• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.17 no.10
• /
• pp.1068-1078
• /
• 2004

In this paper we investigated the characteristics of surface degradation in silicone rubber due to corona exposure and recovery mechanism. It was shown that surface free energy was 22.42 mJ/$m^2$ on initial sample but surface free energy was approximately increased to 71.14 mJ/$m^2$ after 45 minutes. However, surface free energy on silicone rubber after corona discharge treatment was completely recovered within a short time due to diffusion of low molecular weight(LMW) silicone fluid. It was shown that corona discharge insured the increase of diffusible LMW chains, which could lead to recover the surface hydrophobicity. 200～370 g/mol distribution of LMW silicone fluid which was extracted by solvent-extraction with gel permeation chromatography (GPC) was contributed to recovery. The surface degradation characteristics on silicone rubbers and the recovery mechanism based on our results were discussed.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.14 no.2
• /
• pp.81-88
• /
• 2008

There are increasing public concerns that the disposal of most synthetic carbon-based plastics is a great threat to the environment. These have led to intensive research and development of degradable plastics, such as biodegradable plastics, photodegradable plastics, and multi-degradable plastics. Although these degradable plastics may not completely replace common synthetic plastics, these minimize environmental impacts caused by non degradable plastics. Photodegradable plastics are synthetic polymers into which have been incorporated copolymers or light-sensitive additives to weaken the structural bonds in polymer chains when exposed to UV radiation. A better understanding of photodegradable plastics, which also play an important role in the degradation of multi-degradable plastics, will expand the usage of degradable plastics. The aim of present article is to review the formation, degradation mechanism and properties of photodegradable plastics.

• Biodesign
• /
• v.6 no.4
• /
• pp.100-102
• /
• 2018

Autophagy is a degradation pathway that targets many cellular components and plays a particularly important role in protein degradation and recycling. This process is very complex and several proteins participate in this process. One of them, P62/SQSTM1, is related to the N-end rule and induces protein degradation through autophagy. The P62/SQSTM1 makes a huge oligomer, and this oligomerization is known to play an important role in its mechanism. This oligomerization takes two steps. First, the PB1 domain of P62/SQSTM1 makes the base oligomer, and then, when the ligand binds to the ZZ domain of P62/SQSTM1, it induces a higher oligomer by the disulfide bond of the two cysteines. To understand the oligomerization mechanism of P62/SQSTM1, we need to know the dimerization of the PB1 domain. In this study, crystals of PB1 dimer were made and the crystals were diffracted by X-ray to collect usable data up to 3.2A. We are analyzing the structure using the molecular replacement (MR) method.

• Journal of the Korean Physical Society
• /
• v.73 no.12
• /
• pp.1879-1883
• /
• 2018

We analyzed the deep-trap states of GaN/InGaN ultraviolet light-emitting diodes (UV LEDs) before and after electrical stress. After electrical stress, the light output power dropped by 5.5%, and the forward leakage current was increased. The optical degradation mechanism could be explained based on the space-charge-limited conduction (SCLC) theory. Specifically, for the reference UV LED (before stress), two sets of deep-level states which were located 0.26 and 0.52 eV below the conduction band edge were present, one with a density of $2.41{\times}10^{16}$ and the other with a density of $3.91{\times}10^{16}cm^{-3}$. However, after maximum electrical stress, three sets of deep-level states, with respective densities of $1.82{\times}10^{16}$, $2.32{\times}10^{16}cm^{-3}$, $5.31{\times}10^{16}cm^{-3}$ were found to locate at 0.21, 0.24, and 0.50 eV below the conduction band. This finding shows that the SCLC theory is useful for understanding the degradation mechanism associated with defect generation in UV LEDs.

• Biotechnology and Bioprocess Engineering:BBE
• /
• v.5 no.6
• /
• pp.422-430
• /
• 2000

Mechanism of lignin biodegradation caused by basidiomycetes and the history of lignin biodegradation studies were briefly reviewed. The important roles of fungal extracellular ligninolytic enzymes such as lignin and manganese peroxidases (LiP and MnP) were also summarized. These enzymes were unique in their catalytic mechanisms and substrate specificities. Either LiP or MnP system is capable of oxidizing a variety of aromatic substrates via a one-electron oxidation. Extracellular fungal system for aromatic degradation is non-specific, which recently attracts many people working a bioremediation field. On the other hand, an intracellular degradation system for aromatic compounds is rather specific in the fungal cell. Structurally similar compounds were prepared and metabolized, indicating that an intracellular degradation strategy consisted of the cellular systems for substrate recognition and metabolic response. It was assumed that lignin-degrading fungi might be needed to develop multiple metabolic pathways for a variety of aromatic compounds caused by the action of non-specific ligninolytic enzymes on lignin. Our recent results on chemical stress responsible factors analyzed using mRNA differential display techniques were also mentioned.

• Journal of Applied Reliability
• /
• v.7 no.4
• /
• pp.173-181
• /
• 2007

Out door exposure to daylight and weather climate conditions can cause adverse effect on the properties of automotive plastic materials. The effects of sunlight exposure, especially ultra violet (UV) radiation, can break down the chemical bonds in a polymeric material. This degradation process is called photo-degradation and ultimately leads to color changes, cracking, chalking, the loss of physical properties and deterioration of other properties. To explore the effect of sunlight exposure on the automotive materials, this study investigated photo-oxidation degree and surface property change of molding parts by analytical methods. For the further study, accelerated weathering test methods are proposed, which can correlate with out door weathering, to predict long term performance of automotive plastic materials.

• Korean Journal of Materials Research
• /
• v.4 no.4
• /
• pp.439-444
• /
• 1994

The influence of the direction of applied compressive stress on degradation mechanism ofpoled PZT sample was studied. When compressive stress perpendicular to poling direction was appliedon poled PZT sample, the degradation phenomena was explained by the diffusion of space chargepolarization. On the contrary, compressive stress parallel to poling direction was applied, it wasexplained by the rearrangement of 90" domains. As the grain size increased, the degradation phenomenawas promoted. It is attributed to different internal stress due to difference of grain size. of grain size.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.33 no.10
• /
• pp.991-1004
• /
• 2009

Operating experience of the various components in the nuclear power plants has shown that a variety of degradation mechanisms can occur during operation. Therefore, the accurate lifetime evaluation and systematic management are very important for the safe as well as the economical operation of the nuclear power plants. In this paper, the characteristics of a total of 17 degradation mechanisms were reviewed and the plausible degradation mechanisms such as stress corrosion cracking, fatigue, irradiation embrittlement, and so on, were identified. Also, the lifetime evaluation technologies which have been developed for the application to the domestic nuclear power plants are described. In addition, a total of 48 aging management programs which have been established for the safe operation of the various components are explained.

• Journal of Microbiology and Biotechnology
• /
• v.8 no.2
• /
• pp.185-187
• /
• 1998

Pseudomonas putida KCTC 2401 degrades 1,1, 2-trichloroethylene (TCE) using phenol as a cosubstrate. The initial TCE degradation rate decreased with the initial TCE concentration up to 20mg/l of TCE at $30^{\circ}C$ and pH 6.5. The initial degradation rate and total removal efficiency increased with inoculum size. The strain also degraded dichloroacetic acid, which was supposed to be a degradation by-product. Phenol monooxygenase apparently participates in the TCE degradation mechanism.

• Proceedings of the KIEE Conference
• /
• 1998.11c
• /
• pp.813-815
• /
• 1998

In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. Finally, We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.