• Title/Summary/Keyword: detailed chemistry

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Numerical Modeling for Auto-ignition and Combustion Process of Fuel Sprays in High-Pressure Environment (고압 분무 연소장에서 연료 분무의 자발화 및 연소 과정 해석)

  • Yu, Y.W.;Kang, S.M.;Kim, Y.M.
    • Journal of ILASS-Korea
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    • v.5 no.4
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    • pp.66-71
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    • 2000
  • The present study is mainly motivated to investigate the vaporization, auto-ignition and combustion processes in the high-pressure engine conditions. The high-pressure vaporization model is developed to realistically simulate the spray dynamics and vaporization characteristics in high-pressure and high-temperature environment. The interaction between chemistry and turbulence is treated by employing the Representative Interactive Flamelet (RIF) Model. The detailed chemistry of 114 elementary steps and 44 chemical species is adopted for the n-heptane/air reaction. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the multiple RIFs are introduced. Numerical results indicate that the RIF approach together with the high-pressure vaporization model successfully predicts the ignition delay time and location as well as the essential features of a spray ignition and combustion processes.

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Numerical Study on the Characteristics of Spray Combustion Processes in the DME and n-heptane Fueled Diesel-like Engine Conditions (DME 및 n-Heptane 연료의 디젤엔진 조건에서 분무연소특성 해석)

  • Yu, Yong-Wook;Suk, Jun-Ho;Lee, Sang-Kil;Kim, Yong-Mo
    • Journal of ILASS-Korea
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    • v.13 no.2
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    • pp.91-98
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    • 2008
  • In the present study, in order to understand the overall spray combustion characteristics of DME fuel as well as to identify the distinctive differences of DME combustion processes against the conventional hydrocarbon liquid fuels, the sequence of the comparative analysis have been systematically made for DME and n-heptane liquid fuels. To realistically represent the physical processes involved in the spray combustion, this studyemploys the hybrid breakup model, the stochastic droplet tracking model, collision model, high-pressure evaporation model, and transient flamelet model with detailed chemistry. Based on numerical results, the detailed discussions are made in terms of the autoignition, spray combustion processes, flame structure, and turbulence-chemistry interaction in the n-heptane and DME fueled spray combustion processes.

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Taxonomic Studies on Alternaria in Korea(1)

  • Cho, Hye-Sun;Kim, Byung-Ryun;Yu, Seung-Hun
    • Mycobiology
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    • v.29 no.1
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    • pp.27-42
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    • 2001
  • The taxonomy of the Alternaria spp. has been a subject, of controversy because of their high variability in conidial morphology and polymorphism displayed even in pure cultures. The published Korean literature on the genus Alternaria is scattered and fragmentary, and pertains to about 25 species with special emphasis on occurrence and pathogenicity, but mycological studies on this group of fungi are insufficient. This is the first series of detailed and consolidated account of Korean species of Alternaria, which includes 11 species; viz., Alternaria brassicae, A. brassicicola, A. cinerariae, A. dauci, A. dianthi, A. dianthicola, A. helianthi, A. helianthinffciens, A. iridicola, A. japonica and A. protenta. Detailed diagnostic descriptions, specific characterizations, taxonomic discussions and illustrations for each species are presented.

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Numerical Study on Flame Structure and Pollutant Formation for Syngas Turbulent Nonpremixed Swirling Flames (석탄가스 난류 선회 비예혼합 연소기의 화염구조 및 공해물질 생성의 해석)

  • Lee, Jeongwon;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.289-291
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    • 2012
  • The present study numerically investigate detailed flame structure of the Syngas diffusion flames. In order to realistically represent the turbulence-chemistry interaction and the spatial inhomogeneity of scalar dissipation rate, the Eulerian Particle Flamelet Model(EPFM) with multiple flamelets has been applied to simulate the combustion processes and NOx formation in the syngas turbulent nonpremixed flames. And level-set approach is also utilized to account for the partially premixing effect at fuel and oxidizer injector in KEPRI nonpremixed combustor. Based on numerical results, the detailed discussion has been made for the precise structure and NOx formation characteristics of the turbulent syngas nonpremixed flames.

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Numerical Modeling for Auto-Ignition and Combustion Processes of Dimethyl Ether (DME) Fuel Sprays (DME 연료의 점화 및 연소특성 해석)

  • Lee, J.W.;Ryu, L.S.;Kim, Y.M.
    • Journal of ILASS-Korea
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    • v.10 no.4
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    • pp.16-25
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    • 2005
  • The present study is mainly motivated to investigate the vaporization, auto-ignition and combustion processes in high-pressure engine conditions. In order to realistically simulate the dimethyl ether (DME) spray dynamics and vaporization characteristics in high-pressure and high-temperature environment, the high-pressure vaporization model is utilized. The interaction between chemistry and turbulence is treated by employing the Representative Interaction Flamelet(RIF) model. The detailed chemistry of 336 elementary steps and 78 chemical species is used for the DME/air reaction. Numerical results indicate that the RIF approach, together with the high-pressure vaporization model, successfully predicts the essential feature of ignition and spray combustion processes.

