• 제목/요약/키워드: degree of conversion

검색결과 351건 처리시간 0.025초

High Alloying Degree of Carbon Supported Pt-Ru Alloy Nanoparticles Applying Anhydrous Ethanol as a Solvent

  • Choi, Kwang-Hyun;Lee, Kug-Seung;Jeon, Tae-Yeol;Park, Hee-Young;Jung, Nam-Gee;Chung, Young-Hoon;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • 제1권1호
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    • pp.19-24
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    • 2010
  • Alloying degree is an important structural factor of PtRu catalysts for direct methanol fuel cells (DMFC). In this work, carbon supported PtRu catalysts were synthesized by reduction method using anhydrous ethanol as a solvent and $NaBH_4$ as a reducing agent. Using anhydrous ethanol as a solvent resulted in high alloying degree and good dispersion. The morphological structure and crystallanity of synthesized catalysts were characterized by X-ray diffraction (XRD), high resolution transmission electron microscope (HR-TEM). CO stripping and methanol oxidation reaction were measured. Due to high alloying degree catalyst prepared in anhydrous ethanol, exhibited low onset potential for methanol oxidation and negative peak shift of CO oxidation than commercial sample. Consequently, samples, applying ethanol as a solvent, exhibited not only enhanced CO oxidation, but also increased methanol oxidation reaction (MOR) activity compared with commercial PtRu/C (40 wt%, E-tek) and 40 wt% PtRu/C prepared in water solution.

Preparation of Modified Hollow Polypropylene Membrane and Their Adsorption Properties of ${\gamma}$-Globulins

  • Hwang, Taek-Sung;Park, Jin-Won
    • Macromolecular Research
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    • 제11권5호
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    • pp.347-351
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    • 2003
  • The hydrophobic ligand-containing hollow polypropylene (PP) membranes were synthesized by the mutual radiation induced graft copolymerization with glycidylmethacrylate (GMA) onto hollow PP membrane followed by the subsequent functionalization with L-phenylalanine. FT-IR, elemental analysis and UV spectroscopy were utilized to characterize copolymer composition, and degree of grafting, functionalization conversion and ${\gamma}$-globulins adsorption. The degree of grafting on the PP surface increased with the reaction time and total dose of E-beam. In the subsquent functionalization, the amount of L-phenylalanine increased with the increase in the degree of grafting and the degree of conversion was about 30%. The ${\gamma}$-globulins adsorption experiments showed that adsorption capacity had a maximum value at pH 8. The ${\gamma}$-globulins adsorption capacity in the basic pH region was higher than in the acidic pH region.

저점도 및 고점도 Bulk-fill Giomer 복합레진과 Bulk-fill 복합레진의 전환율과 중합수축 (Degree of Conversion and Polymerization Shrinkage of Low and High Viscosity Bulk-Fill Giomer-based and Resin-based composites)

