• Title/Summary/Keyword: cyclic curing

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Preparation of New Polyenaminonitriles Containing Cyclic and Methylene Units and Their Thermal Properties

  • Cho, Jeong-Hyun;Gong, Myoung-Seon
    • Macromolecular Research
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    • v.8 no.5
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    • pp.209-214
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    • 2000
  • Polyenaminonitriles containing cycloaliphatic and aliphatic units were prepared by interfacial or solution polymerization reaction of p-bis(1-chloro-2,2-dicyanovinyl) benzene (1) with 4-aminobenzyl-amine, 1-(2-aminoethyl)piperazine, 2-(aminomethyl)pyrrolidine and 4-(aminomethyl)piperidine. The chemical structure of the polymers was confirmed through a syntheses of the model compound. The resulting polymers possessed inherent viscosities of 0.29∼0.62 dL/g and they were easily soluble in polar aprotic solvents and common organic solvents. Thermal properties of the polymers such as curability and stability were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and infrared spectroscopy. The polymers exhibited a large exotherm in DSC analyses and underwent a curing reaction around 340-370$\^{C}$ to form insoluble materials. The polymers showed 70-80% residual weight at 600 $\^{C}$ under nitrogen.

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Interfacial Evaluation and Nondestructive Damage Sensing of Carbon Fiber Reinforced Epoxy-AT-PEI Composites using Micromechanical Test and Electrical Resistance Measurement (Micromechanical 시험법과 전기저항 측정을 이용한 탄소섬유 강화 Epoxy-AT-PEI복합재료의 비파괴적 손상 감지능 및 계면물성 평가)

  • Joung-Man Park;Dae-Sik Kim;Jin-Woo Kong;Minyoung Kim;Wonho Kim
    • Composites Research
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    • v.16 no.2
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    • pp.62-67
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    • 2003
  • Interfacial properties and damage sensing for the carbon fiber/epoxy-amine terminated (AT)-polyetherimide (PEI) composite were performed using microdroplet test and electrical resistance measurements. As AT-PEI content increased, the fracture toughness of epoxy-AT-PEI matrix increased, and interfacial shear strength (IFSS) increased due to the improved fracture toughness by energy absorption mechanisms of AT-PEI phase. The microdroplet in the carbon fiber/neat epoxy composite showed brittle microfailure mode. At 15 phr AT-PEI content ductile microfailure mode appeared because of improved fracture toughness. After curing, the change in electrical resistance $\Delta\textrm{R}$) with increasing AT-PEI content increased gradually because of thermal shrinkage. Under cyclic stress, in the neat epoxy case the reaching time until same stress was faster and their slope was higher than those of 15 phr AT-PEI. The result obtained from electrical resistance measurements under curing process and reversible stress/strain was correspondence well with matrix toughness properties.

Analysis of Settlement Characteristics and Strength of Cement Mixing Ratio for a Backfill Material at a Railway Abutment (철도교대 뒤채움재료의 시멘트 혼합 비율에 따른 강도 및 침하특성 분석)

  • Yang, Sang-Beom;Choi, Chan-Yong;Kim, Nak-Kyung;Kim, Tae-Kyun
    • Journal of the Korean Geotechnical Society
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    • v.32 no.9
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    • pp.29-36
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    • 2016
  • Backfill materials of rail abutment were commonly composed with cement treated aggregate, general aggregate and soil. The friction angle of cement treated aggregate increased up to $40^{\circ}$ or more due to strength enhancement. However, $30^{\circ}{\sim}35^{\circ}$ of friction angle was typically applied for in-situ condition. This phenomenon could cause over-designing, therefore, it is essential to determine reasonable material properties of cemented treated aggregate. In this study, a series of CBR tests and circular model tests have been conducted for cement treated aggregate, while changing cement mixing ratio. Based on test results, characteristics of settlement and strength have been analyzed quantitatively. The settlement of cement treated aggregate decreased with the number of cyclic loading and aging period. In addition, The strength increment ratio in CBR test increased up to 13~16 times at 28 days aging.

