• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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• pp.108-110
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• 1994

Decomposition products by crosslinking reaction of PE using Dicumylperoxide(DCP) should influence on the electrical properties in XLPE. This paper studies on Behaviors of Decomposition products and Electrical Treeing ding to Drying condition. We used the Gas Chromatography for Decomposition Gases analysis FT-IR for investigating the behaviors of Decomposition products remained in XLPE Break Down Voltage Tester for Electrical Treeing measurement.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1993년도 하계학술대회 논문집 B
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• pp.1236-1238
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• 1993

This paper studies on the behaviors of decomposition products from DCP according to various drying conditions of DCP. The decomposition products formed during crosslinking reaction have an harmful influence on XLPE. Especially explosive gases like methane which is one of decomposition products may cause explosion accident. We used the Gas Chromatography and Gas sensor for decomposition gases analysis, FT-IR for investigating the behaviors of decomposition products remained in XLPE.

• Macromolecular Research
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• 제11권2호
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• pp.87-91
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• 2003

Thermal decomposition reactions of polystyrene using a new heating medium were carried out by a batch system at 190-280 $^{\circ}C$ to clarify the manner in which decomposition is initiated. Polystyrene obtained from a commercial source and low molecular weight compounds obtained from the thermal decomposition were analyzed by GC, GPC, IR, $^{13}$ C-NMR and GC-MS. The main chain underwent virtually no change by heat application. Polystyrene underwent decomposition below its molding temperature and the major decomposition products were 2,4,6-triphenyl-1-hexene (trimer), 2,4-diphenyl-1-butene(dimer) and styrene (monomer). Ethylbenzene, propylbenzene, naphthalene, benzaldehyde, biphenyl and 1,3-diphenylpropane were detected as minor products. This paper presents a new method for examining the decomposition of polystyrene at low temperature into volatile low molecular weight compounds.

• 한국환경과학회지
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• 제11권7호
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• pp.749-755
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• 2002

The effects of noble gas (such as helium, neon, argon, krypton, and xenon) on the sonolytic decomposition of water and 2-methyl-2-propanol(t-butanol) with 200 KHz high power ultrasound were investigated. The physical properties of the noble gas have an effect on the formation rate of products $(H_2O_2,\;H_2,\;O_2)$ and the decomposition rate on the sonolytic decomposition of water. The pyrolysis products, such as methane, ethane, ethylene, and acetylene are formed during the sonolytic decomposition of t-butanol. From the estimation of the ratio $[C_2H_4+C_2H_2] / [C_2H_6]$, the cavitation temperature would be varied by the used noble gas. In all cases for the sonolytic decomposition of water, t-butanol, and diethyl phthalate, the decomposition rates were xenon > krypton > argon > neon > helium with a significant difference and were closely correlated with the formation rate of OH radical and high temperature inside the cavitation bubble under each noble gas.

• 한국대기환경학회지
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• 제17권1호
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• pp.97-104
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• 2001

Decomposition of trichloroethlyene(TCE) in electron beam irradiation was examined on order to obtain information on the treatment of VOC in air. Air containing vaporized TCE has been studied in a flow reactor with different reaction environments, at various initial TCE concentration and in the presence and absence of water vapor. Maximum decomposition was observed in oxygen reaction environment and the degree of decomposition was about 99% at 20kGy for 2,000ppm initial TCE. The concentration of TCE exponentially decreased with dose in air and pure oxygen. The effect of water vapor on TCE decomposition efficiency was examined. The decomposition rate of TCE in the presence of water vapor (5,600 ppm) was approximately 10% higher than that in the absence of water vapor. Dichloroacetic acid, dichloroacethyl chloride and dichloroethyl ester acid were identified as primary products of this reaction adn were decomposed and oxidized to yield CO and $CO_2$. Perchloroethylene, hexachloroethane, chloroform and carbon tetrachloride were also observed as highly chlorinat-ed by products.

