• Title/Summary/Keyword: deinked pulp

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Enzymatic Deinking of Old Newsprit with Alkalophilic Enzymes from Coprinus cinereus 2249

  • Lee, Jung-Myong;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.5
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    • pp.12-17
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    • 1999
  • This study was to evaluate applications of the alkalophilic enzymes from Coprinus cinereus 2249 with old newsprint(ONP). A enzymatic deinking process based on alkalopholic enzymes was investigated . It was found that alkalophilic enzymes could effectively deink old newsprint. When applied on deinking of the old newsprint, it increases the freeness and brightness due to effect of hydrolysis at 0.1% enzyme concentration . Also, the physical properties of deinked pulp were improved.

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The effect of bleaching reagents on bleachabilities of DIP and environmental loads (탈묵펄프용 표백약품에 따른 표백 특성 및 표백폐수의 환경부하 영향)

  • Ahn, Chi-Deuk;Park, Jung-Yoon;Hwang, Sung-Jun;Hong, Seok-Jun;Lee, Jin-Hee;Kim, Hyoung-Jin;Chung, Sung-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.66-74
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    • 2015
  • DIP(deinked pulp) was bleached by FAS, $Na_2S_2O_4$ and $H_2O_2$, which are widely used in DIP bleaching process, in order to improve optical properties of DIP, and the bleaching efficiencies of DIP and environmental loads of waste water were compared, depending on bleaching chemical dosages. With the application of different bleaching chemicals, some positive improvements were shown in optical and physical properties of bleached pulp. However, the physical properties of bleached DIP and their characteristics of wastewater were remarkably different, depending on dosages and bleaching reagents. DIP chemicals with FAS and $Na_2S_2O_4$ have higher improvement in optical and physical properties than $H_2O_2$. Also, environmental loads such as pH, turbidity, SCODcr and cationic demand were decreased in reductive bleaching process. Despite of higher effectiveness of reductive bleaching process, there were some environmental problems caused by sulfur ions from FAS and $Na_2S_2O_4$. With the method of sulfur ion controls, it would be more effective than $H_2O_2$ bleaching process.

Influence of Conductivity and Anionic Trashes on Adsorption Behavior of Cationic Starches (전기전도도와 음이온성 트래쉬에 따른 양상전분의 흡착 거동변화)

  • 허동명;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.10-18
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    • 1999
  • The influence of simple electrolyte or anionic trashes on cationic starch adsorption was examined using deinked pulp and bleached thermomechniical pulp. Adsorbed amounts of cationic starches increased slightly , then decreased abruptly as the concentration of simple electrolyte increased. This phenomenon was discussed based on the compression of electrical double layer and conformation change of starch molecules. Also, the effect of the type of simple electrolytes on starch adsorption was examined and discussed. Addition of sodium slilicate increased starch adsorption since it increased surface charge density of fibers. On the other hand, addition of kraft lignin decreased cationic demand of the pulp slurries and adsorbed amounts of cationic starches. Nonionic surfactant did not show any significant effect on the cationic demand of pulp slurries. When simple electrolytes were added to the stock , grater adsorption or cationic starches was obtained with starches of lower degree of substitution . On t도 other hand, amount of adsorbed starches decreased for lower DS starches when the concentration of anionic trashes increased.

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Neutral Deinking of Old Newsprints Contaminated with Flexo Ink

  • Hoon Ryu;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.5
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    • pp.10-16
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    • 2003
  • Presence of small amount of old newspapers printed with waterbased flexographic inks leads to a significant loss of brightness of the deinked pulp by flotation process. Recently there has been an increased interests in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. Effects of the deinking processes on pulp quality and white water characteristics were examined. It was shown that neutral deinking would provide significant improvement in brightness, yield, and freeness as compared with conventional alkaline deinking. There was no increase in brightness when OMG was added in the furnish up to 20 %, and it was attributed to the redeposition of flexo inks on chemical pulp fibers.

NEUTRAL DEINKING OF OLD NEWSPRINTS CONTAMINATED WITH FLEXO INK

  • Hoon Ryu;Lee, Hak-Lae
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.343-348
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    • 1999
  • Presence of small amount of old newspapers printed with waterbased flexographic inks leads to a significant loss of brightness of the deinked pulp by flotation process. Recently there has been an increased interests in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. Effects of the deinking processes on pulp quality and white water characteristics were examined. It was shown that neutral deinking would provide significant improvement in brightness, yield, and freeness as compared with conventional alkaline deinking. Three was no increase change in brightness when OMG was added in the furnish up to 20%, and it was attributed to the redeposition of flexo inks on chemical pulp fibers.

