• Title/Summary/Keyword: delamination.

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Fabrication of Hydrocarbon Membrane based DMFC MEAs with Low Temperature Decal Method (탄화수소계 전해질막과 저온 전사법을 이용한 DMFC용 MEA 제조)

  • Krishnan, N. Nambi;Prabhuram, Joghee;Ha, Heung-Yong;Kim, Soo-Kil
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.415-417
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    • 2009
  • A low temperature decal (LTD) transfer method is tried to fabricated hydrocarbon (HC) membrane based MEA. Sandwiched structures of outer ionomer/catalyst/carbon coating/substrate, which had been developed for Nafion membrane, are used for transfer of catalyst to the HC membrane. Performances of the HC MEA before and after 500hr continuous operation are compared and it is found that a severe delamination occurs at the interface between the HC membrane and the catalyst layer, which is the main reason of the low performance and its degradation. The delamination is due probably to the different nature of HC membrane to the Nafion ionomer. A substitutional method, therefore, is suggested to overcome this. In such a way, the outer ionomer process is removed and the low transfer rate of catalyst by skipping the ionomer process is compensated with optimization of other process variables such as transfer time or temperature. The resulting performance is superior to the original LTD method, which can be explained in terms of low resistive components both in ohmic and kinetic.

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Shrinkage and Durability Characteristics of Latex Modified Repair Mortar for Agricultural Concrete Structures (농업용 콘크리트 구조물용 라텍스개질 보수용 모르타르의 수축 및 내구성능 평가)

  • Won, Jong-Pil;Lee, Jae-Young;Park, Chan-Gi;Park, Seong-Gi;Kim, Wan-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.5
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    • pp.23-30
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    • 2007
  • This research was to evaluate the shrinkage and durability performance of latex modified repair mortar and to improve the service lift of the agricultural concrete structures. The shrinkage characteristics of the repair material creates the delamination of repair materials and existing concrete. It may reduce the service life of structures. Also the reduction of durability performance of the repair materials induces the destruction of the repaired concrete structures at early stage. In this research, plastic and drying shrinkage, thermal expansion coefficient for shrinkage properties, durability performance, permeability, repeated freezing and thawing, and resistance of chemical solution test were performed. Test results showed that the latex modified repair mortar indicated the shrinkage amount which the delamination does not happen, and the latex modified repair mortar appeared excellent long-term durability performance which can increase the service life.

Impact Behavior Analysis on Composite Laminate with Damages (손상이 있는 복합적층판의 충격거동 해석)

  • Kim, Sung-Joon;Hong, Chang-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.1
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    • pp.22-28
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    • 2010
  • To detect the damage in composite structure, nondestructive evaluation techniques are widely used. Tapping test is perhaps the most common technique used for the detection of damage in composite laminates. The method is accomplished by tapping the inspection area with light hammer-like device. The tapping test has the ability that indicates damages in a structure due to a localized change of stiffness. The change in vibration signature may be detected by measurement of the dynamic contact force during impact. In this study, it has been shown that the characteristics of impact force histories from a structure during tapping are changed by the presence of damage such as surface crack and delamination. And impact response analysis has been performed on composite rotor blade with crack to investigate the effect of damage.

Dynamic Characteristics of Laminated Composite Structures for High-Performance Disaster Prevention of Gyeongbuk Infrastructures (경북기반시설의 고성능 방재를 위한 복합소재 적층구조의 동적특성)

  • Lee, Sang-Youl
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.3
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    • pp.1352-1358
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    • 2012
  • The dynamic analysis of delaminated composite structures is carried out based on the higher order plate theory. In the finite element (FE) formulation, the seven degrees of freedom per each node are used with transformations in order to fit the displacement continuity conditions at the delamination region. The boundaries of the instability regions are determined using the method proposed by Bolotin. The numerical results obtained for skew plates are in good agreement with those reported by other investigators. The new results for delaminated skew plate structures in this study mainly show the effect of the interactions between the geometries and other various parameters.

Bonding Performance of Glulam Reinforced with Textile Type of Glass- and Aramid-Fiber, GFRP and CFRP

  • Kim, Keon-Ho;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.2
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    • pp.156-162
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    • 2011
  • To evaluate the bonding performance of reinforced glulam, the textile type of glass fiber and aramid fiber, and the sheet type of glass fiber reinforced plastic (GFRP) and carbon fiber reinforced plastic (CFRP) were used as reinforcements. The reinforced glulam was manufactured by inserting reinforcement between the outmost and middle lamination of 5ply glulam. The types of adhesives used in this study were polyvinyl acetate resins (MPU500H, and MPU600H), polyurethane resin and resorcinol resin. The block shear strengths of the textile type in glass fiber reinforced glulam using MPU500H and resorcinol resin were higher than 7.1 N/$mm^2$, and these glulams passed the wood failure requirement of Korean standards (KS). In case of the sheet types, GFRP reinforced glulams using MPU500H, polyurethane resin and resorcinol resin, and CFRP reinforced glulams using MPU500H and polyurethane resin passed the requirement of KS. The textile type of glass fiber reinforced glulam using resorcinol resin after water and boiling water soaking passed the delamination requirement of KS. The only GFRP reinforced glulam using MPU500H after water soaking passed the delamination requirement of KS. We conclude that the bonding properties of adhesive according to reinforcements are one of the prime factors to determine the bonding performance of the reinforced glulam.