The Pharmacology and the Clinical Use of Selective Serotonin Reuptake Inhibitors (세로토닌 재흡수억제제의 약리학과 임상적용)

  • Lee, Min-Soo;Kim, Pyo-Han
    • Korean Journal of Biological Psychiatry
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    • v.2 no.2
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    • pp.205-217
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    • 1995
  • In comparison with tricyclic antidepressants(TCAs), one of the most interesting characteristics of selective serotonin reuptake inhibitors(SSRIs) is its structural differences, reveals different pharmacological properties. The applications at the moment are most effective in clinical applications to depression. The limited result of the research to date on the various applications of SSRIs has not revealed the total potential and applicability of SSRIs. Therefore, attending physicians utilizing SSRIs do not know the full capabilities of the drug on patients and what the patients may reap in terms of benefit from its curing elements. Physicians must first try to understand the full potential of SSRIs and its potential applications for it to be effective on patients. recently, it has been determined that SSRIs and other drugs when administered together may be more effective in the healing process because SSRIs complements and aids in the enhancement and effect of the other drugs. This article is written to give attention to the reader of the pharmacological properties and the clinical use of SSRIs. It is the authors's hope that continuous research on the particular aspects of SSRIs can aid the clinicians in the use of this SSRIs.

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Effect of Hardening of Granulated Blast Furnace Slag on the Liquefaction Strength (고로 수쇄슬래그의 경화가 액상화 강도에 미치는 영향)

  • Baek, Won-Jin
    • Journal of the Korean Geotechnical Society
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    • v.22 no.8
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    • pp.99-106
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    • 2006
  • In the present study, in order to clarify the effects of latent hydraulic property of granulated blast furnace slag (GBF slag) on the liquefaction, GBF slag was cured in the high temperature alkali water (adding the calcium hydroxide, pH=12, water temperature is about $30^{\circ}C$), and then the cyclic and the static tri-axial compression tests were carried out. Then the results were compared with those for Japanese standard sand of Toyoura sand and natural sand of Genkai sand. From the test results, it is clarified that the liquefaction strength of the GBF slag increases with the increase of the curing period by the hardening due to the latent hydraulic property. It is also shown that GBF slag with Dr=50% and 80% which was cured for 189 days in the fresh-water shows cohesion due to developing of latent hydraulic property. In addition, as for the liquefaction strength of GBFS during the hardening process, a linear relation between the cyclic stress ratio $R_{20}$ at the number of stress cycles Nc=20 and cohesion $C_{d}$ was observed. It is also clarified that the liquefaction strength for cured GBF slag in the high temperature alkali water is predicted by the cohesive strength or the unconfined compressive strength.

Comparative investigation of endurance and bias temperature instability characteristics in metal-Al2O3-nitride-oxide-semiconductor (MANOS) and semiconductor-oxide-nitride-oxide-semiconductor (SONOS) charge trap flash memory

  • Kim, Dae Hwan;Park, Sungwook;Seo, Yujeong;Kim, Tae Geun;Kim, Dong Myong;Cho, Il Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.4
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    • pp.449-457
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    • 2012
  • The program/erase (P/E) cyclic endurances including bias temperature instability (BTI) behaviors of Metal-$Al_2O_3$-Nitride-Oxide-Semiconductor (MANOS) memories are investigated in comparison with those of Semiconductor-Oxide-Nitride-Oxide-Semiconductor (SONOS) memories. In terms of BTI behaviors, the SONOS power-law exponent n is ~0.3 independent of the P/E cycle and the temperature in the case of programmed cell, and 0.36~0.66 sensitive to the temperature in case of erased cell. Physical mechanisms are observed with thermally activated $h^*$ diffusion-induced Si/$SiO_2$ interface trap ($N_{IT}$) curing and Poole-Frenkel emission of holes trapped in border trap in the bottom oxide ($N_{OT}$). In terms of the BTI behavior in MANOS memory cells, the power-law exponent is n=0.4~0.9 in the programmed cell and n=0.65~1.2 in the erased cell, which means that the power law is strong function of the number of P/E cycles, not of the temperature. Related mechanism is can be explained by the competition between the cycle-induced degradation of P/E efficiency and the temperature-controlled $h^*$ diffusion followed by $N_{IT}$ passivation.

