• Bulletin of the Korean Chemical Society
• /
• 제8권1호
• /
• pp.31-39
• /
• 1987

By using a complete rate constant($k_e$) which treats a solvent (water) as a reactant, and a conventional rate constant($k_c$), which ignores the solvent in describing the rate, the parameters ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were introduced. These quantities represent the volume change, the enthalpy change, and the entropy change accompanying the electrostriction which occurs when solvent molecules condense on the activated complex. The authors measured the rates of the solvolysis of benzoyl chloride in water-acetone mixtures at $15^{\circ}$ to $30^{\circ}C$ and 1 bar to 2500 bars. Applying the authors' theory to the experimental results, the parameters, ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were evaluated, and it was found that they are all negative, indicating that water dipoles condense on the activated complex. They also proposed the following equations: ${\Delta}H^{\neq}_c\;=\;{\Delta}H^{\neq}_e\;+\;{\Delta}H^{\neq}_s\;and\; {\Delta}S^{\neq}_c\;=\;{\Delta}S^{\neq}_e\;+{\Delta}S^{\neq}_s\;,\;where\;{\Delta}H^{\neq}_c\;and\;{\Delta}H^{\neq}_c\;and\;{\Delta}S^{\neq}_s $are the activation enthalpy change and the activation entropy change for the conventional reaction rate, respectively, and ${\Delta}H^{\neq}_e$ and ${\Delta}S^{\neq}_e$ are the corresponding quantities for the complete reaction rate. The authors proposed that for the $SN_1$ type, all the quantities, ${\Delta}V^{\neq}_s,\;{\Delta}S^{\neq}_s\;,{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ are comparatively large, and for the $SN_2$ type, these quantities are smaller than for the $SN_1$ type, and occasionally the case ${\Delta}S^{\neq}_e$ < 0 occurs. Using these criteria, the authors concluded that at high temperature, high pressure and for a high water content solvent, the SN_1$ type mechanism predominates whereas in the reversed case the $SN_2$M type predominates.

• 한국자기학회지
• /
• 제19권1호
• /
• pp.12-16
• /
• 2009

Z-Type 바리움 페라이트($Ba_{3}Co_{0.8}Zn_{1.2}Fe_{24}O_{41}$)를 공침법으로 제조하고 결정구조와 자기적 성질을 조사하였다. $Ba_{3+{\delta}}Co_{0.8}Zn_{1.2}Fe_{24}O_{41}$(${\delta}$ = 3, 5, 7, 13 wt%)와 $Ba_{3}Co_{0.8}Zn_{1.2}Fe_{{24}+{\delta}}O_{41}$(${\delta}$ = 5, 7, 10 wt%)의 조성을 가진 분말의 ${\delta}$ 값에 따른 자기적 성질의 변화를 조사하였다. 제조된 모든 바리움 페라이트에는 Z-type으로 상전이 하지 않은 M-type이 상당량 잔류하고 있었다. 포화자화는 Ba와 Fe의 과잉 첨가량 ${\delta}$가 각각 7 wt%와 5 wt% 일 때 최대로 나타났고 보자력은 조사된 모든 분말에서 다소 높게 나타났다. 높은 보자력은 M-type이 잔류하기 때문이다. 과잉의 Ba와 Fe 첨가에 따른 결정구조의 변화는 없었다. Z-type 바리움 페라이트의 연자성 특성을 향상시키기 위해서는 M-type이 Z-type 형성온도에서 상전이가 일어나도록 해야 함을 알았다.

• Journal of Welding and Joining
• /
• 제28권2호
• /
• pp.91-95
• /
• 2010

Stress distribution and deformation on the CT-type(Cross Tension type) spot welded lap joint subjected to out of plane tensile load were investigated by finite element method. Using the maximum principal stresses at the nugget edge obtained by FEM analysis, evaluated the fatigue strength of the CT-type spot welded lap joints having various dimensions and materials. and also, the influence of the geometrical parameters of CT-type spot welded lap joints on stress distribution and fatigue strength must be evaluated. thus, in this paper, ${\Delta}P-N_f$ curve were obtained by fatigue tests. Using these results, ${\Delta}P-N_f$ curve were systematically rearranged in the $\Delta\sigma-N_f$ relation with the hot spot stresses at the CT-type spot welded lab joints. It was found that the proposed $\Delta\sigma-N_f$ relation could provide a more reasonable fatigue design criterion for the CT-type spot welded lap joints.

• Journal of Ginseng Research
• /
• 제41권2호
• /
• pp.195-200
• /
• 2017

Background: The natural ratios of carbon (C), nitrogen (N), and sulfur (S) stable isotopes can be varied in some specific living organisms owing to various isotopic fractionation processes in nature. Therefore, the analysis of C, N, and S stable isotope ratios in ginseng can provide a feasible method for determining ginseng authenticity depending on the cultivation land and type of fertilizer. Methods: C, N, and S stable isotope composition in 6-yr-old ginseng roots (Jagyeongjong variety) was measured by isotope ratio mass spectrometry. Results: The type of cultivation land and organic fertilizers affected the C, N, and S stable isotope ratio in ginseng (p < 0.05). The ${\delta}^{15}N_{AIR}$ and ${\delta}^{34}S_{VCDT}$ values in ginseng roots more significantly discriminated the cultivation land and type of organic fertilizers in ginseng cultivation than the ${\delta}^{13}C_{VPDB}$ value. The combination of ${\delta}^{13}C_{VPDB}$, ${\delta}^{15}N_{AIR}$, or ${\delta}^{34}S_{VCDT}$ in ginseng, except the combination ${\delta}^{13}C_{VPDB}-^{34}S_{VCDT}$, showed a better discrimination depending on soil type or fertilizer type. Conclusion: This case study provides preliminary results about the variation of C, N, and S isotope composition in ginseng according to the cultivation soil type and organic fertilizer type. Hence, our findings are potentially applicable to evaluate ginseng authenticity depending on cultivation conditions.

