• Title/Summary/Keyword: derivative work

Search Result 123, Processing Time 0.024 seconds

Synthesis and Characterization of Crosslinkable Hole-Injection Transport Material for Polymer Light Emitting Diodes

  • Thi, Mai Nguyen;Kim, Jin-Woo;Vu, Quang Hung;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2009.10a
    • /
    • pp.810-813
    • /
    • 2009
  • Fluorene derivatives are well-known in the polymer OLEDs due to their good charge carrying property. In this work, we synthesized a series of conjugated copolymers based fluorene derivative and phenylamine units by using Buchwald-Hartwig reaction in order to investigate their photoreactivities and use as the HIL/HTL layers of OLEDs using solution processes.

  • PDF

QUALITATIVE ANALYSIS OF ABR-FRACTIONAL VOLTERRA-FREDHOLM SYSTEM

  • Shakir M. Atshan;Ahmed A. Hamoud
    • Nonlinear Functional Analysis and Applications
    • /
    • v.29 no.1
    • /
    • pp.113-130
    • /
    • 2024
  • In this work, we explore the existence and uniqueness results for a class of boundary value issues for implicit Volterra-Fredholm nonlinear integro-differential equations (IDEs) with Atangana-Baleanu-Riemann fractional (ABR-fractional) that have non-instantaneous multi-point fractional boundary conditions. The findings are supported by Krasnoselskii's fixed point theorem, Gronwall-Bellman inequality, and the Banach contraction principle. Finally, a demonstrative example is provided to support our key findings.

Pyran and Pyridine as Building Blocks in Heterocyclic Synthesis (이중고리 합성에 블록제로서 이용된 피란과 피리딘)

  • El-Hashash, Maher.A.;El-Sawy, Abdallah.A.;Eissa, Abdelmonem.M.F.
    • Journal of the Korean Chemical Society
    • /
    • v.53 no.3
    • /
    • pp.308-324
    • /
    • 2009
  • The present work is devoted to study the interaction of $\beta$-aroylacrylic acid derivative (3) with malononitrile in (DMF) in the presence of piperidine and/or ammonium acetate, then using the formed compounds as starting materials for synthesizing fused and isolated heterocyclic systems. It has been established that the $\beta$-aroylacrylic acid (3) reacts with malononitrile in (DMF) in the presence of piperidine as a catalyst with the formation of 4H-pyran derivative (4). By changing the catalyst into ammonium acetate, pyridine derivative (5) has been obtained. Also the N-maleamic acid derivatives (19) and (27) have been synthesized via the interaction of (4) and (5) with maleic anhydride. The purpose of this step is to study the behavior of the formed maleamic acid derivatives – as analogies of $\beta$-aroylacrylic acids – towards different active methylene compounds under Michael addition reaction.

A Study on the Collaborative Authoring Tool based on Rights Information

  • Yi, Yeong-Hun;Choi, Chang-Ha;Cho, Seong-Hwan
    • Journal of the Korea Society of Computer and Information
    • /
    • v.21 no.3
    • /
    • pp.17-23
    • /
    • 2016
  • In this paper, we propose a model of the collaborative authoring tool and its implementation results. In the 'collaborative authoring and automatic distribution system,' users can create eBooks by using partial works (primary and edited sources) on the basis of copyright information registered by the primary author. The Collaborative Authoring Tool is a part of "the collaborative authoring and automatic distribution system" developed through research on "the development of key technologies of social work protection and content mashup tools" as an R&D project granted by the Korea Copyright Commission from 2013. In the collaborative authoring and automatic distribution system, authors of primary sources such as images, audio clips and video clips for eBooks can register them together with the copyright information; users can edit the primary sources to produce secondary sources and in turn register the secondary sources on the system; and users can create and distribute eBooks by using the sources registered in the system.

