• Journal of Electrochemical Science and Technology
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• v.14 no.3
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• pp.243-251
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• 2023

Developing oxygen evolution reaction (OER) electrocatalysts is essential to accomplish viable CO₂ and water electrolysis. Herein, we report the fabrication and OER performance of Ni-foam (NF)-immobilized Ni₆ nanoclusters (NCs) (Ni₆/NF) prepared by a dip-coating process. The Ni₆/NF electrode exhibited a high current density of 500 mA/cm² for the OER at an overpotential as low as 0.39 V. Ni₆/NF exhibited high durability in an alkaline solution without corrosion. Electrokinetic studies revealed that OER can be easily initiated on Ni6 NC with fast electron-transfer rates. Finally, we demonstrated stable CO₂-to-CO electroreduction using an NC-based zero-gap CO₂ electrolyzer operated at a current density of 100 mA/cm² and a full-cell potential of 2.0 V for 12 h.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.280-288
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• 1996

In the ozone evolution using $PbO_2$, which was electrodeposited on Ti plate at various conditions in electrolyte, the effects of lead dioxide structure on the current efficiency and surface structure changes of lead dioxide were investigated. Also the effects of oxygen transfer reaction on the ozone evolution were investigated by means of a $PbO_2$ electrodeposited on the platinum rotating disk electrode. In order to develope an electrode for ozone evolution, durability of lead dioxide and optimum current density were investigated. At the electrodeposited lead dioxide with the larger grain size and higher crystallinity, the efficiency for ozone evolution was higher. Optimum current density to electrodeposite lead dioxide with large grain size and high crystalinity was $50mA/cm^2$. Lead dioxide deposited in the presence of glycerin showed the best advantage of ozone evolution. Also lead dioxide electrodeposited at less than $10mA/cm^2$ or at more than $100mA/cm^2$ has poor performance of ozone evolution and poor adhesive strength to substrate. In the beginning of ozone evolution, surface structure of lead dioxide was changed and this change resulted in good effects on ozone evolution. Lead dioxide doped with other elements was favorable not to ozone evolution but to oxygen evolution, so it is speculated that ozone evolution has not intermediate stage of oxygen evolution and occurs competitively with oxygen evolution. When ozone was evolved at $0.7{\sim}0.8A/cm^2$, the current efficiency was highest.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.369-371
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• 2003

This paper attempts to study the evolution of the Solar System including the earth through various existing hypotheses and the occurrence of earthquakes on the earth. From the analysis of the various theories it can be inferred that the Mystery regarding evolution of Solar System is a complex problem which requires continuos research. The occurrence of the earthquake is also affected by the earth's rotation, which produces Centrifugal Force, which together with convection current causes plate displacement resulting in earthquakes. The extent of displacement varies with the size and density of the plates.

• Korean Journal of Mathematics
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• v.20 no.3
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• pp.323-331
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• 2012

We present a high-order potential ow model for the motion of the impulsively accelerated unstable interface of infinite density jump. The Layzer model for the evolution of the interface is extended to high-order. The time-evolution solutions of the bubble and the spike in the interface are obtained from the high-order model. We show that the high-order model gives improvement on the prediction of the evolution of the bubble and the spike.

• Korean Journal of Materials Research
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• v.19 no.5
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• pp.276-280
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• 2009

The effect of the initial packing structure on the plasticity of amorphous alloys was investigated by tracing the structural evolution of the amorphous solid inside a shear band. According to the molecular dynamics simulations, the structural evolution of the amorphous solids inside the shear band was more abrupt in the alloy with a higher initial packing density. Such a difference in the structural evolution within the shear band observed from the amorphous alloys with different initial packing density is believed to cause different degrees of shear localization, providing an answer to the fundamental question of why amorphous alloys show different plasticity. We clarify the structural origin of the plasticity of bulk amorphous alloys by exploring the microstructural aspects in view of the structural disordering, disorder-induced softening, and shear localization using molecular dynamics simulations based on the recently developed MEAM (modified embedded atom method) potential.