Characteristics of Cyclic Drying-Wetting on Strength of Solidified Soil Mixed Porosity Silica (다공성 실리카를 혼합한 경화토의 건습반복 강도특성)

  • Kim, Donggeun;Bang, Seongtaek;Oh, Sewook
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.10
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    • pp.29-34
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    • 2014
  • In order to examine strength properties depended on climate changes of solidified soil amended by porosity silica which enhance harms of cement, this study conducts a wetting and drying repetition test and then, attempts to verify strength properties before and after solidified soil gets environmental influence. Test pieces for the unconfined compression test changed the mixing ratio of solidified soil compared to mixed soil weigh to 5 %, 10 % and 15 %. For each step, it was created by mixing 0.5 %, 1.0 % and 1.5 % of wood chips, and curing period for 7, 14, and 28 days. Then, the wetting and drying repetition process was repeated 0, 3, 6, and 12 cycles to analyze mechanical properties. To also evaluate changes of relative dynamic elastic modulus before and after the wetting and drying, dynamic elastic modulus tests were conducted when each cycle was completed.

A Study on the Effects of Sobokchukeo-Tang on the Isolated Uterine Muscle of Rats (소복축어탕(少腹逐瘀湯)이 흰쥐의 적출 자궁에 미치는 영향)

  • Jin, Cheon-Sik;Yang, Seung-Jeong
    • The Journal of Korean Obstetrics and Gynecology
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    • v.18 no.4
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    • pp.72-84
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    • 2005
  • Purpose : This study was carried out to investigate the relaxational response to the water extract of Sobokchukeo-Tang(SCT) in isolated uterine muscle in rats. Methods : Segments of uterine muscle obtained from female rats immediately after delivery were mounted in organ baths superfused on a polygraph. The effects of SCT on the tension of potassium induced contracture were studied in rat uterine smooth muscles. All experiments were performed in Krebs-Henseit solution which was aerated with 100% oxygen and kept at $37^{\circ}C$. Results : KCI did not produce contraction in calcium-free solution, but $CaCl_2$ induced concentration-dependent contraction after depolarizing with KCI. SCT inhibited the tonic contraction of uterine muscle as dose dependent manner. And when SCT was pretreated in calcium-free medium, it showed more powerful relaxational effect. The effect of 10mg/ml concentration of SCT was equal to that of 9nM and 70nM of nifedipine and verapamil and the relaxational effect of SCT on rat uterine muscle can be assumed to be concerned with the action of cyclic AMP. But the action mechanism of relaxation on the rat uterine muscles were concerned with the calcium channel. Conclusion : From this study we could suggest that the relaxtional effect of SCT on uterine muscle be available to preventing and curing dysmenorrhea.

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Preparation of Solid Polymer Electrolytes by Ultraviolet Radiation and the Electrochemical Properties of Activated Carbon Supercapacitor Adopting Them (자외선 조사에 의한 고체 고분자 전해질의 제조와 이를 채용한 활성탄 수퍼커패시터의 전기화학적 특성)

  • Won, Jung Ha;Kim, Yong Joo;Lee, Young-Gi;Kim, Kwang Man;Kim, Jong Huy;Ko, Jang Myoun
    • Journal of the Korean Electrochemical Society
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    • v.16 no.2
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    • pp.91-97
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    • 2013
  • Solid polymer electrolyte films are prepared by ultraviolet radiation in the mixtures of an ionic liquid salt (1-ethyl-3-methylimidazolium tetrafluoroborate, $EMIBF_4$) and solvent (acetonitrile (ACN) or propylene carbonate(PC)), and an oligomer (poly(ethylene glycol)diacrylate, PEGDA, 45-60 wt.%). Electrochemical properties of activated carbon supercapacitors adopting the solid polymer electrolyte films as a separator are also examined by cyclic voltammetry and impedance measurement techniques. As a result, the supercapacitor adopting the PEGDA as much as 45 wt.% exhibits a superior capacitance of $46Fg^{-1}$ at $20mVs^{-1}$. It seems that this is due to fast kinetics of ion conduction by sufficient film flexibility, which can be allowed by comparatively weak ultraviolet curing of small anount of the PEGDA.