• Title/Summary/Keyword: differential detection

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Congenital Chloride Diarrhea in Dizygotic Twins

  • Seo, Kyung Ah;Lee, Na Mi;Kim, Gwang Jun;Yun, Sin Weon;Chae, Soo Ahn;Lim, In Seok;Choi, Eung Sang;Yoo, Byoung Hoon
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.16 no.3
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    • pp.195-199
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    • 2013
  • Congenital chloride diarrhea (CLD) is a rare inherited autosomal recessive disorder. Mutations of the solute carrier family 26 member 3 gene cause profuse, chloride ion rich diarrhea, which results in hypochloremia, hyponatremia and metabolic alkalosis with dehydration. If a fetal ultrasound shows bowel dilatation suggestive of bowel obstruction, or if a neonate shows persistent diarrhea and metabolic alkalosis, CLD should be considered in the differential diagnosis. The severity of CLD varies, but early detection and early therapy can prevent complications including growth failure. We report a case of dizygotic twins affected by CLD who had been born to non-consanguineous parents. Both of them showed growth failure, but one of the twins experienced worse clinical course. He showed developmental delay, along with dehydration and severe electrolyte imbalance. He was diagnosed with CLD first at 6-month age, and then the other one was also diagnosed with CLD.

In Situ Detection of the Onset of Phase Separation and Gelation in Epoxy/Anhydride/Thermoplastic Blends

  • Choe, Young-Son;Kim, Min-Young;Kim, Won-Ho
    • Macromolecular Research
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    • v.11 no.4
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    • pp.267-272
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    • 2003
  • The isothermal cure reactions of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer (poly(dimmer acid-co-alkyl polyamine)) or PEI were studied using differential scanning calorimetry (DSC). Rheological measurements have been made to investigate the viscosity and mechanical relaxation behavior of the blends. The reaction rate and the final cure conversion were decreased with increasing the amount of thermoplastics in the blends. Lower values of final cure conversions in the epoxy/thermoplastic blends indicate that thermoplastics hinder the cure reaction between the epoxy and the curing agent. Complete miscibility was observed in the uncured blends of epoxy/thermoplastics up to $120^{\circ}C$ but phase separations occurred in the early stages of the curing process at higher temperatures than $120^{\circ}C$. According to the rheological measurement results, a rise of G' and G" at the onset of phase separation is seen. A rise of G' and G" is not observed for neat epoxy system since no phase separation is seen during cure reaction. At the onset of phase separation the rheological behavior was influenced by the amount of thermoplastics in the epoxy/thermoplastic blends, and the onset of phase separation can be detected by rheological measurements.

Cathodic Stripping Voltammetric Study of Tin(Ⅱ)-Cupferron Complex (Tin(Ⅱ)-Cupferron 착물에 대한 음극벗김전압전류법적 연구)

  • Sohn, Se Chul;Seo, Moo Yul;Jee, kwang Yong;Choi, In kyu
    • Journal of the Korean Chemical Society
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    • v.39 no.1
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    • pp.23-28
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    • 1995
  • Differential-pulse cathodic stripping voltammetry was applied to the Sn(II)-cupferron complex in 0.1 M acetate buffer solution (pH 4.20). Effects of solution pH, ligand concentration, accumulation potential, and accumulation time on the reduction peak current for the adsorptive complex of Sn(II)-cupferron were investigated. Interferences by other metal cations that affected on reduction peak current were also discussed. The detection limit was 3.1${\times}$10-9 M (0.37 ppb) of Sn(II) with 60 seconds accumulation time. The relative standard deviation (n=8) for 5${\times}$10-8 M Sn(II) was 3.0%.

