• Title/Summary/Keyword: density evolution

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Evolution of Crystal Structure by Post-extension in Nylon 56 Fibers (연신에 따른 나일론 56 섬유의 결정 구조 및 수소결합 변화)

  • Jo, Kuk Hyun;Cho, Jung Hyeong;Kim, Hyo Jung;Lee, Hyun Hwi
    • Textile Coloration and Finishing
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    • v.28 no.1
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    • pp.33-39
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    • 2016
  • The crystal structure of nylon 56 fibers post extended by drawing process was investigated by synchrotron x-ray scattering measurement. In as-cast fiber, distinct (004) and (020) diffraction peaks were observed and they were related to initial metastable alignment of nylon molecules. With increase in the drawing ratio, (110) peak intensity was increased in vertical direction with decreasing (020) peak. At the same time, (004)' peak evolved position tilted to 29 degrees from the (004) peak. This evolution is directly related to stable crystalline phase of nylon 56 originated from additional formation of hydrogen bondings between N-H and C=O by post drawing process. We also compared density variation, stress-strain curves of the fiber as a function of drawing ratio and strain. The variations of density and tanacity also supported the increase of stable structure of nylon 56.

Wind-induced fragility assessment of urban trees with structural uncertainties

  • Peng, Yongbo;Wang, Zhiheng;Ai, Xiaoqiu
    • Wind and Structures
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    • v.26 no.1
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    • pp.45-56
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    • 2018
  • Wind damage of urban trees arises to be a serious issue especially in the typhoon-prone areas. As a family of tree species widely-planted in Southeast China, the structural behaviors of Plane tree is investigated. In order to accommodate the complexities of tree morphology, a fractal theory based finite element modeling method is proposed. On-site measurement of Plane trees is performed for physical definition of structural parameters. It is revealed that modal frequencies of Plane trees distribute in a manner of grouped dense-frequencies; bending is the main mode of structural failure. In conjunction with the probability density evolution method, the fragility assessment of urban trees subjected to wind excitations is then proceeded. Numerical results indicate that small-size segments such as secondary branches feature a relatively higher failure risk in a low wind level, and a relatively lower failure risk in a high wind level owing to windward shrinks. Besides, the trunk of Plane tree is the segment most likely to be damaged than other segments in case of high winds. The failure position tends to occur at the connection between trunk and primary branches, where the logical protections and reinforcement measures can be implemented for mitigating the wind damage.

Improving CMD Areal Density Analysis: Algorithms and Strategies

  • Wilson, R.E.
    • Journal of Astronomy and Space Sciences
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    • v.31 no.2
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    • pp.121-130
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    • 2014
  • Essential ideas, successes, and difficulties of Areal Density Analysis (ADA) for color-magnitude diagrams (CMD's) of resolved stellar populations are examined, with explanation of various algorithms and strategies for optimal performance. A CMD-generation program computes theoretical datasets with simulated observational error and a solution program inverts the problem by the method of Differential Corrections (DC) so as to compute parameter values from observed magnitudes and colors, with standard error estimates and correlation coefficients. ADA promises not only impersonal results, but also significant saving of labor, especially where a given dataset is analyzed with several evolution models. Observational errors and multiple star systems, along with various single star characteristics and phenomena, are modeled directly via the Functional Statistics Algorithm (FSA). Unlike Monte Carlo, FSA is not dependent on a random number generator. Discussions include difficulties and overall requirements, such as need for fast evolutionary computation and realization of goals within machine memory limits. Degradation of results due to influence of pixelization on derivatives, Initial Mass Function (IMF) quantization, IMF steepness, low Areal Densities ($\mathcal{A}$), and large variation in $\mathcal{A}$ are reduced or eliminated through a variety of schemes that are explained sufficiently for general application. The Levenberg-Marquardt and MMS algorithms for improvement of solution convergence are contained within the DC program. An example of convergence, which typically is very good, is shown in tabular form. A number of theoretical and practical solution issues are discussed, as are prospects for further development.