  • 김희라;이제식;김현정;권태엽;남순현
    • 대한소아치과학회지
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    • 제46권1호
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    • pp.1-9
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    • 2019
  • 이번 연구에서는 저점도 및 고점도 bulk-fill giomer 복합레진의 전환율과 중합수축을 기존 bulk-fill 복합레진 및 전통적 복합레진과 비교 평가해보고자 하였다. Bulk-fill giomer 복합레진 2종류(Beautifil Bulk Restorative(BBR), Beautifil Bulk Flowable(BBF)), bulk-fill 복합레진 2종류(Tetric N-Ceram Bulk-fill(TBF), SureFil SDR flow(SDR)), 전통적 복합레진 2종류(Tetric N-Ceram(TN), Tetric N-flow(TF))를 사용하였다. 중합도 측정은 Fourier transform infrared spectroscopy을 사용하였으며, 중합수축은 linometer을 이용하여 측정하였다. 복합레진 하면의 전환율 측정 결과 2 mm와 4 mm 깊이 모두 BBR에서 가장 낮게 나왔으며, SDR에서 가장 높게 나왔다. 4 mm 깊이에서 고점도 및 저점도 bulk-fill giomer 복합레진의 전환율은 bulk-fill 복합레진에 비해 유의하게 낮은 값을 보였다(p < 0.05). 깊이에 따른 전환율 비교 시 TBF, TN, TF는 유의차를 보였으며(p < 0.05), BBR, BBF, SDR는 유의차를 보이지 않았다. 중합수축은 TF > SDR > BBF > TBF > TN, BBR 순서로 감소 했으며(p < 0.05), bulk-fill giomer 복합레진은 bulk-fill 복합레진보다 낮은 중합수축량을 보였다(p < 0.05). 이번 연구 결과 4 mm 깊이에서 bulk-fill giomer 복합레진 및 TBF는 불충분한 중합을 나타냈으며, 2 mm와 4 mm 모두에서 고점도 및 저점도 bulk-fill giomer 복합레진은 bulk-fill 복합레진에 비해 낮은 전환율을 보였다. 그러므로 bulk-fill giomer 복합레진의 임상적인 적용을 위해서는 이에 대한 충분한 고찰 및 주의가 필요할 것으로 생각된다.

A Study on Projection Conversion for Efficient 3DoF+ 360-Degree Video Streaming

  • Jeong, Jong-Beom;Lee, Soonbin;Jang, Dongmin;Kim, Sungbin;Lee, Sangsoon;Ryu, Eun-Seok
    • 방송공학회논문지
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    • 제24권7호
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    • pp.1209-1220
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    • 2019
  • The demand for virtual reality (VR) is rapidly increasing. Providing the immersive experience requires much operation and many data to transmit. For example, a 360-degree video (360 video) with at least 4K resolution is needed to offer an immersive experience to users. Moreover, the MPEG-I group defined three degrees of freedom plus (3DoF+), and it requires the transmission of multiview 360 videos simultaneoulsy. This could be a burden for the VR streaming system. Accordingly, in this work, a bitrate-saving method using projection conversion is introduced, along with experimental results for streaming 3DoF+ 360 video. The results show that projection conversion of 360 video with 360lib shows a Bjontegaard delta bitrate gain of as much as 11.4%.

레진 모노머의 중합전환률 증가를 위한 3종 중합개시 시스템의 적정 비율 (Optimal combination of 3-component photoinitiation system to increase the degree of conversion of resin monomers)

  • 김창규;문호진;신동훈
    • Restorative Dentistry and Endodontics
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    • 제36권4호
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    • pp.313-323
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    • 2011
  • 연구목적: 여러 가지 문제점을 가지고 있는 기존의 중합개시제인 CQ와 새로운 개시제인 p-octyloxy-phenyl-phenyl iodonium hexafluoroantimonate (OPPI), 중합촉진제인 지방족 아민(DMAEMA)을 포함한 3종 중합개시시스템을 함유한 레진 모노머의 중합전환률을 증진시키기 위한 각각의 조성 비율을 알아보고 중합개시제와 중합촉진제의 비율에 따른 영향을 분석하고자 하였다. 연구 재료 및 방법: BisGMA/BisEMA/TEGDMA 조성의 레진 모노머를 제조한 다음 다양한 농도 조합의 CQ, OPPI, DMAEMA를 혼합하였다. 각각의 물질을 0.2 wt.% (저농도, L), 1.0 wt.% (중간농도, M), 2.0 wt.% (고농도, H)의 3가지 농도로 혼합하였으며, 그 농도 비율에 따라 9개의 실험군으로 제작하였다: LLL, LMM, LHH, MLM, MMH, MHL, HLH, HML, HHM (CQ-OPPI-DMAEMA의 농도) 중합 시스템이 함유된 각각의 레진 모노머를 NaCl disk에 압착한 다음 Demetron 400 광중합기를 이용하여 5초, 20초, 40초, 60초, 300초 동안 광중합 하였으며, FTIR로 전환률(Degree of Conversion, DC)을 측정하였다. 조성비율은 ANOVA와 Duncan 사후검정법을 이용하였으며 중합개시제와 중합촉진제의 비율이 같은 실험군들의 상호비교에는 T-검정도 시행하였다. 결과: 중합개시시스템을 이루는 조성들의 농도 조합에 따라 중합전환률의 차이를 보였으며, MMH 군과 HHM 군이 높은 초기 중합전환률을 보였다. 중합개시제(CQ, OPPI)와 중합촉진제인 DMAEMA의 비율에 따른 중합전환률의 차이를 보이지 않았으며, CQ의 농도는 전환률에 영향을 주지 않은 반면, OPPI의 농도는 전환률에 영향을 미쳤다. 결론: 중합전환률이 높으며 밝은 색상이 필요한 경우에는 MMH 조합을, 짙거나 불투명한 경우에는 MMH 조합이 추천된다.

