• Journal of the Korea Institute of Building Construction
• /
• v.17 no.4
• /
• pp.313-320
• /
• 2017

Flue gas desulfurization gypsum(FDG) is produced when removing sulfur oxides from combustion gas generated by coal power plant. However, the recycling of FDG is still limited to the certain purposes. In order to expand the possible application of FDG, this study aims to utilize FDG as an activator for ground granulated blast furnace slag. FDG produced by dry- and wet-process were used for the experiments. Slag paste specimens were produced by mixing with deionized water and simulated pore solution, and the role of FDG as an activator for blast furnace slag was evaluated using hydration study by XRD analysis and compressive strength development. According to the results, dry-type FDG was found to work as an activator for blast furnace slag without the presence of soluble alkalis. However, wet-type FDG needs assistance by soluble alkalis in order to work as an activator for blast furnace slag. It was also found that the substitution of dry- and wet-type FDG into blast furnace slag can increase the 28 day compressive strength of slag paste. It is expected that efficient and economical recycling of FDG will be possible if quantitative analysis of strength enhancement according to substitution rate of both dry- and wet-type FDG.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.33 no.2
• /
• pp.54-60
• /
• 2023

In this study, microstructure and basic property analysis of DG (Desulfurization gypsum) and CCMs (Carbondioxide conversion capture materials) made by reacting CO₂ with DG were conducted to analyze applicability as a cement admixture. The main crystalline phases of DG were CaO and CaSO₄, and CCMs were CaSO₄, CaCO₃, Ca(OH)₂ and CaSO₄·H₂O. As a result of particle size analysis, the difference in average particle sizes between the two materials was about 7 ㎛. No major heavy metals were detected in the CCMs, and as a result o f TGA, the CO₂ decomposition of CCMs was more than twice as high as that of DG. Therefore, it was judged that CCMs could be used as a cement admixture through optimization of manufacturing conditions. As a results of measuring the strength behavior of DG and CCMs mixture ratios, the long-term strength of CCMs-mixed mortar was higher, and this is due to the filler effect of CaCO₃ in CCMs.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2014.11a
• /
• pp.148-149
• /
• 2014

The aim of this research is to contribute on investment of less cement mortar or concrete in normal strength range using additional hydration of BS with stimulating effect of FGD and OPC based on the previous research result of the BS and RFA using cement mortar. As a test, the composition for normal strength range of mortar was evaluated with 0, 10, and 20 % of FDA and 0, 20 % of OPC replacement.

• Analytical Science and Technology
• /
• v.13 no.2
• /
• pp.158-165
• /
• 2000

The purity of gypsum and quantitation of impurities of flue gas gypsum will not only play an important role in deciding of the optimal condition during a trial run of FGD (flue gas desulfurization), but also can be utilized in quality control of gypsum. The purity of gypsum can be determined from combined water, sulfur trioxide and calcium concentration. We found that the thermal analysis by TGA (thermogravimetric analysis) was the most accurate and convenient method to determine the purity of gypsum. This method will be done in a hour and the results were reproducible. On the other hand, the best way of the analysis of impurities in gypsum was fusion method using $LiBO_2$ as a fusion agent. We also determined the amount of $CO_2$ gas to analyze magnesium carbonate and calcium carbonate contents. The analyses of combined water by TGA, fusion method followed by ICP-AES (inductively coupled plasmaatomic emission spectroscopy) and determination of $CO_2$ amount can lead to more accurate and convenient method for gypsum analysis.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.8 no.1
• /
• pp.8-16
• /
• 2020

As the circulating fluidized bed combustor(CFBC) boilers system to generate electric power increase in order to reduce environmental pollution, a lot of CFBC fly ashes(CFFA) are produced. CFFA has limited use in concrete because it contains free CaO, which can cause cement expansion and rapid initial hydration. In this study, the microstructure and the initial development of compressive strength characteristics were experimentally analyzed to be used as a stimulant to replace natural gypsum by mixing with CFFA and phosphate gypsum to enhance the initial strength of portland blast furnace slag cement. The recycled gypsum was used as flue-gas desulfurization gypsum and phosphate gypsum. Experimental results show that the initial strength development is relatively lower when CFFA and dihydrate gypsum are mixed, but the strength improvement effect of the mixture with CFFA and anhydrous gypsum as an anhydritedII typed crystalized gypsum is similar to that of natural gypsum. As a result, it w as analyzed to have high possibility of use for stimulant of portland blast furnace slag cement.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.34 no.3
• /
• pp.86-91
• /
• 2024

