• Title/Summary/Keyword: deposit of spray solution

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Measurement of Spray Deposit Amount Using Spectrophotometer and Food Dye as Tracer

  • Rhee, J.Y.;Ahn, S.Y.
    • Agricultural and Biosystems Engineering
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    • v.1 no.1
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    • pp.16-21
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    • 2000
  • Measurement of spray deposit is necessary for evaluation of a chemical application technology. However it is not easy and time consuming. A simple method for measuring the deposition amount of spray using a tracer and a spectrophotometer was developed. Various materials were tested to determine an adequate tracer. Food dye was selected as a tracer, because it was cheep and easily treatable. Using NIRS(Near Infrared Reflection Spectrophotometer), a regression curves between maximum absorbance of a solution and concentration of the tracer were obtained. Yellow food dye solution showed a peak of spectrum at 452 nm, and absorbance of peak showed a tendency to increase as concentration increased. Green or pink food dye were tested and judged to be good tracers. However, tracer concentration should not exceed certain limits in order to measure maximum absorption. Using spraying liquid with known tracer concentration and known amount of washing liquid, spray deposit amount on real targets on leaves could be estimated at less than 13% error level.

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The Deposition of $SnO_2$ Films by Spray Pyrolysis (분무열분해법에 의한 $SnO_2$ 박막의 증착)

  • Kim, Tae-Heui
    • Solar Energy
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    • v.15 no.2
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    • pp.91-99
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    • 1995
  • The influence of deposition parameters on the deposition of $SnO_2$ thin films by spray pyrolysis has been studied. In the case of spray solution with tile concentration of 0.01M, at low deposition temperature the deposition was controlled by surface reaction and portion controlled by mass transfer is increased with increasing deposition temperature to $400^{\circ}C$. Above $400^{\circ}C$, the deposition is controlled by mass transfer at low spray pressure, and by surface reaction at high spray pressure. As the concentration of spray solution increased the deposition rate increased, and in this experiment the deposition depends on the Rideal-Eley mechanism. The deposition rate increased with increasing substrate temperature up to $400^{\circ}C$ and then decreased due to homogeneous nucleation. The thickness of the deposit increased with increasing spray duration, and the adhesion between substrate and deposit was formed physically.

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Comparision of the Residue Property of Insecticide Bifenthrin and Chlorfenapyr in Green Onion and Scallion under Greenhouse Condition (시설재배 쪽파와 부추에서 살충제 Bifenthrin과 Chlorfenapyr의 잔류특성 비교)

  • Park, Jong-Woo;Son, Kyeong-Ae;Kim, Tae-Hwa;Chae, Seok;Sim, Jae-Ryoung;Bae, Byung-Jin;Lee, Hae-Kuen;Im, Geon-Jae;Kim, Jin-Bae;Kim, Jang-Eok
    • The Korean Journal of Pesticide Science
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    • v.16 no.4
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    • pp.294-301
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    • 2012
  • In order to use in the classification of minor crop for the mutual application of safe use guideline, it was compared a green onion with a scallion on the residue property of insecticide bifenthrin and chlorfenapyr. After pesticides were applied 2 times with 1 week interval in that day of harvest, 3 days, 7 days, 10 days and 14 days before harvest, vegetables were harvested, and the residue of pesticides was investigated. Base on the residue in that day of harvest, the deposit of spray solution in vegetables was calculated. The deposit of spray solution of bifenthrin was 123.0 mL/kg in a green onion, and 74 mL/kg in a scallion. In case of chlorfenapyr, it was calculated 126.5 mL/kg in a green onion, and 70.0 mL/kg in a scallion. When the amount of the deposit of both pesticides was compared a green onion with a scallion, it was higher in a green onion. On the other hand, it was estimated the predicted dissipation curve of pesticides in a green onion and a scallion during cultivation. The dissipation curve of bifenthrin was y = 1.0334 $e^{-0.0602x}$ ($R^2$= 0.8606) in a green onion, and y = 0.7693 $e^{-0.1823x}$ ($R^2$= 0.9756) in a scallion. In case of chlorfenapyr, it was y = 2.2603 $e^{-0.0519x}$ ($R^2$= 0.9043) in a green onion, and y = 1.2940 $e^{-0.1051x}$ ($R^2$ = 0.9782) in a scallion. The half-life of bifenthrin was 11.51 days in a green onion, and 3.80 days in a scallion, respectively. Also, it was estimated half-life in chlorfenapyr, it was 13.35 days in a green onion, and 6.59 days in a scallion, respectively. The half-life of both pesticides in a green onion was longer than in a scallion. When both vegetables were compared with the residue property, the deposit of spray solution and half-life of dissipation in a green onion were more than those in a scallion.

