• Bulletin of the Korean Chemical Society
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• v.23 no.5
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• pp.721-726
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• 2002

Two new C2-symmetric chiral $\alpha-$ and w-Diimines incorporating bulky ferrocenylethylamine and their copper(I)complexes have been synthesized and characterized by analytical and various spectroscopic techniques. The catalytic activities of these complexes have been tested in the asymmetric cyclopropanation of a series of olefins with some diazoacetates to achieve varying degree of dia- and enantio-selectivities depending on the nature of the ligand, the substrates, and the reagents. Some mechanistic implication has been made with regard to the interactions among all these chemical species.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.30 no.3
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• pp.432-441
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• 1997

Stomach contents of fat greenling, Hexagrammos otakii were analyzed to understand feeding ecology of the fish in the coastal waters, Shinsudo, Sarhon. Specimens were collected by angling and by gill net from February 1984 to September 1985. The fish consisted of 4 age groups from 0 to 3. The food items of the fish changed slightly by seasons and with growth of the fish. Main preys were copepods, gammarids and caprellids for the fish of age group 0, gammarids and caprellids for age group 1, and brachyurans and carideans for age group 2 and 3. The prey composition of the fish were more varied by seasons than by ages. Food items was not different between male and female of the fish. The fish positively selected for gammarids, polychaetes and brachyurans, but negatively selected for gastropods. The degree of selectivities for the other preys were changed with growth. As the fish grows it consumed larger preys in case of small preys such as gammarids and caprellids, however, it did not consumed larger preys beyond an optimal size in case of large preys such as sphaeromids, brachyurans and polychaetes.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.104-104
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• 2009

Critical dimensions has rapidly shrunk to increase the degree of integration and to reduce the power consumption. However, it is accompanied with several problems like direct tunneling through the gate insulator layer and the low conductivity characteristic of poly-silicon. To cover these faults, the study of new materials is urgently needed. Recently, high dielectric materials like $Al_2O_3$, $ZrO_2$ and $HfO_2$ are being studied for equivalent oxide thickness (EOT). However, poly-silicon gate is not compatible with high-k materials for gate-insulator. To integrate high-k gate dielectric materials in nano-scale devices, metal gate electrodes are expected to be used in the future. Currently, metal gate electrode materials like TiN, TaN, and WN are being widely studied for next-generation nano-scale devices. The TaN gate electrode for metal/high-k gate stack is compatible with high-k materials. According to this trend, the study about dry etching technology of the TaN film is needed. In this study, we investigated the etch mechanism of the TaN thin film in an inductively coupled plasma (ICP) system with $O_2/BCl_3/Ar$ gas chemistry. The etch rates and selectivities of TaN thin films were investigated in terms of the gas mixing ratio, the RF power, the DC-bias voltage, and the process pressure. The characteristics of the plasma were estimated using optical emission spectroscopy (OES). The surface reactions after etching were investigated using X-ray photoelectron spectroscopy (XPS) and auger electron spectroscopy (AES).

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.250-251
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• 2009

For the fabrication of a multilevel resist (MLR) based on a very thin amorphous carbon (a-C) layer an $Si_{3}N_{4}$ hard-mask layer, the selective etching of the $Si_{3}N_{4}$ layer using physical-vapor-deposited (PVD) a-C mask was investigated in a dual-frequency superimposed capacitively coupled plasma etcher by varying the following process parameters in $CH_{2}F_{2}/H_{2}/Ar$ plasmas : HF/LF powr ratio ($P_{HF}/P_{LF}$), and $CH_{2}F_{2}$ and $H_2$ flow rates. It was found that infinitely high etch selectivities of the $Si_{3}N_{4}$ layers to the PVD a-C on both the blanket and patterned wafers could be obtained for certain gas flow conditions. The $H_2$ and $CH_{2}F_{2}$ flow ratio was found to play a critical role in determining the process window for infinite $Si_{3}N_{4}$/PVDa-C etch selectivity, due to the change in the degree of polymerization. Etching of ArF PR/BARC/$SiO_x$/PVDa-C/$Si_{3}N_{4}$ MLR structure supported the possibility of using a very thin PVD a-C layer as an etch-mask layer for the $Si_{3}N_{4}$ layer.

