• Title/Summary/Keyword: diene

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A Study on the AC Interfacial Breakdown Properities of the Interface between Epoxy/EPDM with the variation of spreaded oil (도포된 오일의 변화에 따른 Epoxy/EPDM 계면의 교류 절연 파괴 특성에 관한 연구)

  • Bae, Duck-Kweon;Lee, Su-Kil;Jung, Il-Hyung;Lee, Jun-Eung
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.897-899
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    • 1999
  • In this paper, the interfacial dielectric breakdown phenomenon of interface between Epoxy/EPDM (ethylene propylene diene terpolymer) was discussed, which affects stability of insulation system of power delivery devices. Specimen structure was designed by using MAGSOFT's FLUX2D based on the finite elements method. Design concepts is to reduce the effect of charge transport from electrode in the process of breakdown and to have the tangential electrical potential with the Epoxy/EPDM interface. AC interfacial breakdown phenomenon of was investigated by variation of interfacial conditions oil and temperature which are supposed to have influence on the interfacial breakdown strength. Interfacial breakdown strength was improved by spreading oil over interfacial surface. The decreasing ratio of the AC interfacial breakdown strength in non-oiled specimens was increased by the temperature rising and its of oiled specimens was not affected by temperature.

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Characteristics of Food Nutrition Component of Limpets Cellana spp. (삿갓조개류의 식품 영양성분 특성)

  • Moon, Soo-Kyung;Kim, In-Soo;Jeong, Bo-Young
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.4
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    • pp.453-457
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    • 2017
  • The proximate, fatty acid and dimethyl acetal (DMA) composition, and mineral and total amino acid content of limpets Cellana spp. were studied. Limpets contained 17.6% protein, 1.82% lipids, and 1.28% ash. The most prominent fatty acids in limpets were 20:4n-6, 20:5n-3, 18:1n-9, 16:0, 18:0, and 22:2 nonmethylene-interrupted diene (7,13). Limpets contained significant amounts of 18:0DMA (7.79%) and 20:0DMA (2.45%) derived from plasmalogen. They also contained large amounts of calcium (192.4 mg/100 g) and iron (9.4 mg/100 g), which are components of limpet teeth. The most prominent total amino acids were glutamic acid, arginine, aspartic acid, leucine, lysine, and glycine. These results suggest that limpets are a good source of n-3 and n-6 fatty acids, plasmalogen, calcium iron, and arginine.

Free Radical Scavenging and Antioxidative Activities by Ethanol Extract from Capsella bursa-pastoris (냉이(Capsella bursa-pastoris) 에탄올 추출물의 유리라디칼 소거 및 항산화 활성)

  • Hong, Jeong-Il;Na, Gyeong-Su;Yang, Han-Cheol
    • The Korean Journal of Food And Nutrition
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    • v.7 no.3
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    • pp.169-176
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    • 1994
  • Screening was performed on edible natural sources to examine superoxide radical scavenging activities by using the method of superoxide dismutase assay. Among 47 kinds of samples, the extract of Capsella bursa-pastoris showed a potent superoxide radical scavenging activity of 11.6 unit / mg solid and was selected for further studies. In order to select optimal extraction solvent system, Cappella bursa-pastoris was extracted with various solvents and the electron donating abilities and inhibitory effects on lipid peroxidation of linoleic acid were measured. Among them, the ethanol extract of Capsella bursa-pastoris possessed the highest level of activities. The ethanol extract of Cappella bursa-pastoris was found to have an inhibitory effect on autoxidation of soybean oil at 5$0^{\circ}C$ from peroxide value, conjugated diene value and refractive index. In the soybean oil containing 0.2% of ethanol extract, induction period was increased 2 times in comparison with control.

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The Estimation of the Dielectric Strength Decrease of the Solid-solid Interfaces by using the Applied Voltage to Breakdown Time Characteristics

  • Shin, Cheol-Gi;Bae, Duck-Kweon
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.278-282
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    • 2007
  • In the complex insulation system that is used in extra high voltage(EHV) devices, according to the trend for electric power equipment of high capacity and reduction of its size, macro interfaces between two different bulk materials which affect the stability of insulation system exist inevitably. In this paper, the dielectric strength decrease of the macro interfaces between epoxy and ethylene propylene diene terpolymer(EPDM) was estimated by using the applied voltage to breakdown time characteristics. Firstly, the AC short time dielectric strength of specimens was measured at room temperature. Then, the breakdown time was measured under the applied constant voltage which is 70% of short time breakdown voltage. With these processes, the life exponent n was determined by inverse power law, and the long time breakdown voltage can be evaluated. The best condition of the interface was LOS(low viscosity(350 cSt) silicone oil spread specimen). When 30 years last on the specimens, the breakdown voltage was estimated 44% of the short time breakdown voltage.