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Prenatal Ultrasonographic Diagnosis of Fetal Macroglossia (거대설의 산전 초음파 진단에 대한 고찰)

  • Seo, Mi Hyun;Kim, Soung Min;Myoung, Hoon;Lee, Jong Ho;Choi, Jin Young
    • Korean Journal of Cleft Lip And Palate
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    • v.15 no.2
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    • pp.83-88
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    • 2012
  • Macroglossia is a relatively uncommon condition that occurs in pediatric patients for several reasons and contributes to variety of functional problems. Most of macroglossia arises from tissue overgrowth and tongue muscle hypertrophy. There are no definite guideline in prenatal management or diagnosis in this conditions. However, macroglossia is often associated with syndrome or congenital disease, prenatal diagnosis is important in early detection. There are difficulty in measurement of tongue size, and standardization. Macroglossia can be risky in some aspects, such as airway obstruction. In this review, the author suggest prenatal ultrasonographic findings of macroglossia, investigate differential diagnosis of conditions associated with macroglossia, and management in clinical situation. Macroglossia, when present, can cause a number of functional and aesthetic problems for individuals. Treatment of this problem is challenging and controversial.

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Polarographic Determination of Iron(Ⅱ), Iron(Ⅲ) and Total Iron in the Presence of DTPA (DTPA 존재하에서 폴라로그래피법에 의한 2가 철, 3가 철 및 전체 철의 정량)

  • Se Chul Sohn;Moo yul Suh;Tae Yoon Eom
    • Journal of the Korean Chemical Society
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    • v.37 no.12
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    • pp.1053-1059
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    • 1993
  • The determination of iron(Ⅱ), iron(Ⅲ) and total iron was studied by differential-pulse and Tast polarography in 0.1 M acetate buffer solution at pH 4.60, Half wave potentials of iron(Ⅱ)-DTPA and iron(Ⅲ)-DTPA complexes were -0.150V vs. SCE reference electrode. In the presence of DTPA the redox process of iron(Ⅱ) and iron(Ⅲ) was reversible. Linear calibration plots were obtained for iron(Ⅱ) and iron(Ⅲ) concentration of 0.2∼1.0 mM. The detection limits of iron(Ⅱ) and iron(Ⅲ)by Tast polarographic method were 0.05 mM and 0.07 mM, respectively.

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Simultaneous Determination of Cd2+, Pb2+, Cu2+ and Hg2+ at a Carbon Paste Electrode Modified with Ionic Liquid-functionalized Ordered Mesoporous Silica

  • Zhang, Penghui;Dong, Sheying;Gu, Guangzhe;Huang, Tinglin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2949-2954
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    • 2010
  • Ionic liquid-functionalized ordered mesoporous silica SBA-15 modified carbon paste electrode (CISPE) was fabricated and its electrochemical performance was investigated by cyclic voltammetry, electrochemical impedance spectra. The electrochemical behavior of $Cd^{2+}$, $Pb^{2+}$, $Cu^{2+}$ and $Hg^{2+}$ at CISPE was studied by differential pulse anodic stripping voltammetry (DPASV). Compared with carbon paste electrode, the stripping peak currents had a significant increase at CISPE. Under the optimized conditions, the detection limits were $8.0{\times}10^{-8}\;M$ ($Cd^{2+}$), $4.0{\times}10^{-8}\;M$ ($Pb^{2+}$), $6.0{\times}10^{-8}\;M$ ($Cu^{2+}$), $1.0{\times}10^{-8}\;M$ ($Hg^{2+}$), respectively. Furthermore, the present method was applied to the determination of $Cd^{2+}$, $Pb^{2+}$, $Cu^{2+}$ and $Hg^{2+}$ in water samples and people hair sample.

Application of Wavelet Transform for Fault Discriminant of Generator (발전기의 고장 판별을 위한 웨이브릿 변환의 적용)

  • Park, Chul-Won
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.64 no.1
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    • pp.35-40
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    • 2015
  • Generators are the most complex and expensive single element in a power system. The generator protection relays should to minimize damage during fault states and must be designed for maximum reliability. A conventional CDR(Current Differential Relaying) technique based on DFT(Discrete Fourier Transform) filter have the disadvantages that the time information can lead to loss in the process of converting the signal from the time domain to the frequency domain. A WT(Wavelet transform) and WT analysis is known that it is possible with the local analysis of the fault and transient signal. In this paper, to overcome the defects in the DFT process, an application of WT for fault detection of generator is presented. This paper describes an selection of mother Wavelet to detect faults of generator. Using collected data from the fault simulation with ATPdraw, we analyzed the several mother Wavelet through the course of MLD(multi-level decomposition) using MATLAB software. Finally, it can be seen that the proposed technique using detail coefficient of Daubechies level 2 which can be fault discriminant of generator.