Plastic Deformation and Microstructural Evolution during ECAP Using a Dislocation Cell Related Microstructure-Based Constitutive Model (전위쎌에 기초한 미세조직 구성모델을 이용한 ECAP 공정 시 소성변형과 미세조직의 진화)

  • Yoon, S.C.;Baik, S.C.;Kim, H.S.
    • Transactions of Materials Processing
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    • v.15 no.6 s.87
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    • pp.441-444
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    • 2006
  • The deformation behavior of copper during equal channel angular pressing(ECAP) was calculated using a three-dimensional version of a constitutive model based on the dislocation density evolution. Finite element simulations of the variation of the dislocation density and the dislocation cell size with the number of ECAP passes are reported. The calculated stress, strain and cell size are compared with the experimental data for Cu deformed by ECAP in a modified Route C regime. The results of FEM analysis were found to be in good agreement with the experiments. After a rapid initial decrease down to about 200nm in the first ECAP pass, the average cell size was found to change little with further passes. Similarly, the strength increased steeply after the first pass, but tended to saturate with further pressings. The FEM simulations also showed strain non-uniformities and the dependence of the resulting strength on the location within the workpiece.

On Probability Distribution of Chloride Diffusion Coefficient for Recycled Aggregate Concrete

  • Ying, Jingwei;Xiao, Jianzhuang;Meng, Qiujiang
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.61-73
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    • 2016
  • In predicating the probability distribution of chloride diffusion coefficient of recycled aggregate concrete ($D_{RAC}$), the morphological characteristics of three phases, i.e., the old attached mortar, the natural aggregate and the new mortar, should all be taken into account. The present paper attempts to develop a probability density evolution method (PDEM) to achieve this. After verifying the derived PDEM results with experimental results, the effects of old attached mortar to the $D_{RAC}$ are examined in a quantitative manner. It is found that (1) the variation of the attached mortar content is much sensitive to $D_{RAC}$; (2) given the probability distribution of the content and chloride diffusion coefficient of old mortar, the probability distribution of DRAC can be analysed based on the PDEM; and (3) the critical chloride diffusion coefficient at a certain assurance rate can be obtained by the PDEM. The analysis results of this investigation will be valuable to the durability design for RAC.

Estimation of Fuel Rate on the Galactic Disk from High Velocity Cloud (HVC) Infall

  • Sung, Kwang Hyun;Kwak, Kyujin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.50.2-50.2
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    • 2016
  • Continuous accretion of metal-poor gas can explain the discrepancy between the number of observed G-dwarfs and the number predicted by the "simple model" of galactic evolution. The maximum accretion rate estimated based upon approaching high velocity clouds (HVCs) can be up to ${\sim}0.4M_{\odot}{\cdot}yr^{-1}$ which is comparable with the accretion rate required by many chemical evolution models that is at least ${\sim}0.45M_{\odot}{\cdot}yr^{-1}$. However, it is not clear to what extent the exchange of gas between the disk and the cloud can occur when an HVC collides with the galactic disk. Therefore, we examined a series of HVC-Disk collision simulations using the FLASH 2.5 hydrodynamics simulation code. The outcomes of our simulations show that an HVC will more likely take away substances from the galactic disk rather than adding new material to the disk. We define this as an HVC having a "negative fuel rate". Further results in our study also indicate that the process and amount of fuel rate change can have various forms depending on the density, radius and velocity of an approaching HVC. The simulations in our study covers HVCs with a neutral hydrogen volume density from $1.0{\times}10^{-2}cm^{-3}$ to $41.0cm^{-3}$, radius of 200 pc to 1000 pc and velocity in the range between $40km{\cdot}s^{-1}$ and $100km{\cdot}s^{-1}$.

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Bit-mapping Schemes of LDPC Codes for Partial Chase Combining (부분 체이스 결합을 위한 LDPC 부호의 비트 매핑 기법)

  • Joo, Hyeong-Gun;Shin, Dong-Joon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.37 no.5A
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    • pp.311-316
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    • 2012
  • In this paper, a bit-mapping scheme is proposed for partial Chase combining in LDPC-coded systems. Contrary to the previously known bit mapping that assigns the information bits to more reliable channels, the proposed mapping assigns the codeword bits of irregular LDPC codes to distinct Gaussian channels by considering the characteristics of LDPC codes and channels. The recursion equation for partial Chase combining is derived by using the density evolution technique, based on it, the best bit mapping among the various bit-mapping schemes is derived, and the validity of them is confirmed through simulation.

