서의 혼촉 위험성을 조사하였다. DSC 분석 결과 EVA 분진의 열분해에 따른 발열 peak가 220~$250^{\circ}$ 부근에서 나타나고 있으며, TGA 분석결과 EVA 분진의 분해온도는 250~$500^{\circ}$ 범위이다. 압력 용기 시험에 의한 산화제와 EVA 분진의 혼촉 위험성은 오리피스 직경이 감소할수록 증가하며, 승온속도가 증가할수록 증가한다. 또한 승온속도가 느린 경우에는 시료의 분해온도와 산화제의 분해온도가 비슷한 경우 혼촉 위험성이 크게 나타났으며, 승온속도가 빠른 경우에는 시료 및 산화제의 분해온도보다는 분자 내에 산소의 함유량이 높은 산화제가 혼촉 위험성이 크게 나타났다.

• KIEAE Journal
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• 제14권4호
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• pp.127-131
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• 2014

The ground source heat pump (GSHP) system is a kind of the temperature differential energy system using relatively stable underground temperature as heat source of space heating and cooling. This system can achieve higher performance of system than it of conventional air source heat pump systems. However, its superiority of the system performance is different according to installation location or local climate, because the system performance depends on the underground condition which is decided by annual average air temperature. In this study, in order to estimate the feasibility of the ground source heat pump system according to the local climate, numerical simulation was conducted using the ground heat transfer model and the surface heat balance model. The case study was conducted in the condition of Seoul, Daejeon, and Busan, In the result, the heat exchange rate of Busan was 34.33 W/m as the largest in heating season and it of Seoul was 40.61 W/m as the largest in cooling.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.163-168
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• 2003

Analytical approach is applied to predict temperature of satellite box under worst hot condition from fairing jettison to separation. The box is tried to solve analytically which is exposed to known environmental heating condition and has internal heating and irradiation to space. For a single thermal mass, governing equation for temperature is simplified to 1st order ordinary differential equation(ODE) by several assumptions. Two cases are considered. The one is for constant mass box and the other is for mass-varying box. Each case has three different analytical solution by sign of constant term in ODE. One analytical solution for constant mass is applied to physical launch stage condition. It is concluded that the present analytical method can be used to quick predict the temperature of a satellite box and check whether a satellite is safe against space environment during launch stage.

• BMB Reports
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• 제39권2호
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• pp.167-170
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• 2006

Bovine adenosine deaminase undergoes a nondenaturational conformational change at $29^{\circ}C$ upon heating which is characterized by a large increase in heat capacity. We have determined the transition state thermodynamics of the conformational change using a novel application of differential scanning calorimetry (DSC) which employs very slow scan rates. DSC scans at the conventional, and arbitrary, scan rate of $1^{\circ}C/min$ show no evidence of the transition. Scan rates from 0.030 to $0.20^{\circ}C/min$ reveal the transition indicating it is under kinetic control. The transition temperature $T_t$ and the transition temperature interval ${\Delta}T$ increase with scan rate. A first order rate constant $k_1$ is calculated at each $T_t$ from $k_1\;=\;r_{scan}/{\Delta}T$, where $r_{scan}$ is the scan rate, and an Arrhenius plot is constructed. Standard transition state analysis reveals an activation free energy ${\Delta}G^{\neq}$ of 88.1 kJ/mole and suggests that the conformational change has an unfolding quality that appears to be on the direct path to the physiological-temperature conformer.

• Journal of the Korean Wood Science and Technology
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• 제34권5호
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• pp.59-66
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• 2006

The thermal properties of wood flour, Hwangto, and maleated polyethylene (MAPE) reinforced HDPE composites were investigated in this study. The thermal behavior of reinforced wood polymer composites was characterized by means of thermogravimetric (TGA) and differential scanning calorimetric (DSC) analyses. Hwangto and MAPE were used as an inorganic filler and a coupling agent, respectively. According to TGA analysis, the increase of wood flour level increased the thermal degradation of composites in the early stage, but decreased in the late stage. On the other hand, Hwangto reinforced composites showed the higher thermal stability than virgin HDPE, from the determination of differential peak temperature ($DT_p$). Decomposition temperature of wood flour and/or Hwangto reinforced composites increased with increase of heating rate. From DSC analysis, melting temperature of reinforced composites little bit increased with the addition of wood flour or Hwangto. As the loading of wood flour or Hwangto to HDPE increased, overall enthalpy decreased. It showed that wood flour and Hwangto absorbed more heat energy for melting the reinforced composites. Hwangto reinforced composites required more heat energy than wood flour reinforced composites and virgin HDPE. Coupling agent gave no significant effect on the thermal properties of composites. Thermal analyses indicate that composites with Hwangto are more thermally stable than those without Hwangto.