Effect of Ozonation Consistency on the Ink Removal Efficiency and Pulp Characteristics (오존 처리농도가 ONP의 탈묵 효율 및 펄프 특성에 미치는 영향)

  • 조병묵;원종명
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.18-23
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    • 2001
  • The effect of pulp consistency on the deinking properties in the ozone deinking of ONP was investigated in order to develop the environmentally friendly deinking method. The pulp consistency and ozone treatment time were varied for this purpose. Higher pulp consistency during ozone treatment gave better ink removal efficiency than the conventional deinking method. In was also found that the increase of pulp consistency can decrease the ozone treatment time which can meet the deinking quality. WRV of ozone deinked pulp obtained at 10% and 30% of pulp consistencies was lower than those of the conventional deinking method. However, the higher pulp consistency during ozone treatment improved WRV. Highest brightness was obtained at the ozone treatment condition of 30% pulp consistency and 10 minutes. The lower brightness at the other ozone treatment condition should be originated from the excessive decrease of ink particle size and then decrease of true ink removal efficiency. Scott bond was increased with the increase of pulp consistency and treatment time. However, the improvement of breaking length with ozone treatment was no significant.

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Comparison between PY and YP on Bleach Efficiency of White Ledger according to Deinking Method (탈묵방법에 따른 백상폐지의 표백효율에 미치는 PY와 YP간의 비교)

  • 백기현;안병준
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.37-43
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    • 2001
  • The bleach efficiency between PY and YP bleaching of pulps, which were deinked in neutral (cellulase) and alkaline (NaOH, NaOH/${Na_2}{SiO_3}$) ranges, and were treated on kneader, was compared in this study. The brightness of pulps (84.8~88.4% ISO) which were deinked in alkaline or neutral ranges increased up to 88.4%~88.8% ISO after PY or YP bleaching. There was no difference in the brightness between PY and YP bleaching. And the dirt count of bleached pulps was similar each other at the range of 17~38 ppm. The tensile index of bleached pulps was slightly higher in PY bleaching than those in YP bleaching. While with the treatment of kneading, the brightness and dirt count decreased remarkably compared to those of no-kneading. However, the sharp difference in the brightnesses or in dirt count of bleached pulps decreased after bleaching. The brightness of bleached pulps at YP stages was only numberically higher than those at PY stages without regard to the treatment of kneading. Therefore, in the case of the neutral deinkiing process, the conversion of PY bleaching stages to YP bleaching stages was profitable to water loop system, and was harmless in the aspect of the bleach efficiency.

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The Preparation of CarboxymethylCellulose from Recycled Fiber(I) -The Reactivity in Carboxymethylation of Recycled Fiber- (재생(再生)펄프를 이용(利用)한 카르복시메틸세룰로오스의 제조(製造)(I) -재생(再生)펄프의 Carboxymethylation반응성(反應性)을 중심(中心)으로-)

  • Choi, Jeong-Heon;Jo, Byoung-Muk;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.1
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    • pp.59-64
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    • 1993
  • The purpose of this study is to investigate the preparation of the carboxymethylcellulose from recycled fiber, especially on the reactivity of carboxymethylation. Using a deinked pulp and a dissolving pulp. Green's method is adapted to the carboxymethylation. We conformed that the carboxymethyl group is led for recycled fiber by FT-IR analysis. The recycled fiber is more reactive than the dissolving pulp because the recycled fiber had been defiberated and pretreated with alkali. It suggests that deinking process is in accordance with pretreatment of CMC process. Therefore, it may be possible to prepare CMC from the recylced fiber economically.

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Neutral Deinking of Old Newsprints Contaminated with Flexo Ink -Evaluation of the Deinking Efficiency of Two Neutral Deinking Agents- (플렉소 잉크가 포함된 신문고지의 중성 탈묵 -중성 탈묵제의 효율 평가-)

  • Lee, Hak-Lae;Ryu, Hoon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.1
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    • pp.8-15
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    • 2001
  • Presence of small amount of old newsprints printed with waterbased flexographic inks leads to a significant loss brightness of the deinked pulp by flotation process. Recently there has been an increased interest in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. It was shown that neutral deinking provides significant improvements in brightness, yield and freeness as compared with alkaline deinking. Flotation efficiency was different depending upon the type of surfactants used in neutral deinking. The result of this study showed that alcohol type surfactant is superior to fatty acid type surfactant in neutral deinking efficiency.

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RECYCLING OF WASTEPAPER WITH ALKALINE ENZYME FROM COPRINACEAE SP.

  • Eom, Tae-Jin;Lee, Jung-Myoung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.291-295
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    • 1999
  • Coprinus cinereus 2249 that is a kind of basidiomycetes constitutively produced alkaline carboxymethyl cellulase (CMCase), filter paper cellulase (FPase) and xylanase. Crude enzymes prepared with optimal conditions showed higher FPase activity than CMCase activity. The FPase was most active at pH 9 at 50$^{\circ}C$. When applied on deinking of the old newsprint (ONP), it increases the freeness and brightness due to effect of hydrolysis at 0.1% enzyme concentration. Also, The physical properties of deinked pulp were improved.