• Journal of KIISE:Databases
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• v.29 no.3
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• pp.180-192
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• 2002

We investigate the effect of the data skew of join attributes on the performance of a pipelined multi-way hash join method, and propose two new harsh join methods in the shared-nothing multiprocessor environment. The first proposed method allocates buckets statically by round-robin fashion, and the second one allocates buckets dynamically via a frequency distribution. Using harsh-based joins, multiple joins can be pipelined to that the early results from a join, before the whole join is completed, are sent to the next join processing without staying in disks. Shared nothing multiprocessor architecture is known to be more scalable to support very large databases. However, this hardware structure is very sensitive to the data skew. Unless the pipelining execution of multiple hash joins includes some dynamic load balancing mechanism, the skew effect can severely deteriorate the system performance. In this parer, we derive an execution model of the pipeline segment and a cost model, and develop a simulator for the study. As shown by our simulation with a wide range of parameters, join selectivities and sizes of relations deteriorate the system performance as the degree of data skew is larger. But the proposed method using a large number of buckets and a tuning technique can offer substantial robustness against a wide range of skew conditions.

• The KIPS Transactions:PartD
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• v.9D no.5
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• pp.755-768
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• 2002

We investigate the effect of the data skew of join attributes on the performance of a pipelined multi-way hash join method, and propose two new hash join methods with load balancing capabilities. The first proposed method allocates buckets statically by round-robin fashion, and the second one allocates buckets adaptively via a frequency distribution. Using hash-based joins, multiple joins can be pipelined so that the early results from a join, before the whole join is completed, are sent to the next join processing without staying on disks. Unless the pipelining execution of multiple hash joins includes some load balancing mechanisms, the skew effect can severely deteriorate system performance. In this paper, we derive an execution model of the pipeline segment and a cost model, and develop a simulator for the study. As shown by our simulation with a wide range of parameters, join selectivities and sizes of relations deteriorate the system performance as the degree of data skew is larger. But the proposed method using a large number of buckets and a tuning technique can offer substantial robustness against a wide range of skew conditions.

• Clean Technology
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• v.13 no.1 s.36
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• pp.54-63
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• 2007

Even traces of CO in the hydrogen-rich feed gas to proton exchange membrane fuel cells (PEMFC) poison the platinum anode electrode and dramatically decrease the power output. In this work, a variety of catalytic materials consisting of $Cu/Ce_xZr_{1-x}O_2$, (x = 0.0-1.0) were synthesised, characterized and tested for CO oxidation and preferential oxidation of CO (PROX). These catalysts prepared by hydrothermal and deposition-precipitation methods. The catalysts were characterized by XRD, XRF, SEM, BET, $N_2O$ titration and oxygen storage capacity (OSC) measurement. The effects of composition of the support and degree of excess oxygen were investigated fur activity and $CO_2$ selectivity with different temperatures. The composition of the support markedly influenced the PROX activity. Among the various $Cu/Ce_xZr_{1-x}O_2$ catalysts having different composition, $Cu/Ce_{0.9}Zr_{0.1}O_2$ and $Cu/Ce_{0.7}Zr_{0.3}O_2$ showed the highest activities (>99%) and selectivities (ca.50%) in the temperature range of $150{\sim}160^{\circ}C$. It was found that by using of $Ce_xZr_{1-x}O_2$ mixed oxide support which possesses a high oxygen storage capacity, oxidation-reduction activity of Cu-based catalyst was improved, which resulted in the increase of catalytic activity and selectivity of CO oxidation in excess $H_2$ environments.