• 제목/요약/키워드: desulfurization

검색결과 353건 처리시간 0.029초

Design and Operation of 3MW Pilot Plant of $Mg(OH)_2$ Flue Gas Desulfurization Process

  • Kim, In-Won;Jin, Sang-Hwa;Choi, Byung-Moon;Lee, Hyung-Keun
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.116.2-116
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    • 2001
  • Korea Institute of Energy Research(KIER) has designed the 3MW pilot scale wet FGD process based on the experimental results of the bench scale FGD system which can treat 150 m3/hr of flue gases. The effects of process chemistry, packing material, and operating variables including L/G ratio, pH, scrubber pressure drop were investigated. In cooperation with Kyunggi Chemicals, the 3MW pilot scale plant was established on the industrial site at Onsan, Korea. This system has been operating since October 1999. This paper introduces an outline of the design features of the pilot plant and discusses its operational results.

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대형 디젤기관에서 초저유황경유, 바이오디젤 및 디젤산화촉매 적용시의 배기가스 특성 (Emission Characteristics in The Application of ULSD, Biodiesel and DOC in Heavy Duty Diesel Engine)

  • 백두성;박만재
    • 대한기계학회논문집B
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    • 제28권1호
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    • pp.52-58
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    • 2004
  • To develop a low emission engine, it is necessary to obtain some better quality of automotive fuels. Sulfur in fuel is transformed to sulfate-laden PM as DOC is applied. Therefore, it necessary to provide low sulfur fuels before DOC is applied. According to the specification of test fuels, flash point, distillation 90%, cetane index are improved but viscosity is decreased in the process of desulfurization. Excessively reduced sulfur may cause to decrease lubricity of fuel and engine performance in fuel injection system. Therefore, this research was emphasized how the application of Bio-diesel affects on the emission characteristics and engine performance under the circumstance of ULSD and DOC.

Vortex에 의한 DSI공정 중 혼합효율 향상에 관한 연구 (A Numerical Study of $SO_2$ Efficiency Improvement in the DSI process of FGD)

  • 정진도;김장우
    • 한국분무공학회지
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    • 제14권1호
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    • pp.1-7
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    • 2009
  • This study carried out numerical analysis of flow field of combustion gas and sorbent to test sorbent efficiency of DSI process. To provide rapid mixing for increase utilization rate of sorbent, streamwise vorticity can be introduced into the flowing streams by other means; for example, by installing vortex generators immediately downstream of the wavy trailing edge. Computing results show that the degree of sorbent dispersion depends strongly on duct structure. Highest dispersion efficiency received when vortex generator was installed inside of duct. The results presented in this study a optimum condition for the development of practical DSI process.

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Synthesis of the 7,8-Dihydro-7-deazapurine Derivatives and Their Antibiotic Activity

  • Sung, Sun-Young;Sin, Kwan-Seog
    • Archives of Pharmacal Research
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    • 제21권2호
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    • pp.187-192
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    • 1998
  • The cis- and trans-diastereomers of the 7,8-dihydro-7-deazapurine derivatives were synthesized from the corresponding diastereomers of 4-tran5-cyano-2-methyl-3-phenyl-5-oxopyrrolidine (5), which were reduced from the 2-cis- and 2-tran5-diastereomers of 4-trans-cyano-2-hydroxymethyl-3-phenyl-5-oxopyrrolidine (2) via tosylation, iodination and following elimination respectively. The prepared cis- and ttans-diastereomers of 6-amino-2-mercapto-8-methyl-7-phenyl-7,8-dihydro-7(9H)-deazapurine (8) were transferred to the corresponding 2-methylthio-diastereomers 9 and following desulfurization with Raney-nickel leaded to the cis and trans-diastereomers of 6-amino-8-methyl-7-phenyl-7,8-dihydro-7(9H)-deazapurine (10), respectively. The synthesized 7-deazapurine derivatives were tested for their antibiotic activity by the serial two-fold dilution method.

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용선예비처리용 $Al_2O_3-SiC-C$계 내화물 개발 (Development of $Al_2O_3-SiC-C$ Refractory for Hot Metal Pretreatment)

  • 김의호;이석한;이석향;서병길;박정민;이재옥
    • 한국세라믹학회지
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    • 제23권5호
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    • pp.86-92
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    • 1986
  • As there is a growing trend to make high quality steel improving production efficiency and utilizing slag as resources the technologies of hot metal pretreatment have been progressed to meet these demands. Although mill scale $Na_2CO_3$ and CaO used as fluxes proved to be excellent agents then can severely corrode refractories such as chamotte and high alumina for torpedo or open ladle car. Thus it was considered necessary to develop new refractories which can endure suchy conditions. Desulfurization fluxes vastly used in POSCO are $CaCO_3$ and CaO Recent trials have been made by testing phenol resin bonded $Al_2O_3-SiC-C$ bricks in torpedo ladle car for hot metal pretreatment. The results showed that the life of this brick became about 1.2 times longer than that of foreign products. And the crushing strength M.O.R corrosion resistance and oxidation resistance were tested.

