• Title/Summary/Keyword: degradation ratio

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Microstructure of Cured Urea-Formaldehyde Resins Modified by Rubber Latex Emulsion after Hydrolytic Degradation

  • Nuryawan, Arif;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.5
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    • pp.605-614
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    • 2014
  • This study investigated microstructural changes of cured urea-formaldehyde (UF) resins mixed with aqueous rubber latex emulsion after intentional acid etching. Transmission electron microscopy (TEM) was used in order to better understand a hydrolytic degradation process of cured UF resins responsible for the formaldehyde emission from wood-based composite panels. A liquid UF resin with a formaldehyde to urea (F/U) molar ratio 1.0 was mixed with a rubber latex emulsion at three different mixing mass ratios (UF resin to latex = 30:70, 50:50, and 70:30). The rate of curing of the liquid modified UF resins decreased with an increase of the rubber latex proportion as determined by differential scanning calorimetry (DSC) measurement. Ultrathin sections of modified and cured UF resin films were exposed to hydrochloric acid etching in order to mimic a certain hydrolytic degradation. TEM observation showed spherical particles and various cavities in the cured UF resins after the acid etching, indicating that the acid etching had hydrolytically degraded some part of the cured UF resin by acid hydrolysis, also showing spherical particles of cured UF resin dispersed in the latex matrix. These results suggested that spherical structures of cured UF resin might play an important role in hindering the hydrolysis degradation of cured UF resin.

Effect of Unsaturated Fatty Acids on Cellulose Degradation and Fermentation Characteristics by Mixed Ruminal Microbes

  • Hwang, I.H.;Kim, H.D.;Shim, S.S.;Lee, Sang S.;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.4
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    • pp.501-506
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    • 2001
  • This experiment was conducted to evaluate the effects of supplemental unsaturated fatty acids (UFA) on fermentation characteristics, especially on gas production, cellulose degradation and volatile fatty acid (VFA) concentration by mixed ruminal microorganisms. In order to attain this objective, unsaturated fatty acids including oleic acid (C 18:1), linoleic acid (C18:2) and arachidonic acid (C22:4) were added at varying level. Mixed ruminal microbes used in this experiment were obtained from the rumen of a cannulated Holstein cow. Medium pH values after 7 d incubation were significantly affected by type and level of unsaturated fatty acids (p<0.01). All of UFA inhibited total gas production, and especially treatment of arachidonic acid at the levels of 0.01% gave the lowest gas. production after 7 d incubation (p<0.01). Comparison of the population of protozoa revealed that UFA did not have any significant effect on the total protozoa number. The addition of UFA did not effect dry matter degradation. Volatile fatty acid (VFA) composition of the culture was influenced little by UFA, although the considerable amount of iso-type VFA were detected in UFA supplemented incubations. The ratio of acetic acids to propionic acids, however, was lower than control in all the treatments after 7 d incubation (p<0.01).

Evaluation of Degradation Behavior of the Long-Term Serviced Boiler Header (장기 사용 보일러 헤더의 열화거동 평가에 관한 연구)

  • Gwon, Jae-Do;Bae, Yong-Tak;Choe, Seong-Jong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.7 s.178
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    • pp.1673-1680
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    • 2000
  • The degradation of a boiler header constructed by a material, 1Cr-0.5Mo steel in a fossil power plant is observed when the header is exposed for a long period to the high temperature and pressure. The present investigations are for evaluating the effect of the degradation on the material, such as its strength changes. Reheat-treated metal is used to compare the mechanical properties of the degraded and that of reheat-treated materials. Through the investigation, following results are obtained 1) the area ratio of ferrite in the reheat-treated material is larger than that of the degraded material, 2) the hardness and tensile strength of the degraded material are lower than that of the reheat-treated material, 3) the ductile-brittle transition temperature(DBTT) increased toward high temperature region, 4) the fatigue crack growth rate(FCGR) of the degraded material is higher than that of the reheat-treated material in the region of low ΔK value while FCGR of the both materials are similar in high ΔK region.

