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Diffusion-Selectivity Analysis of Permanent Gases through Carbon Molecular Sieve Membranes

  • Kang, Jong-Seok;Park, Ho-Bum;Lee, Young-Moo
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.43-53
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    • 2003
  • The selectivity of a gas in the carbon molecular sieve membrane (CMSM) can be expressed as the ratio of the product of the diffusivity and the solubility of two different gases. The diffusivity is also expressed as the product of the entropy and the total energy (kinetic and potential energy) in the nano-sized pore of the membrane. The present study calculates the entropic-energy and selectivity of penetrant gases such as H$_2$, O$_2$, N$_2$, and CO$_2$ from the gas-in-a box theory to physically analyze the diffusivity of penetrant gas in slit-shaped pore of CMSM focusing on the restriction of gas motion based on the size difference between penetrant gas pairs. The contribution of each energy term is converted to entropic term separately. By the conjugated calculation for each entropic-energy, the entropic effects on diffusivity-selectivity for gas pairs such as H$_2$/N$_2$, CO$_2$/N$_2$, and O$_2$/N$_2$ were analyzed within active pore of CMSM. In the activated diffusion domain, the calculated value of entropic-selectivity lies between 9.25 and 111.6 for H$_2$/N$_2$, between 3.36 and 6.0 for CO$_2$/N$_2$, and between 1.25 and 16.94 for O$_2$/N$_2$, respectively. The size decrement of active pore in CMSM had the direct effect on the reduction of translational entropic-energy and the contribution of vibrational entropic-energy for N$_2$, O$_2$, and H$_2$ was almost negligible. However, the vibrational entropic term of CO$_2$ might extravagantly affect on the entropic-selectivity.

An Experimental Study on The Development of fly-ash Cement Mortal Permanent (플라이애쉬 시멘트 모르터를 사용한 비탈형 영구거푸집 개발에 관한 실험적연구)

  • 김형남;김우재;김성식;김영희;정상진
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.481-486
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    • 1999
  • According to results of this research Fly-ash Cement permanent-form production was found to be possible by fly-ash mortal. The compress strength 350kg/$\textrm{cm}^2$, banding strength 120kg/$\textrm{cm}^2$ were possible material separting and bleeding by excessive W/C rate was decreased permanent-form made by polymer solved high price of polymer by fly-ash. Model material was made by result of first research. There were no minute-crack on beam form and out surface of form was very smooth, So filling degree seemed desirable length of form after steaming curing was maintained as expected. with these results production of form seemed possible. In the banding load test, fly-ash showed increase of maxim load 12% than RC. in the case of minute-crack, comparing with RC, fly-ash showed no crack at connect. at the first stage under continuing loading size of crack increased. These phenomena seemed to be based on contribution of stress of inner bars in permanent-form. in the test of defection, fly-ash shower about 10% beam load increase than RC. in the case of beam defection, RC showed sudden decrease of tolerance at maxim load and total breaking, but permanent-form showed breaking of bending maintaining defection with contribution of steel stress ($\Phi$6 wire-mash). There phenomenic seemed to be attributed to increase of surface and steel tolerance of form. According to construction explacemaion, it was guessed that each panel was constructed by conner-steels in form edge. so cohesiveness was small. on these bases. keeping width of horizontal band 30cm, form-panel of 20mm width was found to be of use. Permanent-form was found to be efficient in compressibleness, defection, safety and use of Fly-ash mortal.

