• Transactions of the Korean hydrogen and new energy society
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• v.9 no.4
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• pp.169-176
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• 1998

An experimental study on effect of vapor-cooled heat stations in a 5.5 liter cryogenic vessel has been performed. The cryogenic vessel is made of stainless steel of thickness of 1mm and insulated by the combined insulation of vacuum, MLI(multi-layer insulation) and vapor-cooled radiation shield. Vapor-cooled heat stations are also constructed based on the 1-dimensional thermal analysis to reduce the heat inleak through a filling tube. Thermal analysis indicates that the vapor-cooled heat stations can substantially enhance the performance of vessel for cryogenic fluids with high $C_p/h_{fg}$ where $C_p$ the specific heat and $h_{fg}$ the heat of vaporization, such as $LH_2$ and LHe. The experimental results for $LN_2$ shows that the total heat inleak into inner vessel consists of 14% radiation and 86% conduction through the filling tube. Therefore, it is expected that the conduction heat in leak of the vessel for high $C_p/h_{fg}$ cryogenic fluids can be significantly reduced. powders. The amount of copper coating was 20wt%. In order to examine corrosion behavior of the electrodes, the corrosion current and the current density, in 6M KOH aqueous solution after removal of oxygen in the solution, were measured by potentiodynamic and cyclic voltamo methods. The results showed that Co in the alloy increased corrosion resistance of the electrode whereas Ni decreased the stability of the electrode during the charge-discharge cycles. The electrode used Si sealant as a binder showed a lower corrosion current density than the electrode used PTFE and the electrode used Cu-coated alloy powders showed the best corrosion resistance.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.281-286
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• 1989

The redox properties of benzophydroxamic acid (Hben) and its oxovanadium complex, $VO(Ben)_2$ has been studied by the use of polarograpy and cyclic voltammetry. The radical anions of Hben seem to be generated in acetone. The wave at -0.05V vs. Ag/AgCl electrode might be attributed to the formation of radical anion and the wave at -1.78V vs. Ag/AgCl electrode might be attributed the formation of radical dianion. The $VO(Ben)_2$ exhibits one oxidation wave at + 0.55V and two reduction waves at -0.15V and -1.30V vs. Ag/AgCl electrode; the oxidation is reversible one electron process $(VO(ben)_2 {\rightleftharpoons} VO(ben)^+ + e)$. The reduction wave at -0.15V is quasireversible and is arised from the formation of radical anion,$VO(Ben)_2^-$. The second reduction wave at -1.30V is irreversible and this reduction process produces vanadium(III). This oxygen containing ligand of Hben seems to reduce the stability of + 4 oxidation state of vanadium while the sulfur or nitrogen donor of the ligands stabilize the + 4 oxidation state of vanadium when comparisons are made among several oxovanadium complexes.

• Korean Journal of Materials Research
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• v.9 no.10
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• pp.1025-1031
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• 1999

Alloys of TiAl with six different compositions. i. e., Ti-(42, 44)Al-2Nb-4V. Ti-(42, 44)Al-4Nb-2V and Ti -(42, 44)Al-4Nb-2Cr, were manufactured by arc-melting. and their oxidation behavior was studied. Both isothermal and cyclic oxidation tests were performed at 700, 800 and $900^{\circ}C$ in air for 50hr. The oxidation resistance increased in the order of Ti-(42, 44)Al-2Nb-4V, Ti-(42, 44)Al-4Nb-ZV and Ti-(42, 44)Al-4Nb-2Cr. It was found that V was a deleterious element, while Cr was a beneficial element in terms of oxidation resistance. During oxidation, a simultaneous interdiffusion was observed. All the constituent elements in the base alloys diffused outward. whereas oxygen from the atmosphere diffused inward, to form triple oxide layers composed of an outermost $\textrm{TiO}_2$ layer. upper ($\textrm{TiO}_2+\textrm{Al}_2\textrm{O}_3$) mixed layer, and lower $\textrm{TiO}_2$-rich layer.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.34 no.3
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• pp.245-253
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• 2001