Polyacetylenic compounds from Atractylodes rhizomes

  • Kim, Jung-Hoon
    • The Korea Journal of Herbology
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    • v.31 no.5
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    • pp.25-39
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    • 2016
  • Objectives : Atractylodes rhizomes, which have been widely used to treat gastrointestinal disorders, consist of numerous chemical compounds. Polyacetylenes are the parts of characteristic compounds of importance required to understand the therapeutic properties of Atractylodes rhizomes. It is necessary to understand the physicochemical and pharmacological properties of polyacetylenes in the Atractylodes rhizomes.Methods : The literatures from 1970 to January 2016 were searched using Korean and international electronic databases. The chemical structures of polyacetylenes were drawn by structure-drawing software.Results : The reported polyacetylenes were classified by their chemical skeletons and original resources, and their physicochemical and pharmacological features were discussed. Polyacetylenes with skeletal moieties were reported, such as diene-diyne types (two double and two triple carbon-bonds), triene-diyne types (three double carbon bonds and two triple carbon bonds), and monoene-diyne types (one double carbon bonds and two double carbon bonds), with various functional groups. Atractylodin was most frequently reported from many Atractylodes species. Atractylodin-related polyacetylenes showed chemical instability in both high and freezing temperatures. Processing of the Atractylodes rhizomes by stir-frying with bran could affect the contents of polyacetylenes and their bioavailability in vivo. Several polyacetylenes showed structure-related anti-inflammatory activities and gastrointestinal activities.Conclusion : Polyacetylene compounds in Atractylodes rhizomes were based on three chemical backbones and showed diverse physicochemical and pharmacological features. The present study provides structural, physicochemical, and pharmacological information of polyacetylene from Atractylodes rhizomes. This information provides fundamental data for further research.

Service life prediction of rubber seal materials for immersion tunnel by accelerated thermal degradation tests (가속 열 노화시험을 이용한 침매터널용 고무 씰 소재의 사용수명 예측)

  • Park, Joon-Hyung;Park, Kwang-Hwa;Park, Hyeong-Geun;Kwon, Young-Il;Kim, Jong-Ho;Sung, Il-Kyung
    • Journal of Applied Reliability
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    • v.9 no.4
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    • pp.275-290
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    • 2009
  • This paper considers accelerated thermal degradation tests which are performed for rubber seal materials used for undersea tunnels constructed by immersion method. Three types of rubber seals are tested; rubber expansion seal, omega seal, and shock absorber hose. Main ingredient of rubber expansion seal is EPDM(Ethylene Propylene Diene Monomer) and that of both omega seal and shock absorber hose is SBR(Styrene Butadiene Rubber). The accelerated stress is temperature and an Arrhenius model is introduced to describe the relationship between the lifetime and the stress. From the accelerated degradation tests, dominant failure mode of the rubber seals is found to be the loss of elongation. The lifetime distribution and the service life of the rubber seals at use condition are estimated from the test results. The acceleration factor for three types of rubber seals are also investigated.

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Inhibition of Platelet Activation by Marine Sterols from Octocorals (팔방산호충류에서 분리한 해양 스테롤 화합물의 혈소판 응집 억제작용)

  • Park, Young-Hyun;Chang, Sung-Keun;Seo, Young-Wan;Shin, Jong-Heon
    • YAKHAK HOEJI
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    • v.41 no.5
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    • pp.547-553
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    • 1997
  • The purpose of this investigation was to determine the inhibition on $Na^+,\;K^+$-ATPase, cyclic AMP phosphodiesterase and platelet activation by marine sterols isolated from octocorals. Three marine polyhydroxysterols, 7${\alpha},\;8{\alpha}-epoxy-3b{\beta},\;5{\alpha},\;6{\alpha}-trihydroxycholestane (1),\;24-methyl-7{\alpha},\;8{\alpha}-epoxy-3{\beta},\;5{\alpha},\;6{\alpha}-trihydroxycholest-22-ene (2),\;and\;7{\alpha},\;8{\alpha}-epoxy-3{\beta},\;5{\alpha},\;6{\alpha}-trihydroxycholest-22-ene (3)$, were isolated from the Gorgonian Acabaria undulata. Five marine sterols(compound 4, 5, 6, 7, 8) were isolated from the soft coral Alcyonium gracillimum. Three marine polyhydroxysterols (1, 2, 3) and pregna-1. 20-diene-3-one (8) exhibit a potent inhibitory effect on rabbit platelet aggregation induced by collagen and thrombin. Those polyhydroxysterols also exhibit a potent inhibitory effect on cyclic AMP phosphodiesterase. Compound 6 with an unusual cyclic enolether exhibit a inhibitory effect on $Na^+,\;K^+$-ATPase.