Rational Design of Binder-Free Fe-Doped CuCo(OH)2 Nanosheets for High-Performance Water Oxidation

  • Patil, Komal;Jang, Su Young;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.32 no.5
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    • pp.237-242
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    • 2022
  • Designing and producing a low-cost, high-current-density electrode with good electrocatalytic activity for the oxygen evolution reaction (OER) is still a major challenge for the industrial hydrogen energy economy. In this study, nanostructured Fe-doped CuCo(OH)2 was discovered to be a precedent electrocatalyst for OER with low overpotential, low Tafel slope, good durability, and high electrochemically active surface sites at reduced mass loadings. Fe-doped CuCo(OH)2 nanosheets are made using a hydrothermal synthesis process. These nanosheets are clumped together to form a highly open hierarchical structure. When used as an electrocatalyst, the Fe-doped CuCo(OH)2 nanosheets required an overpotential of 260 mV to reach a current density of 50 mA cm-2. Also, it showed a small Tafel slope of 72.9 mV dec-1, and superior stability while catalyzing the generation of O2 continuously for 20 hours. The Fe-doped CuCo(OH)2 was found to have a large number of active sites which provide hierarchical and stable transfer routes for both electrolyte ions and electrons, resulting in exceptional OER performance.

Study on the Coating Electrode for the Alkaline Water Electrolysis (알칼리 수전해용 코팅 전극에 관한 연구)

  • MIN-JI KANG;CHEOL-HWI RYU;GAB-JIN HWANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.575-580
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    • 2023
  • An electrode was prepared by dip-coating NiFe2O4 powder on stainless steel (SUS) support for the application in the alkaline water electrolysis. The prepared electrode was analyzed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDXS), and was evaluated for the voltage properties with the change of current density in oxygen evolution reaction (OER) and hydrgen evolution reaction (HER) using 1, 3 and 7 M KOH solution. From the SEM and EDXS analysis, it was confirmed that the prepared electrode had NiFe2O4 on the SUS support. In OER and HER, the voltage in the 7 M KOH solution had a value of 1.35 and -1.90 V at 0.2 and -0.2 A/cm2 of the current density, respectively. It was considered that the prepared electrode could be use as an electrode in the alkaline water electrolysis from the experimental results.

Phase stability and Sintered Properties of 1.5mol% Yttria-stabilized Zirconia Ceramics Fabricated by Low Temperature Sintering (저온 열처리로 제작된 1.5 mol% 이트리아 안정화 지르코니아 세라믹스의 상 안정성 및 소결물성)

  • Kyung Tae Kim;Han Cheol Choe;Jeong Sik Park;Jong Kook Lee
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.1
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    • pp.1-8
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    • 2024
  • Phase stability of tetragonal crystals in yttria-stabilized zirconia ceramics is dependent on the content of yttria and the heat-treatment condition, related with mechanical properties. In this study, we fabricated the 1.5 mol% yttria-stabilized zirconia (1.5Y-YSZ) ceramics by cold isostatic pressing (CIP) and post-sintering at temperature range of 1200 to 1350℃ for 2 hours and investigated the sintered properties and microstructural evolution. Sintered and microstructural parameters, i.e, apparent density, grain size and phase composition of 1.5Y-YSZ ceramics were mainly dependent on the sintering temperature. Maximum sintered density of 99.4 % and average grain size of 200-300 nm could be obtained from the heat-treatment condition above sintering temperature at 1300℃ for 2 hours, possessing the superior mechanical hardness with 1200 Hv. However, phase stability of tetragonal grains in 1.5 YSZ ceramics is very low, inducing the phase transformation to monoclinic crystals on specimen surface during cooling after heat-treatment.