Joint Carrier and Symbol Timing Recovery Using Repetitive Preamble (반복적인 프리엠블을 이용한 반송파 및 심볼 타이밍 동시 복원)

  • 오성근;황병대
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.8B
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    • pp.1436-1444
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    • 2000
  • In this paper, we propose the joint carrier and symbol timing recovery algorithm using repetitive preamble and differential detection for burst modem. The proposed algorithm can estimate the frequency offset and the symbol timing error regardless of the amount of frequency offset, with a high accuracy, even using very short preamble and at low SNR values. The algorithms for continuous phase frequency shift keying (CPFSK) and phase shift keying (PSK) types are developed. Through computer simulations, we compare the proposed algorithm with the existing algorithms on the estimation accuracy in terms of the preamble length, and analyze those bit error rate(BER) performance.

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Performance Evaluation of Bandwidth Efficient Adaptive QAM Schemes in Flat and Frquency Selective Fading Channels (균일 및 주파수 선택적 페이딩에서 대역폭 효율의 적응 QAM 성능분석)

  • 정연호
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.10A
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    • pp.1473-1479
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    • 2000
  • This paper presents the performance evaluation of an adaptive QAM scheme under flat and frequency selective fading channels for indoor wireless communication systems. The QAM modulation is combined with differential encoding and the demodulation process is carried out noncoherently. The adaptation is performed by varying the modulation level of QAM, depending upon received signal strength. The adaptation mechanism allows a 2- or 3-bit increase or decrease at a time, if the channel condition is considered to be significantly good or bad. Simulation results show that the average number of bits per symbol (ABPS) for each symbol block transmitted over a flat fading channel is higher than 5.0 and the BER performance is better than 10^-4 for a SNR value higher than 30 dB. For frequency selective fading channels, an oversampling technique in the receiver was employed. The BER performance obtained for frequency selective fading channels is better than 10^-4 with a SNR value of 40 dB and ABPS is found to be approximately 5.5. Therefore, this scheme is very useful in that it provides both very high bandwidth efficiency and acceptable performance with moderate SNR values over flat and frequency selective fading channels. In addition, this scheme provides reduced receiver complexity by way of noncoherent detection.

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Determination of Mercury(II) Using Nafion-EDTA-Modified Glassy Carbon Electrodes (Nafion-EDTA가 수식된 유리탄소전극을 이용한 수은(II)의 측정)

  • 정근호;박찬주;박율희;이지영
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.110-114
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    • 2000
  • Determination of mercury(II) using Nafion-EDTA-modified glassy carbon electrodes is proposed. it is based on the chemical reactivity of an immobilized modifier, Nafion-EDTA. Differential pulse voltammetry is employed, and the oxidation of complexes, at +0.43V vs. Ag/AgCl, is observed. For a 5-min preconcentration period, a linear calibration curve is obtained for mercury(II) concentrations ranging from 1.0$\times$ 10$^{-8}$ to 1.0$\times$10$^{-6}$ M. Further, when an approximate amount of copper(II) is added to the test solution, We demonstrate that at a preconcentration time of 5 min the Nafion-EDTA-modified glassy carbon electrode has a dynamic range of 2 orders of magnitude(from 10$^{-10}$ to 10$^{-8}$ M) and the detection limit is as low as 0.5$\times$ 10$^{-10}$ M(0.01 ppb). This method is applied to the determination of mercury(II) in sea water(4.0$\times$10$^{-10}$ M, 0.08ppb). The result agrees satisfactorily with the value(below 0.1 ppb) measured by using ICP/MS.

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