CB(전환사채)의 투자효율성에 관한 실증연구 (A Study on the Investment Efficiency of CB(Convertible Bond))

  • 김선제
    • 서비스연구
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    • 제10권4호
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    • pp.71-88
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    • 2020
  • CB(전환사채)는 주식전환권을 행사한 이후부터는 채권이 아닌 주식으로 변한다는 점에서 채권과 주식의 성격을 갖고 있는 메자닌 증권이다. 본 연구는 투자자 입장에서 CB의 투자효율성 정도를 실증규명하고 효율적인 투자방안을 제시하는 것이 연구목적이다. 연구방법은 CB종목별로 표면이자율, 만기이자율, 채권만기일, 전환가격, 전환청구일 등을 조사한 후, 전환청구일 이후 발행회사의 일별 주가변동과 연결하여 CB에 대한 투자의 효율성과 CB의 주식전환효과가 어느 정도인지를 계량적으로 파악하고자 하였다. 연구 결과, 전환가격초과일수비율이 전환 가능한 날짜의 1/4 정도에 불과하여 투자효율성은 낮은 것으로 분석되었다. 전환일수익률은 평균 -6.3%, 만기일수익률은 평균 -5.2%여서 평균적으로 minus 수익률을 보여 투자자 기대와 다르게 산출되었다. 전환일수익률이 minus인 종목수가 plus인 종목수보다 2.4배 많았으며, 만기일수익률이 minus인 종목수가 plus인 종목수보다 3.7배 많아서 CB의 주식전환 기대수익률은 낮은 것으로 분석되었다. 연구기여도는 CB의 기대수익률이 높지 않다는 문제점을 도출하였고, 투자자 입장에서 CB를 매입할 때 유의사항을 정립한 데 있다.

A Performance Consideration on Conversion Loss in the Integrated Single Balanced Diode Mixer

  • Han, Sok-Kyun;Kim, Kab-Ki
    • Journal of information and communication convergence engineering
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    • 제1권3호
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    • pp.139-142
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    • 2003
  • In this paper, we consider the factors that affect a conversion loss performance in designing a single balanced diode mixer integrated with IRF(Image Reject Filter), based on the embedded electrical wavelength placed between the IRF and mixer, diode matching and LO drive amplifier. To evaluate the conversion loss performance, we suggest two types of a single balanced mixer using 90 degree branch line coupler, microstrip line and schottky diode. One is only mixer and the other is integrated with IRF and LO drive amplifier. The measured results of a single balance diode mixer integrated IRF show the conversion loss of 8.5 dB and the flatness of 1 dB p-p from 21.2 GHz to 22.6 GHz with 10 dBm LO. The measured input PI dB and IIP3 are 7 dBm and 15 dBm respectively under the nominal LO power level of 10dBm. The LO/RF and LO/IF isolation are 22 dB and 50 dB, respectively.