• Nuclear Engineering and Technology
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• 제49권8호
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• pp.1636-1644
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• 2017

The main purpose of this article is to describe the magnetohydrodynamic stagnation point flow of Walter-B nanofluid over a stretching sheet. The phenomena of heat and mass transfer are based on the involvement of thermal radiation and chemical reaction. Characteristics of Newtonian heating are given special attention. The Brownian motion and thermophoresis models are introduced in the temperature and concentration expressions. Appropriate variables are implemented for the transformation of partial differential frameworks into sets of ordinary differential equations. Plots for velocity, temperature, and nanoparticle concentration are displayed and analyzed for governing parameters. The skin friction coefficient and local Nusselt and Sherwood numbers are studied using numerical values. The temperature and heat transfer rate are enhanced within the frame of the thermal conjugate parameter.

• 한국식품영양과학회지
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• 제17권2호
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• pp.144-148
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• 1988

전분의 겔화 온도에 대한 가열속도, 수분함량 및 지방의 영향을 DSC로 측정한 결과 전분으로부터 지방이 제거됨에 따라 수분결합력이 상승함으로서 겔화 온도는 $4{\sim}5^{\circ}C$ 저하하였으며 탈지전분의 겔화 온도는 $52{\sim}67^{\circ}C$로서 옥수수, 감자, 쌀, 밀의 순으로 감소하였다. 수분함량이 증가할수록 겔화 온도는 상승하였으며 열경제적인 측면에서 전분의 겔화에 필요한 최저수분함량은 $31{\sim}41%$였다. 전분의 가열온도와 시간의 함수인 가열속도와 겔화 온도는 비례의 관계를 나타내었으며 가열속도 $15^{\circ}C/min$에서의 겔화 온도는 $5^{\circ}C/min$에 비하여 약 $2{\sim}4^{\circ}C$ 높은 값을 나타내었으며 겔화에 필요한 엔탈피도 높은 값을 나타내었다. 그러므로 가열온도와 시간의 최적화를 위하여 가열속도는 $5^{\circ}C/min$ 이하로 하는 것이 유용하리라 생각된다.

• Elastomers and Composites
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• 제19권1호
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• pp.13-31
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• 1984

The purposes of this dissertation are to demonstrate that DSC theromoanaytical methods of vulcanization can provide useful informations on the vulcanization characteristics of industrial formulations and also provides the potential basis for a rapid and complete method of sulfur and vulcanizing accelerator analysis for quality control. The influences of those factors such as heating rate, scan temperature, vucanizing accelerator's type and concentration upon vulcanization exotherm in NR and NBR compounds in the presence of vulcanizing accelerators such as TMTD,MBTS,DPG,TMTM,CBS, and MBT were evaluated by means of DSC. In order to examine the credibility in the DSC method, the same samples which were used for DSC method were studied to compare the DSC results with the ODR (Oscillating Disk Rheometer) data. The results obtained were as follows 1. In the DSC dynamic experiments, the observed enthalpy results from vulcanization depends upon the heating rate; In the range of 2 to $20^{\circ}C/min$ of heating rate, as the heating rate was increased the enthalpy change was also increased. However, over the heating rate of $30^{\circ}C/min$ it was observed that the enthalpy change was decreased as the heating rate was further increased. Without regard to the change of enthalpy, tremendous instantaneous heat evolving was observed in the range of high heating rates. 2. For the samples which are added with various vulcanizing accelerators, the activation energies of vulcanization were as follows; 3. Regarding to the influences of vulcanizining accelerator's types upon the characteristics of vulcanization exotherm, NR and NBR compounds in the presence of thiuramsulphide compounds type accelerators such as TMTD, TMTM, were exhibited sharper and higher vulclanization exotherm than others. From the resuts of DSC thermograms which was distributed in even shape in the broad temperature range, it was clearly shown that the guanidine compounds type accelerator such as DPG acts as a delayed acting accelerator. 4. In the comparison of DSC and ODR results, the dependency of temperature in the cure rate and the observed conversions show good agreements between two results. 5. In the same curatives, by the comparison of glass transition temperatures, it was possible to predict relative values of maximum torques. Consequently, from the present studies, it is shown that the DSC thermoanalytical method can provide an alternate new method for rapid and complete quality control analysis of rubber industry.