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Analysis on the Kinematics and Dynamics of Human Arm Movement Toward Upper Limb Exoskeleton Robot Control - Part 2: Combination of Kinematic and Dynamic Constraints (상지 외골격 로봇 제어를 위한 인체 팔 동작의 기구학 및 동역학적 분석 - 파트 2: 제한조건의 선형 결합)

  • Kim, Hyunchul;Lee, Choon-Young
    • Journal of Institute of Control, Robotics and Systems
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    • v.20 no.8
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    • pp.875-881
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    • 2014
  • The redundancy resolution of the seven DOF (Degree of Freedom) upper limb exoskeleton is key to the synchronous motion between a robot and a human user. According to the seven DOF human arm model, positioning and orientating the wrist can be completed by multiple arm configurations that results in the non-unique solution to the inverse kinematics. This paper presents analysis on the kinematic and dynamic aspect of the human arm movement and its effect on the redundancy resolution of the seven DOF human arm model. The redundancy of the arm is expressed mathematically by defining the swivel angle. The final form of swivel angle can be represented as a linear combination of two different swivel angles achieved by optimizing two cost functions based on kinematic and dynamic criteria. The kinematic criterion is to maximize the projection of the longest principal axis of the manipulability ellipsoid of the human arm on the vector connecting the wrist and the virtual target on the head region. The dynamic criterion is to minimize the mechanical work done in the joint space for each of two consecutive points along the task space trajectory. The contribution of each criterion on the redundancy was verified by the post processing of experimental data collected with a motion capture system. Results indicate that the bimodal redundancy resolution approach improved the accuracy of the predicted swivel angle. Statistical testing of the dynamic constraint contribution shows that under moderate speeds and no load, the dynamic component of the human arm is not dominant, and it is enough to resolve the redundancy without dynamic constraint for the realtime application.

Interpretation of Agronomic Traits Variation of Sesame Cultivar Using Principal Component Analysis

  • Shim, Kang-Bo;Hwang, Chung-Dong;Pae, Suk-Bok;Park, Jang-Whan;Byun, Jae-Cheon;Park, Keum-Yong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.1
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    • pp.24-28
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    • 2009
  • This study was conducted to evaluate the growth characters and yield components of 18 collected sesame cultivars to get basic information on the variation for the sesame breeding using principal component analysis. All characters except days to flowering, days to maturity and 1,000 seed weight showed significantly different. Seed weight per 10 are showed higher coefficient of variance. Capsule bearing stem length and liter weight showed positive correlation with seed yield per 10 are. The principal components analysis grouped the estimated sesame cultivars into four main components which accounted for 83.7% of the total variation at the eigenvalue and its contribution to total variation obtained from principal component analysis. The first principal component ($Z_1$) was applicable to increase plant height, capsule bearing stem length and 1,000-seed weight. The second principal component ($Z_2$) negatively correlated with days to flowering and maturity by which it was applicable to shorten flowering and maturity date of sesame. At the scatter diagram, Yangbaek, Ansan, M1, M2, M4, M7 and M9 were classified as same group, but M10, Yanghuk, Kanghuk, M5, M6, M12 and M13 were classified as different group. This results would be helpful for sesame breeder to understand genetic relationship of some agronomic characters and select promising cross lines for the development of new sesame variety.

Uncertainty Evaluation of the Analysis of 11-Nor-9-carboxy-${\Delta}^9$-tetrahydrocannabinol in Human Urine by GC/MS (GC/MS를 이용한 소변 중 대마 대사체 분석의 측정불확도 평가)

  • Kim, Jin-Young;Jeong, Jae-Chul;Suh, Sung-Ill;Suh, Yong-Jun;Lee, Jeong-Jik;Kim, Jong-Sang;In, Moon-Kyo
    • YAKHAK HOEJI
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    • v.52 no.6
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    • pp.480-487
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    • 2008
  • We described an estimation of measurement uncertainty in quantitative analysis of 11-nor-9-carboxy-${\Delta}^9$-tetrahydrocannabinol (THCCOOH), the major metabolite of ${\Delta}^9$-tetrahydrocannabinol, in urine sample by solid-phase extraction (SPE) and GC/MS detection. The analytical results were compared and the different contributions to the uncertainty were evaluated. Inter-day and inter-person validation were performed using statistical analysis of several indicative factors. Measurement uncertainty associated with target analyte in real forensic samples was estimated using quality control (QC) data. Traceability of measurement was established through traceable standards, calibrated volumetric glassware and volume measuring device. The major factors of contribution to combined standard uncertainty, were calibration linearity, inter-day repeatability and inter-person reproducibility, while those associated with preparation of analytical standards and sampling volume were not so important considering the degree of contribution. Relative combined standard uncertainties associated with the described method was 12.05% for THCCOOH.

