• Title/Summary/Keyword: density evolution

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SOFT MAGNETIC PROPERTIES OF FeTaNC NANOCRYSTALLINE FILMS

  • Koh, Tae-Hyuk;Shin, Dong-Hoon;Choi, Woon;Ahn, Dong-Hoon;Nam, Seoung-Eui;Kim, Hyoung-June
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.393-398
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    • 1996
  • Soft magnetic properties and microstructural evolution of FeTaNC films were investigated, and compared with FeTaN and FeTaC films. Effects of substrate species (glass vs. $CaTiO_3$) on the magnetic properties were also investigated. Co-addition of N and C significantly enhance the grain refinments and magnetism, compared with N or C addition only. Good soft magnetic characteristics of coercivity of 0.17 Oe, permeability of 4000 (5MHz), and saturation flux density of 17 kG can be obtained in the FeTaNC in the relatively wide process windows. While these values appears to be similar to those of FeTaN on glass substrate, most distinctive difference between FeTaNC and FeTaN(or C) is in the effects of substrate. Whereas FeTaNC films show good magnetic characteristics for both glass and $CaTiO_3$ substrates, FeTaN(or C) films show significant degradation on the $CaTiO_3$ substrate.

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Effects of Platinum Nano Electrodeposits on the Corrosion of Carbon Substrate in an Acidic Environment (백금 나노 도금입자가 산성 환경에서 탄소기판 부식에 미치는 영향)

  • Choe, Min-Ho;Park, Chan-Jin
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.34-35
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    • 2008
  • We investigated the effects of Pt nano electrodeposits on the corrosion of carbon substrate in an acidic solution. The electrodes for experiments were prepared by electrodepositing Pt on carbon substrate in a solution of 5 mM $H_2PtCl_6$ and 0.5 M $H_2SO_4$ using pulse deposition technique. In cyclic voltammograms for the carbon electrodes with and without Pt nano electrodeposits, total anodic current including both currents from oxygen evolution reaction and carbon corrosion increased abruptly above a critical potential. In addition, the critical potential of the carbon electrodes with Pt nano electrodeposits was lower than that of bare carbon electrode. This phenomenon was more prominent at $75^{\circ}C$ than $25^{\circ}C$. In potentiostatic experiments, the current transients and the corresponding power spectral density increased with increasing the applied potential for the electrodes. Furthermore, the current transients for the carbon electrodes with Pt nano electrodeposits were much higher than those for the bare carbon substrate. This indicates that the corrosion of carbon substrate can be highly accelerated by Pt nano electrodeposits.

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Microstructural Evolution and Tensile Properties of Cu-Sn Based Alloys Manufactured by Spray Casting Route (분무주조에 의해 제조된 Cu-Sn계 합금의 미세조직 및 인장성질)

  • Shim, Sang-Hyun;Kang, Hee-Soo;Baik, Kyeong-Ho
    • Journal of Powder Materials
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    • v.17 no.6
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    • pp.477-481
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    • 2010
  • Cu-Sn based alloys were manufactured by gas atomization spray casting route in order to achieve a fine scale microstructure and a high tensile strength. The spray cast Cu-10Sn-2Ni-0.2Si alloy had an equiaxed grain microstructure, with no formation of brittle ${\delta}-Cu_{41}Sn_{11}$ phase. Aging treatment promoted the precipitation of finely distributed particles corresponding to ${\delta}-Ni_2Si$ intermetallic phase throughout the $\alpha$-(CuSn) matrix. The cold-rolled Cu-Sn-Ni-Si alloy had a very high tensile strength of 1200 MPa and an elongation of 5%. Subsequent aging treatment at $450^{\circ}C$ for 1h slightly reduced the tensile strength to 700 MPa and remarkably increased the elongation up to 30%. This result has been explained by coarsening the precipitates due to over aging and reducing the dislocation density due to annealing effects.

