• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.1
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• pp.1-18
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• 2020

Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500℃ were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm³⁺ over the concentration range. Equipped with Sm³⁺ diffusion coefficient, the Randles-Sevcik equation predicted Sm³⁺ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm³⁺ and Sm²⁺. By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.5
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• pp.495-501
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• 2005

Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

• Journal of the Korean institute of surface engineering
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• v.30 no.2
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• pp.93-103
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• 1997

High temperature materials used in the elevated temperature and corrosive atmosphere must have the good oxidation resistance and preserve their own mechanical properties simultaneously. For the oxidation resistance, it is very important to form a protective oxide scale such as $Al_2O_3$ or $Cr_2O_3$ on the substrate. However, the additions of protective oxide forming elements such as Cr and Al in the alloy to enhance its oxidation resistance are limited due to the deleterious effects on their mechanical properties. PECVD(P1asma Enhanced Chemical Vapor Deposition) coating processes were employed to improve the oxidation resistance at high temperature. Cr and/or A1 were coated on the substrates of Ni and Inconel 600 at various temperatures of 400, 500, $600^{\circ}C$ and at different conditions of specimen surfaces. Then, coated specimens were exposed to isothermal and cyclic oxidation conditions in air at 1000 and $1100^{\circ}C$. In order to enhance the adhesion between the substrate and coated layer, heat treatments of the coated specimens were conducted in a vacuum. At isothermal oxidation experiments, Al-coated Ni specimen showed better oxidation resistance than pure Ni. At cyclic oxidation experiments at $1000^{\circ}C$. Cr and Al-coated specimen showed better oxidation resistance. Cr-coated Inconel 600 had also showed better oxidation resistance due to Cr in the substrate. By PECVD coating process, oxidation resistance could be improved, but it was not improved as expected due to the weakness of the adhesion between the substrate and the coated layer.

• Steel and Composite Structures
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• v.43 no.5
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• pp.673-688
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• 2022

Post-earthquake fire is a major threat since most structures are designed allowing some damage during strong earthquakes, which will expose a more vulnerable structure to post-earthquake fire compared to an intact structure. A series of experimental research on steel-concrete composite beam-to-column joints subjected to fire after cyclic loading has been carried out and a clear reduction of fire resistance due to the partial damage caused by cyclic loading was observed. In this paper, by using ABAQUS a robust finite element model is developed for exploring the performance of steel-concrete composite joints in post-earthquake fire scenarios. After validation of these models with the previously conducted experimental results, a comprehensive numerical analysis is performed, allowing influential parameters affecting the post-earthquake fire behavior of the steel-concrete composite joints to be identified. Specifically, the level of pre-damage induced by cyclic loading is regraded to deteriorate mechanical and thermal properties of concrete, material properties of steel, and thickness of the fire protection layer. It is found that the ultimate temperature of the joint is affected by the load ratio while fire-resistant duration is relevant to the heating rate, both of which change due to the damage induced by the cyclic loading.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.1126-1133
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• 2005

The effects of mean particle size and uniformity coefficient of dredged soils to the liquefaction resistance strength and dynamic characteristics are experimentally studied in this paper. Representative 4 mean particle sizes and 3 uniformity coefficients were selected and 12 representative particle size distribution curves which have different mean particle sizes and uniformity coefficients, were artificially manufactured using the real dredged river soil. Cyclic triaxial tests and torsional shear tests were carried out to analyze the effect of mean particle size and uniformity coefficient to the liquefaction resistance strength and dynamic characteristics of soils.

• Geomechanics and Engineering
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• v.3 no.2
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• pp.83-108
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• 2011

The effect of non-plastic fines (silt) on liquefaction and pore pressure generation characteristics of saturated sands was studied through undrained stress controlled cyclic triaxial tests using cylindrical specimens of size 50 mm diameter and height 100 mm at different cyclic stress ratios and at a frequency of 0.1 Hz. The tests were carried out in the laboratory adopting various measures of sample density through various approaches namely gross void ratio approach, relative density approach, sand skeleton void ratio approach, and interfine void ratio approach. The limiting silt content and the relative density of a specimen were found to influence the undrained cyclic response of sand-silt mixtures to a great extent. Undrained cyclic response was observed to be independent of silt content at very high relative densities. However, the presence of fines significantly influenced this response of loose to medium dense specimens. Combined analyses of cyclic resistance have been done using the entire data collected from all the approaches.