Emission Characteristics of Odor Compounds from Pneumatic Waste Collection Plants (생활폐기물 자동집하시설의 악취물질 배출특성)

  • Yoon, Yongkyeong;Kim, Daekeun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.8
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    • pp.541-548
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    • 2012
  • The objective of this study was to investigate emission characteristics of odorous compounds from the pneumatic waste collection plants (namely, A and B sites). The air samples were collected from each site, at a carrier gas inside the plant and an exhaust gas, to analyze complex odor and 22 odorous compounds. Ammonia, sulfur compounds, and acetaldehyde were the critical odorous components generated in the plants studied. Characteristics of odor at exhaust outlet varied according to the type of odor control engineering. In the analysis of the odor contribution degree of odor components based on odor threshold, site A shows that the odor contribution of dimethyl sulfide was found to be 26%, acetaldehyde 18%, and methyl mercaptan 14%. For site B, methyl mercaptan was 56% and both hydrogen sulfide and dimethyl sulfide were 15%.

Effect of modeling assumptions on the seismic behavior of steel buildings with perimeter moment frames

  • Reyes-Salazar, Alfredo;Soto-Lopez, Manuel Ernesto;Bojorquez-Mora, Eden;Lopez-Barraza, Arturo
    • Structural Engineering and Mechanics
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    • v.41 no.2
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    • pp.183-204
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    • 2012
  • Several issues regarding the structural idealization of steel buildings with perimeter moment resisting steel frames (MRSFs) and interior gravity frames (GFs) are studied. Results indicate that the contribution of GFs to the lateral structural resistance may be significant. The contribution increases when the stiffness of the connection of the GFs is considered and is larger for inelastic than for elastic behavior. The interstory shears generally increase when the connections stiffness is taken into account. Resultant stresses at some base columns of MRSFs also increase in some cases but to a lesser degree. For columns of the GFs, however, the increment is significant. Results also indicate that modeling the building as planes frames may result in larger interstory shears and displacements and resultant stresses than those obtained from the more realistic 3-D formulation. These differences may be much larger when semi-rigid (SR) connections are considered. The conservativism is more for resultant stresses. The differences observed in the behaviour of each structural representation are mainly due to a) the elements that contribute to strength and stiffness and b) the dynamics characteristics of each structural representation. It is concluded that, if the structural system under consideration is used, the three-dimensional model should be used in seismic analysis, the GFs should be considered as part of the lateral resistance system, and the stiffness of the connections should be included in the design of the GFs. Otherwise, the capacity of gravity frames may be overestimated while that of MRSFs may be underestimated.

The Impact of Real Estate Value Changes on Retirement Preparation : Focusing on Private Pensions (부동산의 가격변화가 노후준비에 미치는 영향 : 사적연금을 중심으로)

  • Kim, Dae Hwan;Lee, Dong Hyun
    • Korea Real Estate Review
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    • v.28 no.3
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    • pp.53-64
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    • 2018
  • OECD countries have been stimulating private pensions instead of public pensions because the financial stability of public pensions has been threatened by the aging population. Korea, which has the fastest aging population in the world, has been following the recommended policies of major countries. Unlike major economies, however, most of Korea's household assets are composed of real estate assets. Due to the economic and social importance of real estate assets in Korea, the wealth effect of real estate has been used as a major tool in macroeconomic policy. This study analyzed the effect of real estate value changes on the contribution of private pensions (personal pension + retirement pension). Utilizing a two-way, fixed effect model with the balanced panel data of the National Survey of Tax and Benefit, empirical results presented that the private pension contribution increased by 0.171% when the value of real estate increased by 1%. Thus, real estate value changes were analyzed as positive for retirement preparation through private pension. These results suggested that if the real estate market would shrink in the future, consumption would decrease, and the degree of preparation for retirement might be smaller.