Hydrogen Production in Polyvinyl-Immobilized Anabaena azollae Cells (Polyvinyl에 고정화된 Anabaena azollae에서의 수소생성)

  • 박인호;송종호
    • KSBB Journal
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    • v.6 no.2
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    • pp.181-187
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    • 1991
  • Physiological and morphological characteristics of Anabaena azollae cells immobilized in a synthetic polymer, polyvinyl(PV), were investigated. The cell density of the non-immersed PV foam reached 4.4mg Chl/g dry wt. PV foam. This is 8 times higher than that of PV-immobiliz action in immersed batch system. And MSX-induced ammonia productivity and the photosynthectic oxygen evolution activity are higher than that of free cells after short-term dark storage. Nitrogenase activity and thermostability of photosynthetic activity are also higher than that of free Anabaena cells after immobilization. Total hydrogen production reached to 1.6ml $H_2$ per reactor (total 4mg Chl) after 6 days.

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Uncertainty analysis of containment dose rate for core damage assessment in nuclear power plants

  • Wu, Guohua;Tong, Jiejuan;Gao, Yan;Zhang, Liguo;Zhao, Yunfei
    • Nuclear Engineering and Technology
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    • v.50 no.5
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    • pp.673-682
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    • 2018
  • One of the most widely used methods to estimate core damage during a nuclear power plant accident is containment radiation measurement. The evolution of severe accidents is extremely complex, leading to uncertainty in the containment dose rate (CDR). Therefore, it is difficult to accurately determine core damage. This study proposes to conduct uncertainty analysis of CDR for core damage assessment. First, based on source term estimation, the Monte Carlo (MC) and point-kernel integration methods were used to estimate the probability density function of the CDR under different extents of core damage in accident scenarios with late containment failure. Second, the results were verified by comparing the results of both methods. The point-kernel integration method results were more dispersed than the MC results, and the MC method was used for both quantitative and qualitative analyses. Quantitative analysis indicated a linear relationship, rather than the expected proportional relationship, between the CDR and core damage fraction. The CDR distribution obeyed a logarithmic normal distribution in accidents with a small break in containment, but not in accidents with a large break in containment. A possible application of our analysis is a real-time core damage estimation program based on the CDR.

Handover based on Maximum Cell Residence Time and Adaptive TTT for LTE-R High-Speed Railways

  • Cho, Hanbyeog;Han, Donghyuk;Shin, Sungjin;Cho, Hyoungjun;Lee, Changsung;Lim, Goeun;Kang, Mingoo;Chung, Jong-Moon
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.8
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    • pp.4061-4076
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    • 2017
  • With the development of high-speed railway technologies, train velocities can now reach speeds up to 350 km/h, and higher in the future. In high-speed railway systems (HSRs), loss of communication can result in serious accidents, especially when the train is controlled through wireless communications. For to this reason, operators of Long Term Evolution for Railway (LTE-R) communication systems install eNodeBs (eNBs) with high density to achieve highly reliable communications. However, densely located eNBs can result in unnecessary frequent handovers (HOs) resulting in instability because, during every HO process, there is a period of time in which the communication link is disconnected. To solve this problem, in this paper, an HO scheme based on the maximum cell residence time (CRT) and adaptive time to trigger (aTTT), which are collectively called CaT, is proposed to reduce unnecessary HOs (using CRT estimations) and decrease HO failures by improving the handover command transmission point (HCTP) in LTE-R HSR communications.

An NMR Study on Molecular Motions of $\alpha$,2,6-Trichlorotoluene in Solution State

  • Ahn, Sang-Doo;Lee, Jo-Woong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.7
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    • pp.553-559
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    • 1994
  • Dynamics of $CH_2CI$ group in ${\alpha},2,6$-trichlorotoluene dissolved in $CDCl_3$ was studied by observing various relaxation modes for $^{13}C$ under proton undecoupled condition. Partially relaxed $^{13}C$ spectra were obtained at $34^{\circ}C$ as a function of evolution time after applying various designed pulse sequences to this $AX_2$ spin system. It was found that nonlinear regression analysis of the relaxation data for these magnetization modes could provide the information about dipolar and spin-rotational auto-correlation and cross-correlation spectral densities for fluctuation of the $^{13}C-^1H$ internuclear vector in $CH_2Cl$ group. The results show that the effect of cross-correlation is comparable in magnitude to that of auto-correlation and the relaxation in this spin system is dominated by dipolar mechanism rather than spin-rotational one. From the resulting spectral density data we could calculate the bond angle ${\angle}HCH\;(105.1$^{\circ}$) and elements of the rotational diffusion tensor for $CH_2Cl$ group.