Inverse method to obtain reactivity in nuclear reactors with P1 point reactor kinetics model using matrix formulation

  • Suescun-Diaz, Daniel;Espinosa-Paredes, Gilberto;Escobar, Freddy Humberto
    • Nuclear Engineering and Technology
    • /
    • v.53 no.2
    • /
    • pp.414-422
    • /
    • 2021
  • The aim of this work considers a second order point reactor kinetics model based on the P1 approximation of transport theory, called in this work as P1 point reactor model. The P1 point reactor model implicitly considers the time derivative of the neutron source which has not been thus considered previously. The inverse method to calculate the reactivity in nuclear reactors -chosen because its high accuracy- Matrix Formulation. The numerical results shown that the Matrix Formulation for the reactivity estimation constitutes a method with insignificant calculation errors.

The Prediction of Solvent Mutual Diffusion Coefficient Using Vrentas-Duda's Self Diffusion Theory (Vrentas-Duda의 자기확산이론을 이용한 용매의 상호확산계수 예측)

  • 김종수;이광래;김기창
    • Membrane Journal
    • /
    • v.10 no.1
    • /
    • pp.19-29
    • /
    • 2000
  • To estimatc mutual diffusion coefficient for the analysis of mass transfer phenomena in polymer/solvent system, two models are proposed and the equations are derived. The estimates of mutual diffusion coefficients are obtained by two models suggested in this work and compared with and experimental data and Vrentas-Duda's. Vrentas-Duda's self diffusion coefficient was used for the mutual diffusion coefficient. Derivative of chemical potential on solvent was derived and used using original UNIFAC-FV and modified UNIFAC-FV. However, Vrentas-Duda's equation for mutual diffusion coefficient contains Flory-Huggins parameter x. For the derivative of chemical potential term, Vrentas-Duda assumed that parameter x was constant and independent of temperatures and concentrations The assumption is one of shortcoming in vrentas-Duda's mutual diffusion coefficient. New methods proposed in this work do not have such assumptions and simplifications. For the solvent of cyclohexane, n-pentane, and n-hexane in PIB(polyisolbutylene) and PMS-BR (poly(p-methylstyrene-co-isobutylene), new methods well correlate the experimental data at various temperatures and concentrations, and predicted the experimental data much better than Vrentas-Duda's for the PIB/toluene system. It is shown that new methods are excellent tools for correlating mutual diffusion coefficient data in polymer/solvent system over wide ranges of temperature and concentration without any assumptions or simplifications.

  • PDF

Meshless formulation for shear-locking free bending elements

  • Kanok-Nukulchai, W.;Barry, W.J.;Saran-Yasoontorn, K.
    • Structural Engineering and Mechanics
    • /
    • v.11 no.2
    • /
    • pp.123-132
    • /
    • 2001
  • An improved version of the Element-free Galerkin method (EFGM) is presented here for addressing the problem of transverse shear locking in shear-deformable beams with a high length over thickness ratio. Based upon Timoshenko's theory of thick beams, it has been recognized that shear locking will be completely eliminated if the rotation field is constructed to match the field of slope, given by the first derivative of displacement. This criterion is applied directly to the most commonly implemented version of EFGM. However in the numerical process to integrate strain energy, the second derivative of the standard Moving Least Square (MLS) shape functions must be evaluated, thus requiring at least a $C^1$ continuity of MLS shape functions instead of $C^0$ continuity in the conventional EFGM. Yet this hindrance is overcome effortlessly by only using at least a $C^1$ weight function. One-dimensional quartic spline weight function with $C^2$ continuity is therefore adopted for this purpose. Various numerical results in this work indicate that the modified version of the EFGM does not exhibit transverse shear locking, reduces stress oscillations, produces fast convergence, and provides a surprisingly high degree of accuracy even with coarse domain discretizations.