The Residue Property of Fungicide Dimethomorph and Pyraclostrobin in Green Onion under Greenhouse Condition (시설재배 쪽파에서 살균제 Dimethomorph와 Pyraclostrobin의 잔류특성)

  • Park, Jong-Woo;Kim, Tae-Hwa;Chae, Seok;Sim, Jae-Ryoung;Bae, Byung-Jin;Lee, Hae-Kuen;Son, Kyeong-Ae;Im, Geon-Jae;Kim, Jin-Bae;Kim, Jang-Eok
    • The Korean Journal of Pesticide Science
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    • v.16 no.4
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    • pp.328-335
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    • 2012
  • In order to use in the classification of minor crop for the mutual application of safe use guideline, it was investigated the residue property of fungicide dimethomorph and pyraclostrobin in green onion, a stem-crop. After pesticides were applied 2 times with 1 week interval in that day of harvest, 3 days, 7 days, 10 days and 14 days before harvest, a green onion was harvested. The residue of dimethomorph in a green onion was 26.31 and 39.08 mg/kg in that day of harvest, however, in according to elapse time, it was reduced to 6.86 and 9.34 mg/kg in 14 days before harvest. In case of pyraclostrobin, it was also reduced from 13.46 and 39.08 mg/kg to 3.57 and 5.21 mg/kg. Based on the residue in that day of harvest, the deposit of spray solution in a green onion was calculated. The deposit of spray solution of dimethomorph was 274.35~345.84 mL/kg, in case of pyraclostrobin, it was calculated 213.65~343.33 mL/kg. When the amount of the deposit of both pesticides was compared in a green onion, it was so similar. On the other hand, it was estimated the predicted dissipation curve of pesticides in the green onion during cultivation. The half-life of dimethomorph was 6.95~7.45 days, in case of pyraclostrobin, 7.15~7.45 days. When both pesticides were compared with the residue property, the deposit of spray solution and half-life of dissipation were so similar.

The residue property of fungicide boscalid and fluidioxonil at the same time harvest leafy-vegetables (일시수확 엽채류에서 살균제 Boscalid와 Fludioxonil의 잔류특성)

  • Bae, Byung-Jin;Lee, Hae-Kuen;Son, Kyeong-Ae;Im, Geon-Jae;Kim, Jin-Bae;Kim, Tae-Hwa;Chae, Seok;Park, Jong-Woo
    • The Korean Journal of Pesticide Science
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    • v.16 no.2
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    • pp.98-108
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    • 2012
  • In order to use in the classification of minor crop for the mutual application of safe use guideline, it was investigated the residue property of fungicide boscalid and fludioxonil at the same time harvest leafy-vegetables, such as spinach, ulgaribaechu, vitaminchae and cheongkyungchae. After pesticides were applied 2 times with 1 week interval in that day of harvest, 2 days, 5 days and 7 days before harvest, vegetables were harvested, and the residue of pesticides was investigated. Base on the residue in that day of harvest, the deposit of spray solution in vegetables was calculated. The deposit of spray solution of boscalid was 253.9 mL/kg in spinach, 83.0 mL/kg in ulgaribaechu, 97.8 mL/kg in vitaminchae, and 88.3 mL/kg in cheongkyungchae, respectively. In case of fludioxonil, it was calculated 157.6 mL/kg in spinach, 67.6 mL/kg in ulgaribaechu, 64.8 mL/kg in vitaminchae, and 66.6 mL/kg in cheongkyungchae, respectively. When the amount of the deposit of both pesticides was compared in leafy-vegetables, it was the highest in the spinach. On the other hand, it was estimated the predicted dissipation curve of pesticides in leafy-vegetables during cultivation. The half-life of boscalid was 5.9 days in spinach, 7.4 days in ulgaribaechu, 4.6 days in vitaminchae, and 4.3 days in cheongkyungchae, respectively. Also, it was estimated half-life in fludioxonil, it was 3.0 days in spinach, 4.0 days in ulgaribaechu, 3.2 days in vitaminchae, and 3.5 days in cheongkyungchae, respectively. The half-life was the longest in the ulgaribaechu. When both pesticides were compared with the residue property, the deposit of spray solution and half-life of dissipation of boscalid were more than those of fludioxonil.