Bortezomib Is Toxic but Induces Neurogenesis and Inhibits TUBB3 Degradation in Rat Neural Stem Cells

  • Seung Yeon Sohn;Thin Thin San;Junhyung Kim;Hyun-Jung Kim
    • Biomolecules & Therapeutics
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    • v.32 no.1
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    • pp.65-76
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    • 2024
  • Bortezomib (BTZ) is a proteasome inhibitor used to treat multiple myeloma (MM). However, the induction of peripheral neuropathy is one of the major concerns in using BTZ to treat MM. In the current study, we have explored the effects of BTZ (0.01-5 nM) on rat neural stem cells (NSCs). BTZ (5 nM) induced cell death; however, the percentage of neurons was increased in the presence of mitogens. BTZ reduced the B-cell lymphoma 2 (Bcl-2)/Bcl-2 associated X protein ratio in proliferating NSCs and differentiated cells. Inhibition of βIII-tubulin (TUBB3) degradation was observed, but not inhibition of glial fibrillary acidic protein degradation, and a potential PEST sequence was solely found in TUBB3. In the presence of growth factors, BTZ increased cAMP response element-binding protein (CREB) phosphorylation, brain-derived neurotrophic factor (Bdnf) transcription, BDNF expression, and Tubb3 transcription in NSCs. However, in the neuroblastoma cell line, SH-SY5Y, BTZ (1-20 nM) only increased cell death without increasing CREB phosphorylation, Bdnf transcription, or TUBB3 induction. These results suggest that although BTZ induces cell death, it activates neurogenic signals and induces neurogenesis in NSCs.

Experimental and numerical studies on the frame-infill in-teraction in steel reinforced recycled concrete frames

  • Xue, Jianyang;Huang, Xiaogang;Luo, Zheng;Gao, Liang
    • Steel and Composite Structures
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    • v.20 no.6
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    • pp.1391-1409
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    • 2016
  • Masonry infill has a significant effect on stiffness contribution, strength and ductility of masonry-infilled frames. These effects may cause damage of weak floor, torsional damage or short-column failure in structures. This article presents experiments of 1/2.5-scale steel reinforced recycled aggregates concrete (SRRC) frames. Three specimens, with different infill rates consisted of recycled concrete hollow bricks (RCB), were subjected to static cyclic loads. Test phenomena, hysteretic curves and stiffness degradation of the composite structure were analyzed. Furthermore, effects of axial load ratio, aspect ratio, infill thickness and steel ratio on the share of horizontal force supported by the frame and the infill were obtained in the numerical example.

A Study on Disposal Diagnosis Algorithm of PV Modules Considering Performance Degradation Rate (태양광모듈의 성능저하율을 고려한 폐기진단 알고리즘에 관한 연구)

  • Park, Ji-Hyun;Lee, Hu-Dong;Tae, Dong-Hyun;Ferreira, Marito;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.10
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    • pp.493-502
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    • 2019
  • Recently, the installation of renewable energy including PV systems in distribution systems has increased energetically to cope with climate change and energy shortages according to the government's policy of renewable energy 3020. On the other hand, the electrical performance and lifespan of PV modules installed outdoors can be decreased considerably due to a range of deterioration phenomena depending on the ambient environmental factors. To overcome these problems, replacement of degraded PV modules with new ones is increased before the lifespan guaranteed by the makers of PV modules. Therefore, this paper proposes a disposal diagnosis algorithm to evaluate the time interval of the optimal replacement for PV modules according to performance degradation rate of PV modules. In addition, this study modeled an economic evaluation, which is composed of the cost and benefit of PV systems. From the simulation results based on the proposed modeling and algorithm to consider the performance degradation rate specifically, the replacement approach was found to have the best B/C ratio in 10th year with a 3[%] degradation rate and the disposal diagnosis algorithm of PV modules are useful and practical tools for economic evaluations of the replacement of PV modules.