To investigate the effects of hydromechanical and textural characteristics of sediment deposits on the cultivation of Manila clam, Ruditapes philippinarum surface and sub-surface core sediments were collected seasonally in Gomso tidal flat. Grain size distribution were analyzed to investigate the annual variation of sediment texture. In winter unimodal distribution of grain size with the peak at $5\phi$ is dominant However, during the summer sediment texture become a little bit coarser and grain size distribution shows the peaks at $4\~5 \phi$. Optimum sediment texture for the cultivation of manila clam, R. philippinarum was found to be sandy silt in which mean Brain size was between 4 and $5 \phi$ with the sand content less than $50\%$ and clay content of $5\~10\%$. Mechanical and hydrological characteristics of sediment deposits were also studied in the laboratory and the results were applied to the numerical simulation for the behavior of surface sediment subjected to the cyclic loading from sea-water level change. Results of numerical simulation illustrate that the permeability of sediment had to be maintained in the range of $10^{-11}\sim10^{-12}m^2$ to ensure the proper sedimentological environment for the cultivation of manila clam, R. philippinarum. The deposits of virtually impermeable mud layer, with the threshold thickness of 4 cm, would be very hazardous to clam habitat.

• Journal of the Earthquake Engineering Society of Korea
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• v.10 no.1 s.47
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• pp.41-49
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• 2006

Through the 1982 Urahawa-ohi and the 1995 Kobe earthquakes, a number of bridge columns were observed to develop a flexural-shear failure due to the bond slip as a consequence of premature termination of the column longitudinal reinforcement. Because the seismic behavior of RC bridge piers is largely dependent on the performance of the plastic hinge legion of RC bridge piers, it is desirable that the seismic capacity of RC bridge pier is to evaluate as a curvature ductility. The provision for the lap splice of longitudinal steel was not specified in KHBDS(Korea Highway Bridge Design Specification) before the implementation of 1992 seismic design code, but the lap splice of not more than 50%, longitudinal reinforcement was newly allowed in the 2005 version of the KHBDS. The objective of this research is to investigate the distribution and ductility of the curvature of RC bridge column with the lap splice of longitudinal reinforcement in the plastic hinge legion. Six (6) specimens were made in 600 mm diameter with an aspect ratio of 2.5 or 3.5. These piers were cyclically subjected to the quasi-static loads with the uniform axial load of $P=0.1f_{ck}A_g$. According to the slip failure of longitudinal steels of the lap spliced specimen by cyclic loads, the curvatures of the lower and upper parts of the lap spliced region were bigger and smaller than the corresponding paris of the specimen without a lap splice, respectively. Therefore, the damage of the lap spliced test column was concentrated almost on the lower part of the lap spliced region, that appeared io be failed in flexure.

• Journal of the Earthquake Engineering Society of Korea
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• v.16 no.5
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• pp.1-11
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• 2012

In this paper, non-linear analysis was performed for Reinforced Concrete (RC) walls using different macroscopic models subjected to cyclic loading, and the analytical results were compared with previous experimental studies of RC walls. ASCE41-06 (American Society of Civil Engineers) specifies that the hysteresis behaviors of RC walls are different due to the aspect ratio of the walls. For a comparison between analytical and experimental results, a slender wall with an aspect ratio exceeding 3.0 and a squat wall with an aspect ratio of 1.0 were selected among previous research works. For the non-linear analysis, each test specimen was modeled using two different macroscopic methods: the first representing the flexural behavior of the RC wall, and the second considering the diagonal shear in the web of the wall. Through nonlinear analysis of the considered RC walls, the analytical difference of a slender wall was negligible due to the different macroscopic modeling methods. However, the squat wall was significantly affected by the considered components of the modeling method. For an accurate performance evaluation of the RC building with squat walls, it would be reasonable to use a macroscopic model considering diagonal shear.