• Journal of applied mathematics & informatics
• /
• 제17권1_2_3호
• /
• pp.701-707
• /
• 2005

Delta sequences play an important role in convergence and approximation theory. Much of classical approximation theory is based on delta sequence. The rate of convergence of certain types of these sequences in Sobolev spaces has recently been studied. Here we estimate convergence rate of convolution type delta sequence in higher dimension.

• 한국수학교육학회지시리즈B:순수및응용수학
• /
• 제19권3호
• /
• pp.281-288
• /
• 2012

In this paper, the author defines a new generalized ${\eta}$, ${\delta}$, ${\alpha}$)-pseudomonotone mapping and considers the equivalence of Stampacchia-type vector variational-like inequality problems and Minty-type vector variational-like inequality problems for generalized (${\eta}$, ${\delta}$, ${\alpha}$)-pseudomonotone mappings in Banach spaces, called the generalized vector Minty's lemma.

• 산경연구논집
• /
• 제9권12호
• /
• pp.15-21
• /
• 2018

Purpose - In order to improve the comprehensive competitiveness of cultural tourism creative industries in the region, different grade cities should adapt to local conditions and differentiated development as the angle. It can promote the optimization of regional tourism industry structure, and make relevant suggestions accordingly. Research design, data, and methodology - Based on the characteristics of cultural tourism creative industry, 24 indicators are selected from four aspects. The comprehensive competitiveness evaluation index system of cultural tourism creative industry is constructed. The essay use factor analysis to quantitatively evaluate 27 cities in the Pan-Yangtze River Delta, and use cluster analysis to classify the competitiveness of cultural tourism creative industries in each city into five types. Results - The results of cluster analysis show that the whole area presents five kinds of step-like features, which are mature leading type, the advantageous development type, comparatively advantageous type, well-grounded type and difference-promotion type. Conclusions - The factor analysis method was used to quantitatively evaluate 27 cities in the Pan-Yangtze River Delta, and cluster analysis was used to classify the cultural tourism creative industry competitiveness of each city into fives type city. Based on the differentiation of cultural tourism creative industry competitiveness and 27 cities in the Pan-Yangtze River Delta, the relevant strategies were proposed.

• 한국작물학회지
• /
• 제30권3호
• /
• pp.217-222
• /
• 1985

초형이 다른 3종의 수도 Isogenic line(Open-Spread- 및 Broom-type)을 5수준의 이앙밀도(47.62, 22.22, 15.15, 15.11 및 8.33주/$m^2$)와 4수준의 시비조건(증비, 보비, 감비 및 무비)에 공시하여 얻은 수량자료를 Multiple regression polynomial 수식으로 고정하고 편미분하여 밀도와 시비및 밀도$\times$시비의 작용력을 해석하였다. 그 결과는 다음과 갈다. 1. 소식조건하에서의 밀도변동에 따른 수량 반응은 Broom-type이 가장 높고 예민하였다(도 1). 2. 이앙밀도의 작용력〔$\delta$f(D, F)/$\delta$D〕은 Open-, 및 Spread-type이 다비에서 높아지는 대신에Broom-type은 시비와 관계없이 소식 및 밀식에서 높은 경향이었다.(도 2). 3. 시비율의 작용력 〔$\delta$f(D, F)/$\delta$D〕은 0~1000kg/10a 범위로서 Open- 및 Spread-type에서는 밀식조건하에서 높았으나 Broom-type에서는 소식조건하에서 소비 및 다비의 작용력이 큰 경향이었다(도 3). 4. Broom-type의 소식조건하에서 밀도$\times$시비의 상호작용력 〔$\delta$$^2$F(D, F)/$\delta$D$\delta$F〕은 음성을 나타내었고, Open- 및 Spread-type은 표준 및 밀식과 증비 조건에서 양성을 나타내었다(도 4). 5. $m^2$당 11~14주의 소식조건하에서 추정되는 소요시비수준은 Open-type 이 1.3~1.5배비인 반면에 Broom-type은 1.5배비 이상의 수준인 것으로 판단되었다. 6. 소식에 의한 이앙노동의 생력화를 위해서는 다비수용이 가능한 Broom-type의 연구가 필요할 것으로 해석이 된다.

• Journal of applied mathematics & informatics
• /
• 제16권1_2호
• /
• pp.633-641
• /
• 2004

In this paper we deal with functions in higher dimension. We provide several convergence theorem for approximation by convolution type delta sequence. We also give sufficient and necessary condition for Gibbs phenomenon to exist.

• Kyungpook Mathematical Journal
• /
• 제46권1호
• /
• pp.119-130
• /
• 2006

A new class of functions is introduced in this paper. This class is called almost ${\delta}$-precontinuity. This type of functions is seen to be strictly weaker than almost precontinuity. By using ${\delta}$-preopen sets, many characterizations and properties of the said type of functions are investigated.