A Study of Mixed Convection on a Flat Plate with an Unheated Starting Length (비가열부가 있는 평판에서의 혼합대류에 관한 연구)

  • 김민수;강영규;백병준;박복춘
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1304-1312
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    • 1993
  • The buoyancy effects on mixed convection heat transfer over a flat plate surface with unheated starting length is reported. The governing equations are solved by a finite difference method using Patankar scheme and the solution was numerically obtained for various mixed convection parametr $Gr_{x}/Re_{x}^3$, and Prandtl number of 0.7 Local heat flux was measured by using Schilieren Interferometer. The local heat transfer results show that the presence of the unheated starting length can significantly accentuate the effects of buoyancy. The degree of accentuation of the buoyancy effects is strongly influenced by the magnitude of $Gr_{x}/Re_{x}^3$. When the parameter is larger than the order of $10^{-3}$, the contribution of natural convection to the heat transfer coefficients increased significantly due to the unheated starting length. In contrast, when $Gr_{x}/Re_{x}^3$ is smaller then about $10^{-5}$ , the buoyancy contribution is essentially unaffected by the unheated starting length. The shape of the velocity profile is also found to be highly responsive to the interaction between the buoyancy and the starting length.

Risk Factor Analysis of Cryopreserved Autologous Bone Flap Resorption in Adult Patients Undergoing Cranioplasty with Volumetry Measurement Using Conventional Statistics and Machine-Learning Technique

  • Yohan Son;Jaewoo Chung
    • Journal of Korean Neurosurgical Society
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    • v.67 no.1
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    • pp.103-114
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    • 2024
  • Objective : Decompressive craniectomy (DC) with duroplasty is one of the common surgical treatments for life-threatening increased intracranial pressure (ICP). Once ICP is controlled, cranioplasty (CP) with reinsertion of the cryopreserved autologous bone flap or a synthetic implant is considered for protection and esthetics. Although with the risk of autologous bone flap resorption (BFR), cryopreserved autologous bone flap for CP is one of the important material due to its cost effectiveness. In this article, we performed conventional statistical analysis and the machine learning technique understand the risk factors for BFR. Methods : Patients aged >18 years who underwent autologous bone CP between January 2015 and December 2021 were reviewed. Demographic data, medical records, and volumetric measurements of the autologous bone flap volume from 94 patients were collected. BFR was defined with absolute quantitative method (BFR-A) and relative quantitative method (BFR%). Conventional statistical analysis and random forest with hyper-ensemble approach (RF with HEA) was performed. And overlapped partial dependence plots (PDP) were generated. Results : Conventional statistical analysis showed that only the initial autologous bone flap volume was statistically significant on BFR-A. RF with HEA showed that the initial autologous bone flap volume, interval between DC and CP, and bone quality were the factors with most contribution to BFR-A, while, trauma, bone quality, and initial autologous bone flap volume were the factors with most contribution to BFR%. Overlapped PDPs of the initial autologous bone flap volume on the BRF-A crossed at approximately 60 mL, and a relatively clear separation was found between the non-BFR and BFR groups. Therefore, the initial autologous bone flap of over 60 mL could be a possible risk factor for BFR. Conclusion : From the present study, BFR in patients who underwent CP with autologous bone flap might be inevitable. However, the degree of BFR may differ from one to another. Therefore, considering artificial bone flaps as implants for patients with large DC could be reasonable. Still, the risk factors for BFR are not clearly understood. Therefore, chronological analysis and pathophysiologic studies are needed.