• Macromolecular Research
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• 제11권3호
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• pp.178-182
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• 2003

The thermal decomposition of phthalate alone and with poly(vinyl chloride) (PVC) was carried out under a nitrogen atmosphere in a 4-necked separable flask. The thermal decomposition of phthalate in the presence of PVC began at 150$^{\circ}$, about 10$0^{\circ}C$ lower than the decomposition of phthalate alone. The formation of octyl chloride indicated an interaction reaction between phthalate and PVC. From the analysis of the composition of commercially plasticized PVC sheet (film and board), the phthalates (dibutyl phthalate, dihexyl phthalate) and di(2-ethylhexyl) phthalate), 2-ethyl-1-hexanol, phthalic anhydride, and 2-ethylhexyl hydrogen phthalate were identified. The mutage-nicities of these decomposition products were higher than those of phthalic diesters (phthalates).

• Bulletin of the Korean Chemical Society
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• 제17권9호
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• pp.798-802
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• 1996

The photochemical decomposition of aqueous ammonia in the absence (saturated with argon) and the presence of O2 (saturated with air or oxygen) has been investigated using 184.9 nm UV light. The decomposition of ammonia depended on the concentration of oxygen in the solution. With increasing the concentration of oxygen, the decomposition of ammonia diminishes. Hydrazine is found the major product from the irradiation. In the presence of oxygen, hydrogenperoxide was also produced. The product yields depended also on the concentration of oxygen in the solution. The initial quantum yield of the products and of the ammonia decomposed were determined. Probable reaction mechanisms for the reaction were presented from the products analysis.

• 한국산업보건학회지
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• 제22권1호
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• pp.52-59
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• 2012

Objectives: The purpose of this study was to evaluate the exposure possibility of by-products during the semiconductor manufacturing processes. Methods: The authors investigated types of chemicals generated during semiconductor manufacturing processes by the qualitative experiment on generation of by-products at the laboratory and a literature survey. Results: By-products due to decomposition of photoresist by UV-light during the photo-lithography process, ionization of arsine during the ion implant process, and inter-reactions of chemicals used at diffusion and deposition processes can be generated in wafer fabrication line. Volatile organic compounds (VOCs) such as benzene and formaldehyde can be generated during the mold process due to decomposition of epoxy molding compound and mold cleaner in semiconductor chip assembly line. Conclusions: Various types of by-products can be generated during the semiconductor manufacturing processes. Therefore, by-products carcinogen such as benzene, formaldehyde, and arsenic as well as chemical substances used during the semiconductor manufacturing processes should be controlled carefully.

• Journal of Electrical Engineering and Technology
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• 제13권6호
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• pp.2385-2391
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• 2018

This paper is devoted to detecting decomposition characteristics of Iodotrifluoromethane ($CF_3I$) under alternating current (AC) discharges or load current interruptions. The decomposition products are measured utilizing chromatography-mass spectroscopy. It is found that less than 1% $CF_3I$ gas decomposed after several interruptions at load current of 200 A or hundred times of AC discharges. However, under interruptions at a current of 400 A, more than 95% $CF_3I$ gas decomposed into carbon tetrafluoride ($CF_4$) and hexafluoroethane ($C_2F_6$). The equilibrium compositions based on Gibbs free energy minimization of $CF_3I$ was calculated to explain the decomposition mechanism.

• 조명전기설비학회논문지
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• 제28권6호
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• pp.52-59
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• 2014

This paper deals with the effect of decomposition products which occur in breakdown of mineral oil, on the insulation characteristics of its oil. Breakdown tests in the oil were conducted by the proposed experimental methods under a quasi-uniform field and AC HV (60Hz). The breakdown voltage in the oil shows characteristics of dispersion from successive breakdowns and, it is found that there are three patterns of the decomposition products behavior at the process of breakdown progress in the oil. Finally, the breakdown voltage dispersion in the oil can be described in detail based on the behavior patterns of the decomposition products and its diffusion time.