• Title/Summary/Keyword: depth of chloride ion penetration

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Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Bisphenol A and F Type Epoxy Resin with Calumite (비스페놀 A 및 F형 에폭시수지와 칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Joo-Young;Kim, Wan-Ki
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.517-524
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    • 2014
  • Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.

Strength and Durability of Polymer-Modified Mortars Using Ground Granulated Blast-Furnace Slag (고로슬래그 미분말을 혼입한 폴리머 시멘트 모르타르의 강도 및 내구성)

  • 주명기;김남길;연규석
    • Journal of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.164-170
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    • 2002
  • Effect of the polymer-binder ratio and slag content on the properties of combined wet/dry-cured polymer-modified mortars using granulated blast-furnace slag are examined. Results shows that the flexural and compressive strengths of polymer-modified mortar using the slag tend to increase with increasing slag content, and reaches a maximum at a slag content of 40 %, and is inclined to increase with increasing polymer-binder ratio. Water absorption, carbonation depth and chloride ion penetration depth tend to decrease with increasing polymer-binder ratio and slag content. Accordingly, the incorporation of slag into polymer-modified mortars at a slag content of 40% is recommended for a combined wet/dry curing regardless of the types of polymer.

A Study on Chloride Attack Resistibility of Quaternary Concrete (4성분계 콘크리트의 염해 저항성능에 관한 연구)

  • Lee, Dong-Un;Park, Hyun-Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.1188-1194
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    • 2014
  • The purpose of this study is to estimate Chloride Attack Resistibility and mechanical properties of quaternary concrete adding fly ash, blast-furnace slag, and silica fume. Compressive strength, modulus of elasticity, chloride migration coefficient, charge passed from Rapid chloride penetration test(RCPT), and immersion testing in 3% NaCl are tested. Chloride migration coefficient and charge passed of quaternary concrete measured $0.032{\times}10^{-12}m^2/sec$ and 650 coulomb at 17 weeks, which are in a permitted limit. Also in immersion test, depth of chloride penetration and maximum chloride ion of quaternary concrete measured 3.7 mm and $10.211kg/m^3$ respectively. From the results, quaternary concrete adding fly ash, blast-furnace slag, and silica fume denotes improvement of mechanical properties and chloride attack resistibility.

Evaluation of Chloride Attack Resistibility of Heavyweight Concrete Using Copper Slag and Magnetite as Aggregate (동슬래그 및 자철석을 골재로 사용한 중량 콘크리트의 회파블록 적용을 위한 염해저항성 평가)

  • Moon, Hoon;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.6
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    • pp.483-492
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    • 2017
  • Recently, the coastal area has become the popular place for infrastructure development. To provide a beautiful scenary of costal area to nearby facilities without any hinderance, and also to protect those facilities from the sea water overflow, it is necessary to develop a new type of wave dissipating block, which is a turning wave block. It is noticeable that the top of the turning wave block is flat and thus can provide spaces for various purposes. However, the unit weight of the block decreases due to the presence of pipeline that is installed for turning the direction of the waves. In order to mitigate such problem, a heavyweight concrete needs to be used to increase the resistance against tidal waves. The copper slag and magnetite were used as a source of fine and coarse aggregate, respectively. The 28 day compressive strength of concrete incorporating ordinary and heavyweight aggregate did not show significant differences. It should be noted that the chloride ion penetration resistance was evaluated using NT-BUILD 492 rather than ASTM C 1202 method because concrete incorporating magnetite as a coarse aggregate showed excessive current flow by ASTM C 1202 method. According to the results from NT Build 492 method, which uses the penetration depth of chlorine ions to obtain chloride ion diffusivity, the heavyweight concrete incorporating the copper slag and the magnetite showed the best resistance against the chloride ion penetration. Therefore, it is reasonable to say that heavyweight concrete made with copper slag and magnetite can be used for production of turning wave block.

An Experimental Study on the Engineering Characteristics of Ternary Lightweight aggregate Mortar Using Recycling Water (회수수를 사용한 3성분계 경량 골재 모르타르의 공학적 특성에 관한 실험적 연구)

  • Lee, Jae-In;Bae, Sung-Ho;Kim, Ji-Hwan;Choi, Se-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.48-55
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    • 2022
  • This study uses the recovered water as mixing water and artificial lightweight aggregate pre-wetting water as part of a study to increase the recycling rate and reduce greenhouse gas of the ready-mixed concrete recovered during the concrete transport process, and cement fine powder of blast furnace slag(BFS) and fly ash(FA). The engineering characteristics of the three-component lightweight aggregate mortar used as a substitute were reviewed. For this purpose, the flow, dry unit mass, compressive strength, drying shrinkage, neutralization depth, and chloride ion penetration resistance of the three-component lightweight aggregate mortar were measured. When used together with the formulation, when 15 % of BFS and 5 % of FA were used, it was found to be positive in improving the compressive strength and durability of the mortar.