A Reliability Test for Pb-Free Plating Solution and its Deposit (Pb-Free 도금용액 및 피막의 신뢰성평가)

  • Hur, Jin-Young;Koo, Suck bone;Lee, Hong-Kee
    • Clean Technology
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    • v.11 no.3
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    • pp.153-164
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    • 2005
  • This study found a reliable evaluation for four kinds of pb-Free plating solutions and it's layers, through pure Sn, SnAg, SnBi and SnCu. These four kind of solutions are widely used to pb-Free plating. Hull-cell, Harring-blum, coverage, throwing power, current efficiency, stability, life-time, composition, hardness, roughness, abrasion, scratch, solderability, corrosion, contact angle, morphology, SIR(Surface insulation resistance) and Whisker test were experimented. Also, Using ICP, XRF, FE-SEM, EDS, temperature/humidity chamber, solderability tester, hardness tester, roughness tester, abrasion tester, salt spray tester, contact angle tester, SIR tester, and microscope. In this paper could be shown the systematic and various analysis for reliability about four kinds of pb-Free plating solutions, processes and it's deposit surface.

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Cut Edge Corrosion of Painted Zn and 55%Al-Zn Coated Steels under Alternate Wetting and Drying

  • Nishikata, A.;Tsuda, T.;Tsuru, T.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.34-38
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    • 2010
  • Electrochemical study on cut edge corrosion of prepainted Zn coated (GI) and 55%Al-Zn coated (GL) steels has been performed in wet-dry cyclic conditions. Maximum width of delaminated polymer coating from the cut edge for GI and GL specimens was evaluated under wet-dry cyclic conditions. The cyclic tests were carried out for 1000 h by changing of relative humidity, where the salt of NaCl was deposited on the specimen every 48 h. The cut edge corrosion test under NaCl deposit indicated that the delamination of the GL specimen progresses at a higher rate than the GI. The electrochemical corrosion monitoring was also performed under condition of alternate exposure to immersion in NaCl solution and drying at 60%RH and $25^{\circ}C$. On the basis of the results of the delamination tests and electrochemical measurements, the mechanism of cut edge corrosion for GI and GL were discussed.

Aerosol Jet Deposition of $CuInS_2$ Thin Films

  • Fan, Rong;Kong, Seon-Mi;Kim, Dong-Chan;Chung, Chee-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.159-159
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    • 2011
  • Among the semiconductor ternary compounds in the I-III-$VI_2$ series, $CulnS_2$ ($CulnSe_2$) are one of the promising materials for photovoltaic applications because of the suitability of their electrical and optical properties. The $CuInS_2$ thin film is one of I-III-$VI_2$ type semiconductors, which crystallizes in the chalcopyrite structure. Its direct band gap of 1.5 eV, high absorption coefficient and environmental viewpoint that $CuInS_2$ does not contain any toxic constituents make it suitable for terrestrial photovoltaic applications. A variety of techniques have been applied to deposit $CuInS_2$ thin films, such as single/double source evaporation, coevaporation, rf sputtering, chemical vapor deposition and chemical spray pyrolysis. This is the first report that $CuInS_2$ thin films have been prepared by Aerosol Jet Deposition (AJD) technique which is a novel and attractive method because thin films with high deposition rate can be grown at very low cost. In this study, $CuInS_2$ thin films have been prepared by Aerosol Jet Deposition (AJD) method which employs a nozzle expansion. The mixed fluid is expanded through the nozzle into the chamber evacuated in a lower pressure to deposit $CuInS_2$ films on Mo coated glass substrate. In this AJD system, the characteristics of $CuInS_2$ films are dependent on various deposition parameters, such as compositional ratio of precursor solution, flow rate of carrier gas, stagnation pressure, substrate temperature, nozzle shape, nozzle size and chamber pressure, etc. In this report, $CuInS_2$ thin films are deposited using the deposition parameters such as the compositional ratio of the precursor solution and the substrate temperature. The deposited $CuInS_2$ thin films will be analyzed in terms of deposition rate, crystal structure, and optical properties.