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Selection Procedure for DVT and Cis - abienol in Burley Tobacco (고 DVT 및 cis-abienol 함유 버어리종 계통 선발)

  • 조천준;김대송;정석훈;최상주;조명조
    • Journal of the Korean Society of Tobacco Science
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    • v.15 no.2
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    • pp.111-114
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    • 1993
  • This study was carried out to obtain the basic information for breeding of aromatic burley tobacco, and to select the breeding lines with higher DVT (diterpenes $\alpha$-and $\beta$-4, 8, 13-duvatriene-1, 3-diols) and cis-abienol (Z-labda-12, 14-diene-8$\alpha$-ol) concentrations. The parental genotypes used to develop the Fl and Fl generations were Burley 21, Ky 17, male-sterile(MS) NC 107, TC 612, TC 613, Va 509 and Tl 1068. To estimated the modes of inheritances of DVT and cis-abienol known as the flavor and aroma compounds, the method of thin - layer chromatography (TLC) was used. It was considered that TLC procedure being relatively simple and reproducible in the selection of the breeding lines with higher DVT and cis-abienol. DVT was present in all of parents except MS NC 107, but cia-abienol presented only in Tl 1068. It was estimated from the TLC analysis of parents and Fl's that DVT and cis-abienol were each inherited by dominant gene or genes. But it was less clear to determine the presence or not of sucrose ester(SE) on the TLC plate. The eleven plants which had burley leaf color and also estimated to have DVT and cis-abienol were selected in the F2 population of three combinations.

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A Study on Finite Element Analysis and Aging Test for Automotive Grommet (자동차 그로멧의 유한요소해석 및 노화시험에 대한 연구)

  • Lee, Seong-Beom;Yeom, Sang-Hoon;Han, Chang-Yong;Woo, Chang-Su
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.201-209
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    • 2012
  • Grommet is one of the Automotive rubber components and is made from EPDM(Ethylene Propylene Diene monomer M-class) rubber and the nonlinear hyperelastic material properties of rubber are important to predict the behavior of rubber product. In this study, the stable stress-strain relations were obtained from the uni-axial tension test and the equi-biaxial tension test. Finite element analysis for grommet was carried out and heat aging test for the lifetime prediction of grommet was introduced.

Enhancement of Herboxidiene Production in Streptomyces chromofuscus ATCC 49982

  • Jha, Amit Kumar;Lamichhane, Janardan;Sohng, Jae Kyung
    • Journal of Microbiology and Biotechnology
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    • v.24 no.1
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    • pp.52-58
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    • 2014
  • Structurally, herboxidiene contains the tetrahydropyran acetic acid moiety and a side chain including a conjugated diene, and has been isolated from Streptomyces chromofuscus ATCC 49982. Its production was significantly elevated nearly 13.5-fold (0.74 g/l) in a medium supplemented with glycerol (medium No. 6A6), and was more efficacious (1.08 g/l; 19.8-fold) in fed-batch fermentation at 36 h in medium No. 6A6, from Streptomyces chromofuscus. For further enhancement, regulatory genes metK1-sp and afsR-sp from Streptomyces peucetius were overexpressed using an expression vector, pIBR25, and similarly ACCase from Streptomyces coelicolor and two genes, metK1-sp and afsR-sp, were also overexpressed using an integration vector, pSET152, under the control of the strong $ermE^*$ promoter in Streptomyces chromofuscus. Only the recombinant strains S. chromofuscus SIBR, S. chromofuscus GIBR, and S. chromofuscus AFS produced more herboxidiene than the parental strain in optimized medium No. 6A6 with an increment of 1.32-fold (0.976 g/l), 3.85-fold (2.849 g/l), and 1.7-fold(1.258 g/l) respectively.