Prediction of Longitudinal and Directional Stability Derivatives for the SDM using Forced Harmonic Oscillation (강제조화운동을 이용한 SDM의 세로 및 방향 안정성 미계수 예측)

  • Lee, Hyungro;Lee, Seungsoo;Joh, Chang-Yeol
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.40 no.11
    • /
    • pp.948-956
    • /
    • 2012
  • This paper presents the computations of the longitudinal and directional stability derivatives for the SDM(Standard Dynamic Model). The static and dynamic derivatives are evaluated at once using forced harmonic oscillations in the pitch and yaw directions. For the numerical simulations, a 3-D Euler solver that uses a dual time stepping method for unsteady time accurate simulations is applied. This work investigates the variation of the derivatives in terms of the Mach number and the several motion parameters. Good agreement of the pitch and yaw stability derivatives with previously published numerical results and experimental results are observed.

Control of a pressurized light-water nuclear reactor two-point kinetics model with the performance index-oriented PSO

  • Mousakazemi, Seyed Mohammad Hossein
    • Nuclear Engineering and Technology
    • /
    • v.53 no.8
    • /
    • pp.2556-2563
    • /
    • 2021
  • Metaheuristic algorithms can work well in solving or optimizing problems, especially those that require approximation or do not have a good analytical solution. Particle swarm optimization (PSO) is one of these algorithms. The response quality of these algorithms depends on the objective function and its regulated parameters. The nonlinear nature of the pressurized light-water nuclear reactor (PWR) dynamics is a significant target for PSO. The two-point kinetics model of this type of reactor is used because of fission products properties. The proportional-integral-derivative (PID) controller is intended to control the power level of the PWR at a short-time transient. The absolute error (IAE), integral of square error (ISE), integral of time-absolute error (ITAE), and integral of time-square error (ITSE) objective functions have been used as performance indexes to tune the PID gains with PSO. The optimization results with each of them are evaluated with the number of function evaluations (NFE). All performance indexes achieve good results with differences in the rate of over/under-shoot or convergence rate of the cost function, in the desired time domain.

Prediction of the content of white clover and perennial ryegrass in fresh or dry mixtures made up from pure botanical samples, by near infrared spectroscopy

  • Blanco, Jose A.;Alomar, Daniel J.;Fuchslocher, Rita I.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
    • /
    • 2001.06a
    • /
    • pp.1266-1266
    • /
    • 2001
  • Pasture composition, an important attribute determining sward condition and value, is normally assessed by hand separation, drying and measuring weight contribution of each species in the mixture. This is a tedious, time and labour consuming procedure. NIRS has demonstrated the potential for predicting botanical composition of swards, but most of the work has been carried out on dry samples. The aim of this work was to evaluate the feasibility of developing NIR models for predicting the white clover and ryegrass content in fresh or dry mixtures artificially prepared from pure samples of both species. Mixtures from pure stands of white clover(Trifolium repens) and perennial ryegrass (Lolium perenne) were prepared with different proportions (0 to 100%) of each species (fresh weight). A total of 55 samples were made (11 mixtures,5 cuts). Spectra (400 to 2500 nm) were taken from fresh chopped (rectangular cuvettes, transport sample module) samples, in a NIR Systems 6500 scanning monochromator controlled by the software NIRS 3 (Infrasoft International), which was also utilized for calibration development. Different math treatments (derivative order, subtraction gap and smooth segment) and a scatter correction treatment of the spectra (SNV and Detrend) were tested. Equations were developed by modified partial least squares. Prediction accuracy evaluated by cross-validation, showed that percentage of clover or ryegrass, as contribution in dry weight, can be successfully percentage of clover or ryegrass, as contribution in dry weight, can be successfully predicted either on fresh or dried samples, with equations developed by different math treatments. Best equations for fresh samples were developed including a first, second, or third derivative, whereas for dry samples best equations included a second or third derivative. Standard errors of ross validation were about 6% for fresh and 3.6% for dry samples, Coefficient of determination of cross validation (1-VR) were over 0.95 times the value of SECV for fresh samples and over 8 times the value of SECV for dry samples. Scatter correction (SNV and Detrend) in general improved prediction accuracy. It is concluded more precise on dried and ground samples, it can be used with an acceptable error level and less time and labour, on fresh samples.

  • PDF