• 제목/요약/키워드: detergents

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Morphological Analysis of Engineered PCC by Gas-Liquid Mixing Conditions (기체-액체 혼합조건에 따른 Engineered PCC의 형태학적 분석)

  • Lee, Tai-Ju;Seo, Jin-Ho;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.113-120
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    • 2011
  • Precipitated calcium carbonate(PCC), particularly calcite crystal, is extensively used as a pigment, filler or extender in various industries such as paper, paint, textile, detergents, adhesives, rubber and plastics, food, cosmetics, and biomaterials. PCC is conventionally produced through the gas-liquid carbonation process, which consists on bubbling gaseous $CO_2$ through a concentrated calcium hydroxide slurry. This study is aimed to find some factors for controlling the morphology of engineered PCC in lab-scaled mixing batch. The experimental designs were based on temperature variables, $Ca(OH)_2$ concentration, $CO_2$ flow rate, and electrical conductivity. The model of engineered PCC morphology was finally controlled by adjustment of electrical conductivity(6.0~7.0 mS/cm) and $Ca(OH)_2$ concentration(10 g/L). Orthorhombic calcite crystals were mostly created at high concentration and electrical conductivity conditions because the increased ratio of $Ca^{2+}$ and $CO{_3}^{2-}$ ions affects the growth rate of orthorhombic faces. Excess calcium spices were contributed to the growth of faces in calcium carbonate crystal, and the non-stoichiometric reaction was occurred between $Ca^{2+}$ and $CO{_3}^{2-}$ ions during carbonation process.

The chemical effects of milking machine detergents on the rubber composition of the newly-developed teat cup liners (착유기 세척제가 신개발 젖소 유두컵 라이너용 고무조성물 재질에 미치는 화학적 영향)

  • Lee, Jeong-Chi
    • Korean Journal of Veterinary Service
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    • v.41 no.2
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    • pp.125-131
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    • 2018
  • This study investigated the effects of the alkaline detergent and acid rinse used for cleaning milking machines on the rubber composition of the newly-developed teat cup liners. The samples prepared for use in the clean-in-place process were analyzed by ultraviolet spectrophotometer, ion chromatography and liquid chromatography. In the absorption spectrum of the first sample solution, the form of absorbance or absorption peak was largely different, compared to the absorption spectrum of alkaline detergent alone, but in the absorption spectra of the second and third sample solutions, the absorbance decreased, which was similar to the absorption spectrum in the pure acid detergent. In the ion chromatogram, two main peaks only, which might be shown by the pure alkaline detergent alone, were measured. In the liquid chromatograms, however, new peaks were observed in addition to the two main peaks caused by the pure alkaline detergent alone, which suggested that various molecular materials were created or eluted from the liner by the reaction with the alkaline detergent, but when washed with the acid detergent, any ion species were not produced. Therefore, we propose that an acid rinse should be applied, after cleaning the milking machine with the alkaline detergent.

The effect of Palmitoylcarnitine and Ginseng Saponin on the nutrient uptake in Escherichia coli B. (대장균에 있어서 영양물 흡수에 미치는 Palmitoylcarnitine과 인삼 Saponin의 영향)

  • Kim, Soon-Ok;Lee, Ho-Yong;Lee, Chong-Sam;Choi, Yong-Keel;Cho, Key-Seung
    • Korean Journal of Microbiology
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    • v.22 no.3
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    • pp.151-156
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    • 1984
  • When enterobacterium, Escherichia coli B was cultivated with normal media in the presence of $0.2{\sim}0.6%$ Palmitoylcarnitine and $0.05{\sim}0.2%$ Ginseng Saponin, maximum population growth of the bacteria was presented 71% and 31%, respectively. Such a result, in vitro test, was concluded from the result that both detergents stimulated $C^{14}$-glucose, $C^{14}$-alanine and $C^{14}$-phosphatidylethanolamine uptake into the membrane of cells. The pre-treatment of cells with different amounts of Palmitoylcarnitine from $0.005{\sim}0.05{\mu}$ moles represented a significant increase of uptake, 33% of $C^{14}$-glucose, 129% of $C^{14}$-alanine and 158% of phosphatidylethanolamine at the concentration of $0.05{\mu}$ moles of Palmitoylcarnitine. On the other hand, the result of $C^{-2}%$ Saponin treatment showed the maximum value of uptake, 17% of $C^{14}$-glucose and 112% of $C^{14}$-alanine. In case of $C^{14}$-phosphatidylethanolamine, the maximum uptake showed 25% of increase at the concentration of $C^{14}$% Saponin.