Development of Plasma Reactor of Dielectric Barrier Discharge for Water Treatment (수처리용 유전체 장벽 방전 플라즈마 반응기 개발)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.21 no.5
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    • pp.597-603
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    • 2012
  • Non-thermal plasma processing using a dielectric barrier discharge (DBD) has been investigated as an alternative method for the degradation of non-biodegradable organic compounds in wastewater. The active species such as OH radical, produced by the electrical discharge may play an important role in degrading organic compound in water. The degradation of N, N-Dimethyl-4-nitrosoaniline (RNO) was investigated as an indicator of the generation of OH radical. The DBD plasma reactor of this study consisted of a plasma reactor, recycling pump, power supply and reservoir. The effect of diameter of external reactor (15 ~ 40 mm), width of ground electrode (2.5 ~ 30 cm), shape (pipe, spring) and material (copper, stainless steel and titanium) of ground electrode, water circulation rate (3.1 ~ 54.8 cm/s), air flow rate (0.5 ~ 3.0 L/min) and ratio of packing material (0 ~ 100 %) were evaluated. The experimental results showed that shape and materials of ground were not influenced the RNO degradation. Optimum diameter of external reactor, water circulation rate and air flow rate for RNO degradation were 30 mm, 25.4 cm/s and 4 L/min, respectively. Ground electrode length to get the maximum RNO degradation was 30 cm, which was same as reactor length. Filling up of glass beads decreased the RNO degradation. Among the experimented parameters, air flow rate was most important parameters which are influenced the decomposition of RNO.

Program Development for Material Degradation Evaluation Using Grain Boundary Etching Method (입계부식법을 이용한 열화도 평가 프로그램 개발)

  • Yu, Hyo-Seon;Baek, Seung-Se;Na, Seong-Hun;Kim, Jeong-Gi;Lee, Hae-Mu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.7
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    • pp.1064-1072
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    • 2001
  • It is very important to evaluate material degradation like temper and carbide embrittlements to secure the reliable and efficient operational conditions and to prevent brittle failure in service. The extent of material deterioration can be accurately evaluated by mechanical test such as impact test or creep test. But it is almost impossible to sample a large specimen from in-service plants. Thus, the material degradation evaluation by a non-destructive method is earnestly required. Recently the non-destructive test technique which uses the grain boundary etching characteristics owing to the variation of material structures has been proposed. However the program for material degradation evaluation using the grain boundary etching method(GEM) in Windows 98 domain doesnt be developed now. The aims of this paper are to develop the program and to complete the new master curve equations for the evaluation of material degradation on in-serviced high temperature components.

Butterfly Log-MAP Decoding Algorithm

  • Hou, Jia;Lee, Moon Ho;Kim, Chang Joo
    • Journal of Communications and Networks
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    • v.6 no.3
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    • pp.209-215
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    • 2004
  • In this paper, a butterfly Log-MAP decoding algorithm for turbo code is proposed. Different from the conventional turbo decoder, we derived a generalized formula to calculate the log-likelihood ratio (LLR) and drew a modified butterfly states diagram in 8-states systematic turbo coded system. By comparing the complexity of conventional implementations, the proposed algorithm can efficiently reduce both the computations and work units without bit error ratio (BER) performance degradation.

Lignocellulose Biodegradation and Interaction between Cellulose and Lignin under Sulfate Reducing Conditions (황산염 환원 조건에서 리그노셀룰로오스의 분해 및 리그닌과 셀룰로오스의 상호작용)

  • Ko, Jae-Jung;Kim, Seog-Ku;Shimizu, Yoshihisa
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.4
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    • pp.131-137
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    • 2007
  • In this study, the biodegradation test on lignocellulose under sulfate reducing conditions was carried out. In particular, the interaction between cellulose and lignin was investigated with various g-cellulose/g-lignin (C/L) ratios: 42.15, 4.59, 2.51, 1.14 and 0.7. It was shown that the rate of cellulose degradation decreased in proportion to the lignin content. Assuming first order degradation kinetics, the consequences of competitive inhibition were graphically shown for different C/L ratios. The relation between cellulose reduction rate and C/L ratio was expressed by logarithm function with a determination coefficient of 0.97. Lignocellulose reduction rate was also described as a logarithm function of C/L ratio showing a inhibition effect by lignin. In the mean time, the rate of lignin decomposition was higher at C/L ratio of 2.51 and 1.14 compared with C/L ratios of 4.59 and 0.7, indicating that excessive extra carbon source is not appropriate for lignin biodegradation.

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