광원의 종류에 따른 복합레진의 중합거동 및 중합률에 관한 연구 (THE POLYMERIZATION RATE AND THE DEGREE OF CONVERSION OF COMPOSITE RESINS BY DIFFERENT LIGHT SOURCES)

  • 류주희;이인복;유현미;김미자;석창인;권혁춘
    • Restorative Dentistry and Endodontics
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    • 제29권4호
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    • pp.386-398
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    • 2004
  • Objectives: The purpose of this study was to observe the reaction kinetics and the degree of polymerization of composite resins when cured by different light sources and to evaluate the effectiveness of the blue Light Emitting Diode Light Curing Units (LED LCUs) compared with conventional halogen LCUs. Materials and Methods: First, thermal analysis was performed by a differential scanning calorimeter (DSC). The LED LCU (Elipar Freelight, $320{\;}mW/\textrm{cm}^2$) and the conventional halogen LCU (XL3000, $400{\;}mV/\textrm{cm}^2$) were used in this study for curing three composite resins (SureFil, Z-250 and AEliteFLO). Second. the degree of conversion was obtained in the composite resins cured according to the above curing mode with a FTIR. Third, the measurements of depth of cure were carried out in accordance with ISO 4049 standards. Statistical analysis was performed by two-way ANOVA test at 95% levels of confidence and Duncan's procedure for multiple comparisons. Results: The heat of cure was not statistically different among the LCUs (p > 0.05). The composites cured by the LED (Exp) LCUs were statistically more slowly polymerized than by the halogen LCU and the LED (Std) LCU (p < 0.05). The composite resin groups cured by the LED (Exp) LCUs had significantly greater degree of conversion value than by the halogen LCU and the LED (Std) LCU (p =0.0002). The composite resin groups cured by the LED (Std) LCUs showed significantly greater depth of cure value than by the halogen LCU and the LED (Exp) LCU (p < 0.05).

Evaluation of Spin Direction in Ferrite-Plated Films by $Fe^{57}$ Conversion Electron Mossbauer Spectroscopy

  • Shirasaki, Fumio;Kitamoto, Yoshitaka;Kantake, Shusuke;Abe, Masanori
    • The Korean Journal of Ceramics
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    • 제6권4호
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    • pp.405-407
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    • 2000
  • Polycrystalline films of Ni- and Co-ferrites films are prepared from aqueous solution at $90^{\circ}C$ by ferrite plating, which are subjected to Fe$^57$ conversion electron Mossbauer spectroscopy in backscatter mode. The average angle of Fe spins relative to the film plane is evaluated as 18 degree and 82 degree for the Ni- and Co-ferrite films, respectively, indicating a prominent magnetic anisotropy parallel and perpendicular to the film plane. It was also verified by the magnetization measurements.

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Dentin shear bond strength and degree of conversion of the dentin bonding agents irradiated with light emitting diode

  • Kim, Sun-Young;Um, Chung-Moon
    • 대한치과보존학회:학술대회논문집
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    • 대한치과보존학회 2003년도 제120회 추계학술대회 제 5차 한ㆍ일 치과보존학회 공동학술대회
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    • pp.576-577
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    • 2003
  • I. Objectives This study investigated the dentin shear bond strength and the degree of conversion (DC) of currently used dentin bonding agents (DBAs) that were irradiated with a light emitting diode (LED) light curing unit (LCU) and a halogen LCU. II. Materials and methods The halogen LCU and the LED LCU used in this study were a VIP(Bisco, Schaumburg, IL, USA) and an Elipar Freelight(3M ESPE, St Paul, MN, USA) respectively. For the VIP, $400mW{\cdot}cm-2$ intensity mode was used to adjust to the intensity of the LED LCU. The DBAs used in this study were Scotchbond Multipurpose (3M ESPE), Single Bond (3M ESPE), One-step(Bisco), Clearfil SE Bond(Kuraray), and Adper Prompt(3M ESPE).(omitted)

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