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The Effect of Fluorescent Whitening Agents on the Whiteness and the Shade of Fabrics in Repeated Washings (반복 세척시 형광증백제에 의한 증백효과와 색상변화)

  • 윤혜신;정혜원
    • Textile Coloration and Finishing
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    • v.12 no.3
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    • pp.192-198
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    • 2000
  • Influence of the fluorescent whitening agent(FWA)'s adsorption on the whiteness of cotton and on the color change of the dyed fabrics was investigated by repeating wash cycles. Cotton 100% and cotton60/polyester40 blended fabrics were dyed pink, blue and yellow, and cyanuric chloride diamino stilbene(CC/DAS) and distyryl bisphenyl(DSBP) were used for the FWA with laundry detergents. Fabrics were washed at $20^\circ{C}$ with Terg-o-tometer. The FWA adsorption amount was measured by the absorption intensity for the pyridine-water extracted solution. The FWA adsorption increased on the cotton fabric with the wash cycles. Though adsorption of CC/DAS continuously increased up to the 20th cycle, that of DSBP increased sharply before the 10th cycle and reached an equilibrium. The whiteness of the fabrics dried in the shade was greater than that dried under the sunlight through window glass. The color change of dyed fabrics was increased by the number of wash cycles. Pink changed more greatly than blue, yellow or grey cloth. The color change(\Delta{E)}$ of dyed fabric washed repeatedly up to the 20th cycle with the detergent without FWA was less than 1. It is recommended to wash pale colored fabric with the detergent free of FWA.

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Detergency of Triolein in Mixed Burfactant Solutions (혼합 계면활성제용액에서 Triolein의 세척성)

  • 정혜원
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.2
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    • pp.390-397
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    • 1996
  • The effects of the mixture of surfactants on the removal of triolein applied to cotton and polyester fabrics were studied. The sunactants which were usually formulated to the Iriundry detergents, such as sodium dodecyl sulfonate (LAS), sodium lauryl sulfate (AS), $\alpha$-olefin sulfonate (AOS, C=14), sodium laurethoxy sulfate (AES, EO=3) and lauryl ethoxylate (AE, EO=7) were used. Washing was done at 40'C, 60"C, 80'c and the surfactant concentration was 0.05%. Backscattered electron imaging was made to study the location of triolein in the yarns. Triolein was removed easily from polyester than cotton fabrics.01eic acid added triolein wa9 removed greater than triolein only, except in AE solutions. In AE solutions, the removal of triolein was increased as the tremperature went higher and the increasing rate of the removal of triolein only was greater than that of oleic acid added triolein. In the result, more triolein was removed from triolein only than from oleic acid added triolein at 80t When the other surfactant was added to LAS, AES was the best to cotton fabrics, AOS was to polyester fabrics. Triolein was located in the lumen and grooves of the fibers and the deeper interfiber spaces. Triolein did not make thin film arround the cotton fiber in the surface, but polyester fibers. These are the main reason why the removal of triolein was difficult from cotton fabrics.rics.

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Washing of Pigment Dyed Fabrics (시판 피그먼트 염색직물의 워싱가공에 관한 연구)

  • Lee, Hye-Ja;Yoo, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.8
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    • pp.1169-1177
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    • 2006
  • The aim of this study was to investigate the change of the weight loss, tensile strength, flex stiffness, and color-values of the pigment-dyed cotton, polyester/cotton, polyester and nylon fabrics after washing process. Pigment-dyed cotton and polyester/cotton fabrics were treated with the cellulase, of which concentrations were 0, 1, 3 and 5g/l. The time of washing process ranges from 30 to 120 minutes. Pigment-dyed polyester and nylon fabrics were treated without enzyme, of which the washing temperature were 13, 30, $55^{\circ}C$ and the washing time ranges from 30 to 120 minutes. Also, they were tested in terms of the influences of agitation speed(rpm) and additives such as softeners, enzymes, detergents. The weight loss and tensile strength of the pigment-dyed cotton and polyester/cotton fabrics were positively correlated with the concentration of cellulase and washing time. Neither polyester nor nylon fabrics exhibited any change of the weight. All fabrics showed the decline of flex stiffness and decoloration after washing process. Decoloration of cotton and polyester/cotton fabrics was due to both the influence of cellulase and the mechanical rubbing. On the other hand, that of polyester and nylon fabrics was caused by the mechanical rubbing only.

Detergency and Soil Redeposition of Wool Fabric in Eco-friendly Drycleaning Solvent(Decamethylcyclopentasiloxane) (친환경 실리콘계 드라이클리닝용제(Decamethylcyclopentasiloxane)에서 모직물의 세척성과 재오염성)

  • Kim, Chun-Hee
    • Textile Coloration and Finishing
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    • v.24 no.2
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    • pp.138-144
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    • 2012
  • Detergency and soil redeposition of wool fabric in 8 nonionic surfactants (Span 20, 40, 60, 80/Tween 20, 40, 60, 80) and 4 solvents (water, petroleum, perchloroethylene(PCE), decamethylcyclopentasiloxane($D_5$)) were studied. Detergency of wool fabric in water was very low with and without surfactants due to the low wetting and difficulty in penetration of water into the fabric. Lipophilic surfactants improved the detergency of wool fabric in petroleum solvent and PCE. The detergency of wool fabric in $D_5$ was similar to that in petroleum solvent without surfactants. When water was solubilized, Span 20 addition to petroleum solvent and PCE increased the detergency of wool fabric. The detergency for $D_5$ was improved with solubilized water, however, it was lowered when the surfactants were added to the system. Therefore, it is important to formulate appropriate detergents which have good solubility and affinity to silicone for $D_5$ charge system. Hydrophilic surfactants were effective for water and lipophilic surfactants were effective for petroleum solvent and PCE in soil redeposition prevention of wool fabric. The soil redeposition prevention effects are not found in $D_5$ with both Span 20 and Tween 20. The same tendency of results in soil redeposition of wool fabric is observed when water is solubilized.