• Journal of the Korean Geotechnical Society
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• v.22 no.12
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• pp.89-98
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• 2006

In this paper the behavior of saturated sand deposits where liquefaction occurred before is studied for successive earthquakes. The relationship between past pore pressure generation and reliquefaction resistance is examined by using cyclic direct simple shear tests. If the soil sample in direct simple shear produced nearly 90% of excess pore pressure during first time loading, its liquefaction resistance increased during following cyclic loading after consolidation. However, a fully liquefied soil during first time loading has a densely packed condition but shows less liquefaction resistance for the following cyclic loading. UBCSAND model that can account for pore pressure change and stiffness loss of soil during shaking is used to analyze the centrifuge test simulating reliquefaction. The pore pressure rise during first time cyclic loading controls liquefaction resistance. The measurements from reliquefaction centrifuge test are compared with numerical predictions. By considering frequent earthquakes having occurred at the Southern Korea near Japan, such effective stress approach is necessary for reliquefaction study.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.23 no.7 s.166
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• pp.1112-1119
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• 1999

Fracture resistance(J-R) curves, which are used for the elastic-plastic fracture mechanics analyses, are known to be dependent on the cyclic loading history. The objective of this paper is to study the effect of reverse cyclic loading on J-R curves in CT specimens. The effect of two parameters was observed on the J-R curves during the reverse cyclic loading. One was the minimum-to-maximum load ratio(R) and the other was the incremental plastic displacement(${\delta}_{cycle}/{\delta}_i$), which is related to the amount of crack growth that occurs in a cycle. Fracture resistance test on CT specimens with varying load ratio and incremental plastic displacement were performed. For the SA 516 Gr. 70 steel, the results showed that the J-R curves were decreased with decreasing the load ratio and the incremental plastic displacement. When the load ratio was set to -1, the results of the J-R curves and the $J_i$ value were about $40{\sim}50$ percent of those for the monotonic loading condition. Also on condition that the incremental plastic displacement reached 1/40, the J-R curves and the $J_i$ value were about $50{\sim}60$ percent of those for the incremental plastic displacement of 1/10.

• Journal of the Korean Geotechnical Society
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• v.38 no.9
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• pp.35-44
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• 2022

The cyclic triaxial strength test is commonly applied as a laboratory test for evaluating the liquefaction resistance ratio. However, the test procedure was not standardized in South Korea until recently; thus, the test results could significantly differ depending on the performer and apparatus, even when identical soil is used. In this study, the American and Japanese standards for the cyclic triaxial strength test were analyzed and the Korean standard was developed considering domestic circumstances. To verify the effectiveness of the standardization of liquefaction laboratory tests, several cases of cyclic triaxial strength tests were conducted and analyzed (1) following the Korean standard and (2) without following any specific instructions for the test procedure. Under (1), the deviation of the liquefaction resistance ratio dramatically decreased.

• Journal of the Korean Geotechnical Society
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• v.35 no.6
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• pp.39-48
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• 2019

This study investigated the lateral behavior of monopile embedded in the dry sand through cyclic lateral loading test using a centrifuge test. The sand sample for the experiment was the dry Jumunjin standard sand at 80% relative density and the friction angle of $38^{\circ}$. In the experimental procedure, firstly, it was determined the static lateral bearing capacity by performing the static lateral loading test to decide the cyclic load. This derived static lateral bearing capacity values of 30%, 50%, 80%, 120% were determined as the cyclic lateral load, and the number of cycle was performed 100 times. Through the results, the experiment cyclic p-y curve was calculated, and the cyclic p-y backbone curve by depth was derived using the derived maximum soil resistance point by the load. The initial slope at the same depth was underestimated than API (1987) p-y curves, and the ultimate soil resistance was overestimated than API (1987) p-y curves. In addition, the result of the comparison with the suggested dynamic p-y curve was that the suggested dynamic p-y curve was overestimated than the cyclic p-y backbone curve on the initial slope and soil resistance at the same depth. It is considered that the p-y curve should be applied differently depending on the loading conditions of the pile.