Characterization for Performance of Zn-Air Recharegeable Batteries on Different Composition in Acidic Electrolyte (산성용액에서 전해액 조성에 따른 아연공기 이차전지의 성능변화)

  • DAI, GUANXIA;LU, LIXIN;SHIM, JOONGPYO;LEE, HONG-KI
    • Journal of Hydrogen and New Energy
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    • v.32 no.5
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    • pp.401-409
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    • 2021
  • The combination of different concentrations of ZnSO4 in acidic solution as electrolyte in Zn-air batteries was investigated by Zn symmetrical cell test, half-cell and full cell tests. Using 1 M ZnSO4 + 0.05 M H2SO4 as electrolyte and MnO2 as air cathode catalyst with Zn foil anode, this combination had a satisfactory performance with balance of electrochemical activity and stability. Its electrochemical activity was matched to or even better than the PtRu catalyst in different current density. And its cycle life was improved (more than 100 cycles stable) by suppressing the growth of zinc dendrites on anode obviously. This electrolyte overcame the shortcomings of alkaline electrolyte that are easy to react with CO2 in the air, severely growth of Zn dendrites caused by uneven plating/stripping of Zn.

Modelling of multidimensional effects in thermal-hydraulic system codes under asymmetric flow conditions - Simulation of ROCOM tests 1.1 and 2.1 with ATHLET 3D-Module

  • Pescador, E. Diaz;Schafer, F.;Kliem, S.
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3182-3195
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    • 2021
  • The implementation and validation of multi-dimensional (multi-D) features in thermal-hydraulic system codes aims to extend the application of these codes towards multi-scale simulations. The main goal is the simulation of large-scale three-dimensional effects inside large volumes such as piping or vessel. This novel approach becomes especially relevant during the simulation of accidents with strongly asymmetric flow conditions entailing density gradients. Under such conditions, coolant mixing is a key phenomenon on the eventual variation of the coolant temperature and/or boron concentration at the core inlet and on the extent of a local re-criticality based on the reactivity feedback effects. This approach presents several advantages compared to CFD calculations, mainly concerning the model size and computational efforts. However, the range of applicability and accuracy of the newly implemented physical models at this point is still limited and needs to be further extended. This paper aims at contributing to the validation of the multi-D features of the system code ATHLET based on the simulation of the Tests 1.1 and 2.1, conducted at the test facility ROCOM. Overall, the multi-D features of ATHLET predict reasonably well the evolution from both experiments, despite an observed overprediction of coolant mixing at the vessel during both experiments.

Measurement of fast ion life time using neutron diagnostics and its application to the fast ion instability at ELM suppressed KSTAR plasma by RMP

  • Kwak, Jong-Gu;Woo, M.H.;Rhee, T.
    • Nuclear Engineering and Technology
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    • v.51 no.7
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    • pp.1860-1865
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    • 2019
  • The confinement degradation of the energetic particles during RMP would be a key issue in success of realizing the successful energy production using fusion plasma, because a 3.5 MeV energetic alpha particle should be able to sustain the burning plasma after the ignition. As KSTAR recent results indicate the generation of high-performance plasma(${\beta}_p{\sim}3$), the confinement of the energetic particles is also an important key aspect in neutral beam driven plasma. In general, the measured absolute value of the neutron intensity is generally used for to estimating the confinement time of energetic particles by comparing it with the theoretical value based on transport calculations. However, the availability of, but for its calculation process, many accurate diagnostic data of plasma parameters such as thermal and incident fast ion density, are essential to the calculation process. In this paper, the time evolution of the neutron signal from an He3 counter during the beam blank has permitted to facilitate the estimation of the slowing down time of energetic particles and the method is applied to investigate the fast ion effect on ELM suppressed KSTAR plasma which is heated by high energy deuterium neutral beams.