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자력선별법에 의한 선탄의 탈황 (COAL DESULFURIZATION BY MAGNETIC SEPARATION METHODS)

  • 전호석;이재장
    • 산업기술연구
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    • 제15권
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    • pp.175-185
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    • 1995
  • Under the new environmental regulations announced by the government, utilities will have to cut their sulfur dioxide emissions by 60% from 1991 levels by the year of 1999. Sulfur dioxide emissions can be reduced prior to combustion by physical, chemical or biological coal cleaning. The new technology of high gradient magnetic separation (HGMS) offers the potential of economic separatoins of a variety of fine, weakly magnetic minerals including inorganic sulfur and many ash-forming minerals from coals. In the present paper, magnetic separation tests have been conducted on Korean anthracite and high-sulfur Chinese coal to investigate the feasibility of these techniques for reducing sulfur content from coals. In wet magnetic separation, the studied operating parameters include particle size, pH, matrix types, feed solids content, feed rate, number of cleaning stages and etc. The results shows that for wet separation, 60~70% of total sulfur was removed from coals with over 80% combustible recovery, on the other hand, for dry separation, 47.6% of total sulfur was removed from coals with 75% recovery.

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800MW 습식배연탈황설비 홉수탑 유동특성 해석 (Flow Analysis of the Wet Flue Gas Desulfurization System for 800MW Power Plant)

  • 정석용;김중석;문길호;김성원;이호경
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 추계학술대회 논문집
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    • pp.467-468
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    • 2003
  • 국내 최초 800MW급 석탄화력발전소로서 국제환경 규제 기준치를 능가하는 최첨단 환경 설비를 모두 갖춘 최신 발전소로 건설되고 있는 한국남동발전(주) 영흥화력 1,2호기가 2004년 7월과 12월에 완공을 목표로 보일러 및 습식배연탈항설비의 공사가 진행되고 있다. 이에 당사는 본 공사의 주계약자로서 국내 최대 규모의 최첨단 발전소 건설을 위해 최선의 노력을 경주하고 있다. 영흥화력 1,2호기 습식배연탈황설비는 800MW 2호기로 구성되어 있으며 용량 및 시스템 배열 면에 있어서 기존의 설비들과는 상이하므로 시스템 성능 예측 및 평가와 그에 파생되는 설계개선을 위한 새로운 접근방법이 필요하다. (중략)

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계면활성제가 Rhodococcus erythropolis IGTS8에 의한 dibenzothiophene의 탈황에 미치는 영향 (Influence of Surfactant on Biodesulfurization of Dibenzothiophene by Rhodococcus erythropolis IGTS8)

  • 김충식;백기태;신현재;이현호;양지원
    • KSBB Journal
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    • 제14권3호
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    • pp.380-383
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    • 1999
  • 본 연구를 통하여 Rhodococcus erythropolis IGTS8은 배양증애 유기 황화합물인 dibenzothiophene을 2-hydroxybiphenyl로 탈황하며 이 과정에서 계면활성 물질을 분비함을 확인하였다. 생산된 계면활성제로 인하여 배지내의 탁도와 균체의 건조증량 사이에는 비례관계가 없음을 확인하였다. 인위적으로 Tween 80을 넣어준 결과 균체성장 속도, 즉 DBT 분해율은 증가되었으며 2%(v/v)이상의 Tween 80 농도에서는 오히려 저해 효과를 보았다.

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오일샌드를 이용한 pilot급 합성가스 제조 및 활용 시스템 개발 (Technology Development for Pilot Scale Syngas Production and Utilization System using Oil Sand)

  • 정석우;이도연;정우현;황상연;박준성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.537-540
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    • 2009
  • 오일샌드는 아스팔트와 같은 중질유를 10% 이상 함유한 모래 또는 사암으로서, 겉으로 보기에는 시커먼 흙이나 모래처럼 보이나 내부에는 모래(점토)와 같은 광물질이 70~80%, 에너지원으로 활용이 가능한 중질유 성분인 bitumen이 10~18%, 물이 3~5% 정도 혼합되어 있다. 본 연구에서는 이러한 오일샌드 활용방안 개발을 위하여 오일샌드로부터 bitumen의 추출 및 증류 특성에 대한 시험을 진행하였으며, 가스화를 통한 합성가스 제조, 합성가스 중 분진제거 및 탈황, CO/$H_2$비 제어를 위한 합성가스 전환 등의 시험을 진행하였는데, pilot급 시스템을 이용한 합성가스 제조 시험 결과 중질잔사유를 5~7 kg/h 공급하는 조건에서 CO 40~50%, $H_2$ 20~30%, $CO_2$ 10~20% 조성의 합성가스 18~22 $Nm^3$/h를 제조하였다.

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MDEA를 이용한 $H_2S$의 습식탈황 고찰 (A Study on Wet Process of $H_2S$ removal with MDEA)

  • 한근희;조아라;이종섭;민병무
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.238-241
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    • 2008
  • In this study, absorption behaviors of absorbents and additives were measured for removing of $H_2S$ and COS from syn-gas in IGCC process, such as MDEA and HMDA. The experimental variables were concentration of absorbents and reaction temperature. From these experiments, the loading ratios of $H_2S$ were decreased with increasing of concentration of absorbents and absorption temperatures. These results will be applied to basic data for designing of $H_2S$ removal process in IGCC.

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