• Interaction and multiscale mechanics
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• v.6 no.2
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• pp.157-172
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• 2013

This paper presented an investigation of macromolecular suspension in a grooved channel by using the dissipative particle dynamics (DPD) with finitely extensible non-linear elastic (FENE) bead spring chains model. Before studying the movement and evolution of macromolecules, the DPD method was first validated by modeling the simple fluid flow in the grooved channel. For both simple fluid flow and macromolecular suspension, the flow fields were analyzed in detail. It is found that the structure of the grooved channel with sudden contraction and expansion strongly affects the velocity distribution. As the width of the channel reduces, the horizontal velocity increases simultaneously. Vortices can also be found at the top and bottom corners behind the contraction section. For macromolecular suspension, the macromolecular chains influence velocity and density distribution rather than the temperature and pressure. Macromolecules tend to drag simple fluid particles, reducing the velocity with density and velocity fluctuations. Particle trajectories and evolution of macromolecular conformation were investigated. The structure of the grooved channel with sudden contraction and expansion significantly influence the evolution of macromolecular conformation, while macromolecules display adaptivity to adjust their own conformation and angle to suit the structure so as to pass the channel smoothly.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.41.2-41.2
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• 2012

It has been suggested that merging plays an important role in the formation and the evolution of early-type galaxies (ETGs). Optical-NIR color gradients of ETGs in high density environments are found to be less steep than those of ETGs in low density environments, hinting frequent merger activities in ETGs in high density environments. In order to examine if the flat color gradients are the result of dry mergers, we studied the relations between merging features, luminosities, environments and color gradients of 196 low redshift ETGs selected from Sloan Digital Sky Survey (SDSS) Stripe82. Near Infrared (NIR) images are taken from UKIRT Infrared Deep Sky Survey (UKIDSS) Large Area Survey (LAS). Color (r-K) gradients of ETGs with tidal features are a little flatter than relaxed ETGs, but not significant. We found that massive (> 10^11.3 solar masses) ETGs have -40% less scattered color gradients than less massive ETGs. The less scattered color gradients of massive ETGs could be evidence of dry merger processes in the evolution of massive ETGs. We found no relation between color gradients of ETGs and their environments.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.87.1-87.1
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• 2017

High functional catalyst to efficiently produce clean and earth-abundant renewable fuels plays a key role in securing energy sustainability and environmental protection of our society. Hydrogen has been considered as one of the most promising energy carrier as represented by focused research works on developing catalysts for the hydrogen evolution reaction (HER) from the water hydrolysis over the last several decades. So far, however, the major catalysts are expensive transition metals. Here using first principles density functional theory (DFT) calculations we screen various pyrites for HER by identifying fundamental descriptor governing the catalytic activity. We enable to capture a strong linearity between experimentally measured exchange current density in HER and calculated adsorption energy of hydrogen atom in the pyrites. The correlation implies that there is an underlying design principle tuning the catalytic activity of HER.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.10 no.12
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• pp.5401-5421
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• 2016

Both low-density parity-check (LDPC) codes and the multiple access technique of spatially coupling data transmission (SCDT) can be expressed in bipartite graphs. To improve the performance of iterative demodulation and decoding for SCDT, a novel joint sparse graph (JSG) with SCDT and LDPC codes is constructed. Based on the JSG, an approach for iterative joint demodulation and decoding by belief propagation (BP) is presented as an exploration of the flooding schedule, and based on BP, density evolution equations are derived to analyze the performance of the iterative receiver. To accelerate the convergence speed and reduce the complexity of joint demodulation and decoding, a novel serial schedule is proposed. Numerical results show that the joint demodulation and decoding for SCDT based on JSG can significantly improve the system's performance, while roughly half of the iterations can be saved by using the proposed serial schedule.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.42 no.7 s.337
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• pp.27-34
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• 2005

Iterative detection (ID) has proven to be a near-optimal solution for concatenated Finite State Machines (FSMs) with interleavers over an additive white Gaussian noise (AWGN) channel. When perfect channel state information (CSI) is not available at the receiver, an adaptive ID (AID) scheme is required to deal with the unknown, and possibly time-varying parameters. The basic building block for ID or AID is the soft-input soft-output (SISO) or adaptive SISO (A-SISO) module. In this paper, Reduced State SISO (RS-SISO) algorithms have been applied for complexity reduction of the A-SISO module. We show that serially concatenated CPM (SCCPM) with AID has turbo-like performance over fading ISI channels and also RS-A-SISO systems have large iteration gains. Various design options for RS-A-SISO algorithms are evaluated. Recently developed density evolution technique is used to analyze RS-A-SISO algorithms. We show that density evolution technique that is usually used for AWGN systems is also a good analysis tool for RS-A-SISO systems over frequency-selective fading channels.