• Title/Summary/Keyword: cycloaddition

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New Synthesis of Perhydrotriazolotriazoles Catalyzed by TiCl4 under Ambient Conditions

  • Safari, J.;Gandomi-Ravandi, S.;Ghotbinejad, M.
    • Journal of the Korean Chemical Society
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    • v.56 no.1
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    • pp.78-81
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    • 2012
  • Aromatic 2,3-diazabuta-1,3-dienes in glacial acetic acid with isothiocyanate in the presence of catalyst $TiCl_4$ at room temperature produced via criss-cross cycloaddition reactions the corresponding perhydro[1,2,4]triazolo[1,2-a][1,2,4] triazole-1,5-dithiones in relatively high yields and short reaction time.

Facile Synthesis of Fréchet Type Dendritic Benzyl Azides and Dendrimer via Cycloaddition Reaction with Tripodal Core

  • Lee, Jae-Wook;Kim, Byung-Ku;Kim, Jung-Hwan;Shin, Won-Suk;Jin, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1790-1794
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    • 2005
  • Fréchet-type dendritic benzyl azides were efficiently synthesized using 5-(azidomethyl)-1,3-dihydroxybenzene as an azide focal point functionalized unit by adding a generation to the existing dendron and applied for the construction of dendrimers containing 1,2,3-triazole rings as connectors via click chemistry with a tripodal acetylene core.

Entry to Highly Hindered Chiral β-Amino Triazoles Bearing a gem-Diaryl Group by Azide-alkyne Click Chemistry

  • Sadu, Venkata Subbaiah;Roy, Harendra Nath;Arigala, Pitchaiah;Hwang, In-Taek;Lee, Kee-In
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1605-1612
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    • 2014
  • Copper(I)-catalyzed Huisgen cycloaddition of terminal alkynes with unmasked azidoamines derived from amino acids is described. The reported strategy provides a new entry to highly hindered ${\beta}$-amino 1,2,3-triazole derivatives bearing a gem-diaryl group, which are potentially valuable entities as molecular catalysts for asymmetric transformations.

High Pressure Effects on 1,3-Dipolar Cycloaddition of Azides with Alkynes (아자이드와 알킨의 1,3-쌍극자 고리첨가반응에서 고압이 반응속도에 미치는 영향에 대한 연구)

  • Kwon, Jinju
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.6
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    • pp.736-742
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    • 2015
  • The effect of pressure on 1,3-dipolar cycloaddtion has been studied by means of FT-IR and NMR spectroscopy. Pressure accelerates 1,3-dipolar cycloaddition without solvent or catalyst. This simple and inexpensive method eliminates the need for work-up or purification. The method is expected to be applied to the synthesis of binders for solid rocket propellants.

Cycloaddition of Homophthalic Anhydrides to Azodicarboxylate and Alkylidenecarbamates (호모프탈산 무수물과 아조디카르복시산 에스테르 및 알킬리덴카르밤산 에스테르와의 고리화첨가반응)

  • Youn Young Lee;Ho Hyeon Kim;Yang Mo Goo
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.243-247
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    • 1986
  • The cycloaddition between homophthalic anhydrides (1 or 2) and diethyl azodicarboxylate and ethyl arylmetbyldenecarbamates was investigated. The former led to 2,3-diethoxycarbonyl-2,3-dihydro-1-hydroxyphthalazines (3 and 4), while the latter gave 3-aryl-4-carboxy-2-ethoxycarbonyl-3,4-dihydro-1(2H) isoquinolinones (5∼10).

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