Thermal Inactivation of Lipase from Geotrichum candidum (Geotrichum candidum Lipase의 열불활성(熱不活性)에 관(關)하여)

  • Park, K.H.
    • Applied Biological Chemistry
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    • v.20 no.1
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    • pp.101-104
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    • 1977
  • Lipase from Geotrichum candidum was heat inactivated in 0.1M phosphate buffer solution. The thermal inactivation followed first order kinetics for the range of temperatures $50^{\circ}-80^{\circ}C$ except at $50^{\circ}C$. The changes in enthalpy, entropy and Gibbs free energy at $60^{\circ}C$ were 120.4 kJ/mol, 73.0 J/mol K and 96.9 kJ/mol respectively a value of $19^{\circ}C$(Geotrichum candidum lipase) is greater than that of lipases from milk and pancreas. The effect of detergents, lecithin and linoleic acid or the thermal inactivation of lipase was found to be negligible.

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The Regulation Mechanism of Chitin Synthetases in Saccharomyces cerevisiae

  • Choi, Won-Ja
    • Proceedings of the Zoological Society Korea Conference
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    • 1995.10b
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    • pp.83-83
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    • 1995
  • The three chitin synthetases of Saccharomyces cerevisiae, Chs1, Chs2, and Chs3, participate in septum and cell wall formation of vegetative cells and in wall morphogenesis of conjugating cells and spores. Because of the differences in the nature and in the time of execution of their functions, the synthetases must be specifically and individually regulated. The nature of that regulation has been investigated by measuring changes in the levels of the three synthetases and of the messages of the three corresponding gnes, CDSI, CHS2, and CAL1/CSD2/DITl0l(referred to below as CAL1), during the budding cycles. For Chs1 and Chs3, posttranslational regulation, probably by activation of latent forms, appears to be predominant. Since Chs2, like Chs1, is found in the cell in the zymogenic form, a posttranslational activation step appears to be necessary for this synthetase also. The regulation mechanism was investigated to search the relationship of CAL1, CAL2 and CALJ which is involved in Chs3 activity us ing different assay methods other than previous one. Treatment of Chs3-containing membranes with detergents drastically reduced the enzymatic activity. Activity could, however, be restored by subsequent incubation with trypsin or other pro teases in the presence of UDPGlcNAc. Experiments wi th mutants in the three genes invoIved in Chs3 activity-CAL1, CAL2, and CALJ-showed that only CAL1 and CALJ are required for the proteaseelicited (zymogenic) activity. It is concluded that Chs3 IS a zymogen and that the CAL2 product funct ions as its activator.ivator.

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Improved Cleaning Method for Dental Instruments

  • Kim, In-Geol;Lee, Yun-Ji
    • Journal of Korean Dental Science
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    • v.3 no.2
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    • pp.26-33
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    • 2010
  • We searched at the "PubMed.gov" and "jendodon.com" sites to conduct a literature review on dental instruments that are reused in clinical settings and on infection control involving pre-disinfection or sterilization cleaning/rinsing. The keyword "dental clean" was used for the Web search. We found the present official definition of instrument cleaning performed prior to disinfection or sterilization rather limiting ("removal of foreign matter (soil, organism, etc.) from the instruments"). Thus, we proposed to expand the definition to include the removal of oils applied to protect the metallic instruments and from corrosion, stains, and rust resulting from the frequent reuse of the instruments. Clinicians are found to clean their dental instruments (a) immediately after treating their patients or (b) following their treatment but not immediately afterward. In the latter case, we recommend presoaking to be added. Ultrasonic sterilization of 5~15 minutes is found to be more effective in terms of eliminating residual matter from the instruments compared to other methods. To check on the cleaning results, we recommend visual inspection, which can be quick and practical in clinical settings. The latest products being developed and marketed on the market address the related problems. Nonetheless, research must be continued on the effects of presoak, cleaning/rinsing, disinfection, and high-temperature or heating-based sterilization on the dental instruments and on dental clinicians' practices in cleaning, disinfection, and sterilization. We advise dental clinicians to select the proper cleaning methods and detergents for their instruments to help eliminate or prevent corrosion, staining, and rusting, to reduce the maintenance costs, and to ensure user-friendly instruments/apparatuses.

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