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The $Schl\ddot{o}gl$ Model with the Second Order Transition Under the Influence of a Singular Multiplicative Random Force

  • Kyoung-Ran Kim;Dong J. Lee;Cheol-Ju Kim;Kook Joe Shin
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.631-636
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    • 1994
  • For the Schlogl model with the second order transition under the influence of the multiplicative noise singular at the unstable steady state, the detailed discussions are presented for various kinds of stochastic phenomena, suchas the effects of parameters on stationary probability distribution, noise-induced phase transitions and escape rate.

Induction Parameter Modeling of Hydrocarbon Fuel/Oxidizer for Detonation Wave Analysis (데토네이션 파 해석을 위한 탄화수소 연료/산화제의 Induction Parameter Modeling)

  • Choi, Jeong-Yeol;Yang, Vigor
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.57-62
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    • 2003
  • A general procedure of obtaining reliable one-step kinetics model for hydrocarbon mixture from the fully detailed chemistry is described iin this study. One-step theoretical formulation of the induction parameter model IPM uses a theoretical reconstruction of the induction time database obtained from a detailed kinetics library. Non-dimensional induction time calculations is compared with that of detailed kinetics. The IPM was latter implemented to fluid dynamics code and applied for the numerical simulation of detonation wave propagation. The numerical results including the numerical smoked-foil record show the all the details of the detonation wave propagation characteristics at the cost around 1/100 of the detailed kinetics calculation.

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Raman Spectroscopic Study of Benzonitrile on Silver Surface

  • Boo, Doo-Wan;Kim, Kwan;Kim, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.8 no.4
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    • pp.251-254
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    • 1987
  • The surface-enhanced Raman scattering(SERS) of benzonitrile in a silver sol was investigated. It was concluded that the molecule adsorbed onto the silver surface via the nitrogen lone pair electrons. Using the surface selection rule, the orientation of the benzene ring with respect to the surface plane could not be determined conclusively. However, it seemed likely that benzonitrile is adsorbed edge-on to the surface. It was demonstrated that the SERS technique provides a useful method for detailed characterization of the chemisorbed layer.

Microbial Transformation of a Monoterpene, Geraniol, by the Marine-derived Fungus Hypocrea sp.

  • Leutou, Alain S.;Yang, Guohua;Nenkep, Viviane N.;Siwe, Xavier N.;Feng, Zhile;Khong, Thang T.;Choi, Hong-Dae;Kang, Jung-Sook;Son, Byeng-Wha
    • Journal of Microbiology and Biotechnology
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    • v.19 no.10
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    • pp.1150-1152
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    • 2009
  • Geraniol (1) is the biogenetic precursor of a number of monoterpenes. We tested various marine-derived microorganisms to determine their ability to biotransform 1. Only Hypocrea sp. was capable of transforming 1 into its oxidized derivative, 1,7-dihydroxy-3,7-dimethyl-(E)-oct-2-ene (2). The structure of the metabolite obtained was assigned on the basis of detailed spectroscopic data analyses.

Changes in Epistemological Beliefs in Chemistry Following Completion of Advanced Chemistry in Science High School Students

  • Dong-Seon Shin;Min Jung Jung;Jong Keun Park
    • International Journal of Advanced Culture Technology
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    • v.12 no.1
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    • pp.209-219
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    • 2024
  • We studied the effects of science high school students on the change of epistemological beliefs in chemistry and the academic achievement of chemistry by completing 'advanced chemistry'. For seven months from July 2023 to January 2024, 80 first-year students at G Science High School in Gyeongnam were surveyed and analyzed for epistemological beliefs about chemistry before and after classes in advanced chemistry. Chemistry academic achievement was classified by 'upper' and 'lower' levels based on the end-of-semester grades of 'advanced chemistry' in the second semester of the first year and analyzed with the SPSS 28 program. After completing advanced chemistry, the epistemological belief in chemistry increased in the proportion of favorable responses. After completing advanced chemistry, the proportion of favorable responses increased in detailed factors such as 'effort', 'math link', 'outcome', 'reality link', and 'concepts', while the 'visualization' factor decreased. Although completing 'advanced chemistry' positively changed students' epistemological beliefs about chemistry, visual expression showed little contribution to understanding chemical concepts. Based on the above results, we will have to focus on the design of instructors' teaching-learning, such as learner-centered inquiry experiments, creative visual expressions, etc., for successful chemistry teaching-learning.