Durability of High-fluidity Polymer-Modified Mortar Using Redispersible Polymer Powder (재유화형 분말수지 혼입 고유동 폴리머 시멘트 모르타르의 내구성)

  • Joo Myung-Ki;Lee Youn-Su;Youn Do-Yong;Jung In-Su
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.703-708
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    • 2005
  • The effects of polymer-cement ratio and antifoamer content on the setting time and durability of high-fluidity polymer-modified mortars using redispersible polymer powder are examined. As the result, the setting time of the polymer-modified mortars using redispersible polymer powder tends to be delayed with increasing polymer-cement ratio, regardless of the antifoamer content. The water absorption, chloride ion penetration depth and carbonation depth of the high-fluidity polymer-modified mortars using redispersible polymer powder decrease with increasing polymer-cement ratio and antifoamer content. The resistance of freezing and thawing and chemicals improvement is attributed to the improved bond between cement hydrates and aggregates because of the incorporation of redispersible polymer powder

A Study on the Determination of Construction Depth of Vertical Drain by Cone Resistance (콘 관입저항치를 이용한 수직배수재 타설심도 결정에 관한 연구)

  • Jang, Seo-Yong;Kim, Jong-Ryeol;Shin, Yun-Sup;Ma, Bong-Duk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.163-170
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    • 2006
  • Recently, piezocone penetration test is frequently used in order to estimate the characteristics of soft ground with standard penetration test, generally used in the past. In this study, the correlation of standard penetration test, piezocone penetration test and driving resistance of vertical drain is analyzed in order to increase the confidence for determination of soft ground depth. As the results of each zone, the relation between standard penetration test and piezocone penetration test shows qc=(1.09~1.63)N at the soft ground, determined by 5/30 N value which is decided for soft ground criteria. And qc=(1.21~1.98)N was shown at the point of compressible layer, evaluated by the preconsolidation pressure. And driving resistance of vertical drain is $65{\sim}70kgf/cm^2$ which is equal to $10kgf/cm^2$ of cone penetration resistance.

Properties of Epoxy-Modified Mortars with Alkali Activators and Ground Granulated Blast Furnace Slag (알칼리자극제 및 고로슬래그미분말을 병용한 에폭시수지 혼입 폴리머 시멘트 모르타르의 성질)

  • Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.85-92
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    • 2021
  • The purpose of this study is to investigate the properties of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS) and alkali activators. The hardener-free EMMs with a GGBFS content of 20% using 4 types of alkali activators were prepared with various polymer-binder ratios, and tested for strengths, water absorption, carbonation depth, chloride ion and H2SO4 penetration depth. The conclusions obtained from the test results are summarized as follows: The compressive strength of the EMMs with a GGBFS content of 20% attains a maximum at a polymer-binder ratio of 10%. The flexural strength of the hardener-free EMMs using Ca(OH)2 as a alkali activator is improved with increasing polymer-binder ratios. However, the flexural strength of the EMMs using NaCO3, Na2SO4 and Li2CO3 is gradually decreased with increasing polymer-binder ratios. Regardless of the type of alkali activator, the water absorption, chloride ion penetration and carbonation depth are remarkably decreased with increasing polymer-binder ratios due to the epoxy film formed in the EMMs. The H2SO4 penetration depth of the hardener-free EMMs with a GGBFS content of 20% is gradually increased with increasing polymer-binder ratio. In this study, the properties of hardener-free EMMs using Ca(OH)2 as a alkali activator are more excellent than those of other alkali activators.

Chloride Penetration Analysis of Fly Ash Concrete using Potentiometric Titration and XRF (플라이애시를 혼입한 콘크리트의 전위차 적정법과 XRF를 이용한 염화물 침투 분석 )

  • Eun-A Seo;Ji-Hyun Kim;Ho-Jae Lee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.5
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    • pp.16-22
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    • 2023
  • In this study, a salt water immersion test was performed on concrete specimens simulating the concrete mix design of the nuclear power plant, and the correlation between the amount of chloride and the XRF component according to the depth of the concrete was analyzed. The amount of chloride on the surface of the nuclear power plant concrete increased slightly with increasing immersion time in salt water, but the amount of chloride in the depth of 5.5 mm or more showed a clear tendency to increase with increasing immersion time in salt water. As a result of analyzing the correlation between the amount of chloride in concrete and the XRF component, the concrete with 20% FA substitution compared with the OPC concrete showed a very high correlation between the composition ratio of Cl ions and the evaluation result of salt damage resistance by XRF component analysis. Accordingly, it was confirmed that chlorine ion analysis and salt damage resistance performance evaluation by XRF component analysis were possible through repeated data accumulation in the nuclear power plant concrete mix with 20% fly ash replacement.

Performance Evaluation of Repair Material and Method for Reinforced Concrete Structure by Long Term Exposure Experiment (장기폭로실험에 의한 철근콘크리트 구조물의 보수재료.공법 성능평가)

  • Kim, Moo-Han;Kim, Gyu-Yong;Cho, Bong-Suk;Kim, Young-Duck;Kim, Young-Sun
    • Journal of the Korea Concrete Institute
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    • v.19 no.1
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    • pp.39-46
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    • 2007
  • In this study, for the establishment of the performance evaluation methods and the quality control standards of durability recovery method, the quantitative exposure data by long term exposure test under the coast and normal atmosphere is accumulated and analyzed. Investigating and evaluating the result of exposure test during 30 months of exposure age under the coastal and normal atmosphere environment, carbonation depth and chloride-ion penetration depth very little penetrated than cover depth. It seems reasonable to conclude that main cause of Corrosion of reinforcing bar are chloride-ion and macro cell from the result of corrosion area and corrosion velocity. Therefore, it is considered to be applied as the fundamental data on the performance evaluation and quality control standards of repair material and method through continuous exposure test in the future.