In this study, the characteristics of mortar using carbondioxide conversion capture materials (CCMs), fabricated by reacting CO₂ with desulfurization gypsum (DG) by-produced from a oil refinery, as a cement mixture. Based on the chemical component and particle size analysis results, it estimated that desulfurized gypsum reacted with carbon dioxide to produce carbonate crystals such as CaCO₃. Using CCMs as a cement mixture, physical property and durability analysis were conducted by measuring such as workability, compressive strength, compressive strength ratio after freezing-thawing and accelerated carbonation depth. The experimental results showed that as the content of the admixture increased, workability and compressive strength characteristics decreased. Compressive strength after freezing-thawing and accelerated carbonation depth also showed similar characteristics to the physical property measurement results. In addition, compared to desulfurized gypsum, using CCMs showed better physical properties and durability. This was assumed to be due to differences in the crystal phases of the mixed materials such as free-CaO and CaCO₃.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.2 no.4
• /
• pp.291-296
• /
• 2014

For the purpose of energy consumption and green-house gas reduction from building, new insulation materials with improved thermal property have been developed and used. Among new insulation materials, mineral hydrate which compensates for the defects of existing materials is using as a prominent insulation material. The fabrication method of mineral hydrate is similar to that of ALC for building structure but mineral hydrate is only used for insulation. The raw materials that make up of mineral hydrate are cement, lime and anhydrite. Especially anhydrite is all dependant on imports. In this study, Desulfurization Gypsum(DG), by-product of oil plant, was used for replacing for imported anhydrite and waste recycling. DG substituted all of anhydrite and a part of lime. Mineral hydrate used DG had analogous thermal and physical properties, compared to existing mineral hydrate.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.5 no.4
• /
• pp.450-457
• /
• 2017

This study is to develop high quality floor mortar which can be applied in construction sites using EXFG(Expansive admixdure Flue Gas desulfurization gypsum). First, as the substitution rate of ALS(Aluminum Slag) increased, the flow is increased proportionally. EXFG showed a tendency to decrease with increasing substitution rate. Also, in the case of the setting time of 5% of ALS replacement rate, the setting time of Plain compared to EXFG was decreased by 5~20%. The compressive strength increased with the ALS replacement ratio at 0%, 5% and the EXFG replacement ratio at 1%. The strength was increased when the ALS replacement ratio was more than 10%. In the case of ALS replacement rate of 0% and 5%, drying shrinkage compared to plain was decreased by about 10~25% regardless of EXFG replacement rate.

• Economic and Environmental Geology
• /
• v.52 no.2
• /
• pp.119-128
• /
• 2019

About 300,000 tones of oyster shell are annually produced in Korea and, thus, a massive recycling plan is required. Many desulfurizing studies using oyster shells with chemical composition of $CaCO_3$ have been performed so far; however, most of them have focused on dry desulfurization. This study investigates the possibility of using oyster shells for wet desulfurization after calcination. For this, a simulated wet desulfurization facility of spray type was devised and compared the SOx-stripping characteristics of calcined oyster shell with those of limestone. The calcined oyster shell slurry indicate a better desulfurizability than the slurries of raw shell or limestone because the oyster shell transformed to a more reactive phase ($Ca(OH)_2$) by the calcination and hydration. Because of this reason, when the calcined oyster shell slurries were used, the reaction residue showed the higher gypsum ($CaSO_4{\cdot}2H_2O$) contents than any other cases. In the continuous desulfurization experiments, calcined oyster shell slurry showed a wider pH variation than limestone or raw oyster shell slurries, another clear indication of high reactivity of calcined oyster shells for $SO_2$ absorption. Our study also shows that the efficiency of wet desulfurization can be improved by the use of calcined oyster shells.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.5 no.4
• /
• pp.389-394
• /
• 2017

The aim of the research is providing the application method of recycled materials to manufacture the low costed eco-friend block at currently operated concrete block plant. In this research, based on the previous research results on three types of slag cement with illite, desulfurized gypsum, and wasted refractory products, the actual block product was manufactured by the currently operated plant facility and evaluated their properties to suggest the optimal proportions. As an experimental results, in aspect of compressive strength, absorption ratio, freezing resistance, and pH, type III slag incorporating 5% desulfurized gypsum with 1% replaced illite as an aggregate could be suggested as am optimal proportion. In additionally, considering the high cost of the illite, it can be considered as an optimal proportion that type III slag incorporating 5% desulfurized gypsum for binder.