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Application and Functionalization of Graphene Oxide on Cotton Fabric Via Aerosol Spray Pyrolysis (그래핀 옥사이드의 에어로졸 분무열분해 공정을 통한 면직물의 전기전도성 및 물성 평가)

  • Ohm, Hyunji;Cho, Gilsoo
    • Fashion & Textile Research Journal
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    • v.24 no.1
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    • pp.138-145
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    • 2022
  • Today, graphene loaded textiles are being considered promising smart clothing due to their high conductivity. In this study, we reported reduced graphene oxide(r-GO) deposited pure cotton fabrics fabricated with a colloidal solution of graphene(GO), using a one-step aerosol spray pyrolysis(ASP) process and their potential application on smart textiles. The ASP process is advantageous in that it is easily implementable and can be applied for continuous processing. Moreover, this process has never been applied to deposit r-GO on pure cotton fabric. The field emission-scanning microscopy (FE-SEM) observation, Fourier transform-infrared(FT-IR) analysis, Raman spectroscopy, X-ray diffraction(XRD) analysis, and ultraviolet transmittance(UVT) were used to evaluate material properties of the r-GO colloids. The resistance was also measured to evaluate the electrical conductivity of the specimens. The results revealed that the r-GO was successfully deposed on specimens, and the specimen with the highest electrical conductivity demonstrated an electrical resistance value of 2.27 kΩ/sq. Taken together, the results revealed that the ASP method demonstrated a high potential for effective deposition of r-GO on cotton fabric specimens and is a prospect for the development of conductive cotton-based smart clothing. Therefore, this study is also meaningful in that the ASP process can be newly applied by depositing r-GO on the pure cotton fabric.

Fungicidal Activity Enhancement of KNF-1002 Against Barley Powdery Mildew by Facilitating Foliar Uptake and Deposition (KNF-1002의 경엽 침투성과 부착량 증진에 의한 보리 흰가루병 방제 효과)

  • Yu, Ju-Hyun;Choi, Gyung-Ja
    • The Korean Journal of Pesticide Science
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    • v.14 no.3
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    • pp.272-279
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    • 2010
  • KNF-1002, a new fungicide candidate, is very effective for protecting crops against plant diseases, but its curative activity against barley powdery mildew is negligible due to its weak penetrability into plant leaf. To select the most efficient activator and, at the same time, spreade-sticker, foliar uptake and deposit of aqueous spray formulations containing non-ionic or anionic surfactants and fatty acid alkyl esters as an adjuvant were assessed by using Congo Red method. In the absence of activator, only 0.1% of the applied active ingredient was absorbed by barley leaves 24 h after spraying with an aqueous acetone containing KNF-1002 100 mg/L. But, non-ionic surfactants (500 mg/L), such as heptaethylene glycol monooctadecenyl ether (OE-7), dodecaethylene glycol monohexadecyl ether (CE-12), so facilitated KNF-1002 uptake that the uptake was increased up to 48.5%. To wheat plant, the addition of surfactants in spray solution of KNF-1002 also increased the foliar uptake and deposition of active ingredient, but its efficiency varied according to the kind of fatty alcohol moiety of polyoxyethylene surfactant. KNF-1002 formulations containing nonaethylene glycol monododecyl ether (LE-9) as an activator and spreader-sticker showed remarkable increases of fungicidal activity against barley powdery mildew.