Low-velocity Impact Damage of a Thick Graphite/Epoxy Case (Graphite/Epoxy로 만든 두꺼운 관의 저속 충격손상에 관한 연구)

  • 김형원;윤영주;나성엽
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.2
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    • pp.31-38
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    • 2000
  • Pressure vessels by composite materials were damaged sometimes during manufacturing or assembling. The state and the size of damage by low-velocity tests were investigated in this paper. Impactors of various masses and various tup shapes were dropped freely in the range of 120mm height to 700mm height. Compared with hemispherical tup of 12.7mm diameter, for hemispherical tup of 25.4mm diameter the size of surface dent was smaller but the size of delamination was bigger.

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Progressive failure of symmetrically laminated plates under uni-axial compression

  • Singh, S.B.;Kumar, Ashwini;Iyengar, N.G.R.
    • Structural Engineering and Mechanics
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    • v.5 no.4
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    • pp.433-450
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    • 1997
  • The objective of this work is to predict the failure loads, associated maximum transverse displacements, locations and the modes of failure, including the onset of delamination, of thin, flat, square symmetric laminates under the action of uni-axial compression. Two progressive failure analyses, one using Hashin criterion and the other using Tensor polynomial criteria, are used in conjunction with the finite element method. First order shear deformation theory and geometric nonlinearity in the von Karman sense have been employed. Five different types of lay-up sequence are considered for laminates with all edges simply supported. In addition, two boundary conditions, one with all edges fixed and other with mixed boundary conditions for $(+45/-45/0/90)_{2s}$ quasi-isotropic laminate have also been considered to study the effect of boundary restraints on the failure loads and the corresponding modes of failure. A comparison of linear and nonlinear results is also made for $({\pm}45/0/90)_{2s}$ quasi-isotropic laminate. It is observed that the maximum difference between the failure loads predicted by various criteria depend strongly on the laminate lay-ups and the flexural boundary restraints. Laminates with clamped edges are found to be more susceptible to failure due to the transverse shear and delamination, while those with the simply supported edges undergo total collapse at a load slightly higher than the fiber failure load.

Stundy on Simulation Characteristics of Low Velocity Impact Test of Carbon/Epoxy Composite Plates Manufactured by Filament Winding Method (필라멘트 와인딩 공법으로 제작한 탄소섬유/에폭시 복합소재 평판의 저속 낙하 충격시험 시뮬레이션에 관한 연구)

  • BYUN, JONGIK;KIM, JONGLYUL;HEO, SEOKBONG;KIM, HANSANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.2
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    • pp.190-196
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    • 2018
  • Carbon fiber/epoxy composites are typical brittle materials and have low impact properties. Recently, it is important to investigate impact characteristics of carbon fiber composites because of increasing use as automobile parts and high pressure hydrogen vessels of fuel cell electric vehicles for light weight. In this study, the low velocity impact properties of carbon fiber/epoxy composites fabricated by a filament winding method are studied. The low velocity impact properties were measured by performing tests according to ASTM D7136. The low velocity impact simulations were carried out using commercial structural analysis software, Abaqus. The absorbed energy and the delamination shapes were compared between the experimental and simulation results. The numerical analysis method showed that the absorbed energy decreased with the reduced number of cohesive elements in the composite models.

Mechanical Properties of Carbon/Phenolic Ablative Composites (Carbon/Phenolic 내열 복합재료의 기계적 특성)

  • Kim, P.W.;Hong, S.H.;Kim, Y.C.;Yeh, B.H.;Jung, B.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.160-163
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    • 1999
  • The mechanical properties and failure behaviour of carbon/phenolic composites were inverstigated by tension and compression. Carbon/phenolic composites were fabricated by infiltration of matrix into 8 harness satin woven fabric of PAN-based carbon fibers. The tensile and compressive tests were performed at 25℃ under air atmosphere and, at 400℃ and 700℃ under N₂ atmosphere. The tensile strengths of carbon/phenolic composites in with-laminar/0° warp direction were about 10 times higher than those in with-laminar/45° warp direction, which was analyzed due to a change of fracture mode from fiber pull-out by shear to tensile fracture of fibers. The fracture of carbon/phenolic composites in with-laminar/45° direction was analyzed due to delamination by buckling. Tensile and compressive strength of carbon/phenolic composites decreased to about 50% at 400℃, and to about 10% at 700℃ compared to that at room temperature. The main reason for the decrease of tensile or compressive strength with increasing temperature was analyzed due to a reduction of bond strength between fibers and matrix resulting from thermal degradation of phenolic resin.

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Damage propagation in CFRP laminates subjected to low velocity impact and static indentation

  • Aoki, Yuichiro;Suemasu, Hiroshi;Ishikawa, Takashi
    • Advanced Composite Materials
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    • v.16 no.1
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    • pp.45-61
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    • 2007
  • This paper describes a damage accumulation mechanism in cross-ply CFRP laminates $[0_2/90_2]_{2S}$ subjected to out-of-plane loading. Drop-weight impact and static indentation tests were carried out, and induced damage was observed by ultrasonic C-scan and an optical microscope. Both tests gave essentially the same results for damage modes, sizes, and load-deformation history. First, a crack occurred in the bottom $0^{\circ}$ layer accompanying some delamination along the crack caused by bending stress. Then, transverse cracks occurred in the middle $90^{\circ}$ layer with decreasing contact force between the specimen and the indenter. Measured local strains near the impact point showed that the stress state changed from a bending dominant state to an in-plane tensile dominant state. A cohesive interface element was used to simulate the propagation of multiple delaminations and transverse cracks under static indentation. Two types of analytical models are considered, one with multiple delaminations and the other with both multiple delaminations and transverse cracks. The damage obtained for the model with only multiple delaminations was quite different from that obtained from the experiment. However, the results obtained from the model with both delaminations and transverse cracks well explain the characteristics of the damage obtained in the experiment. The existence of the transverse cracks is essential to form the characteristic impact damage.