• Journal of the Korean Chemical Society
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• v.34 no.6
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• pp.561-568
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• 1990

Voltammetric behavior of some light lanthanide ions (La$^{3+}$, Pr$^{3+}$, Nd$^{3+}$, Sm$^{3+}$, and Eu$^{3+}$) in various supporting electrolytes has been investigated by several electrochemical techniques. The peak potentials and the peak currents, their dependency on the concentration, temperature and pH effects, the reversibility of the electrode reactions are described. The reduction of La$^{3+}$, Pr$^{3+}$ and Nd$^{3+}$ in 0.1 M lithium chloride proceeds by a three-electron change directly to the metallic state (Ln$^{3+}$ ＋ 3e- → Ln$^0$) and charge transfer is totally irreversible. However, the reduction of Sm$^{3+}$ in 0.1 M tetramethylammonium iodide and Eu$^{3+}$ in 0.1 M lithium chloride proceeds in two stages (Ln$^{3+}$ ＋ e- → Ln$^{2+}$ and Ln$^{2+}$ ＋ 2e- → Ln$^0$). At pH values lower than ca.4 the hydrated lanthanide species (Ln(OH)$^{2+}$) reduced before the lanthanide ions (Ln$^{3+}$) due to the catalytic effect of hydrogen ions, and peak current increase with in the order Eu$^{3+}$ < Sm$^{3+}$ < Nd$^{3+}$ < Pr$^{3+}$ < La$^{3+}$ in differential pulse polarography. Some representative plots of $i_{pc}V^{-1/2} (proportional to current function) vs. V show considerable influence of hydrogen ion/lanthanide ion concentration in cyclic voltammetry. It is shown that a reaction of lanthanide ions with proton and/or water and catalytic reaction is enhanced at lower pH and at decreased lanthanide ion concentration.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.390-396
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• 2012

In order to understand the nature of dendritic zinc growth, electrochemical zinc redox reaction on nickel plate was investigated in aqueous solutions containing different concentrations, 0.2, 0.1 and 0.02 $mol{\cdot}dm^{-3}$ (M), of zinc sulfate ($ZnSO_4$) or zinc chloride ($ZnCl_2$). Zinc ion was efficiently reduced and oxidized on nickel in the high-concentration (0.2 M) solution, whereas relatively poor efficiency was obtained from the other low-concentration solutions (0,1 and 0.02 M). Cyclic voltammetry (CV) analysis revealed that the 0.2 M electrolyte solution decomposes at more positive potentials than the 0.1 and the 0.02 M solutions. These results suggested that the concentration of electrolyte solution and anion would be an important factor that suppresses the reaction of the zinc dendrite formation. Scanning Electron Microscopy (SEM) data revealed that the shape of dendritic zinc and its growing behavior were also influenced by electrolyte concentration.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.411-417
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• 2013

To use as an anode material of lithium secondary battery, graphite-silicon composite powders are prepared by ball-milling with silicon nanoparticles (average diameter 100 nm, 0~50 wt%) and graphite powder (average diameter $15{\mu}m$) and their electrochemical properties are examined. As the silicon content increases, the graphite becomes smaller by the ball-milling and amorphous phase appears whereas the silicon do not suffer the change of nanocrystalline phases and embeds within the amorphous phase of graphite. Cyclic voltammetry at low scan rate reveals that typical oxidation peaks of graphite and silicon appear at 0.2~0.35 and 0.55~0.6 V, respectively, with higher reversibility for repeated cycles. In contrast, the high-scan-rate redox behavior is very irreversible for repeated cycles. High irreversible capacity is exhibited in the initial charging-discharging cycles, but it diminishes as the cycle number increases. The saturated discharge capacity achieves about 485 mAh $g^{-1}$ at 50th cycle for the composite of Si 20 wt%. This is due to the formation of amorphous graphite morphology by the adequate composition (C:Si=8:2 w/w), which efficiently buffers the volume change during alloying/dealloying between silicon and lithium.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.4
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• pp.94-103
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• 2016

For elevated railway station on which track is connected with superstructure of station, structural vibration level and structure-borne-noise level has exceeded the reference level due to structural characteristics which transmits vibration directly. Therefore, existing elevated railway station is in need of economical and effective vibration reduction method which enable train service without interruption. In this study, structural vibration non-transmissible system which is applied to vibroisolating material for column member is developed to reduce vibration. That system is cut covering material of the column section using water-jet method and is installed with vibroisolating material on cut section. To verify vibration reduction effect and structural performance for structural vibration non-transmissible system, impact hammer test and cyclic lateral load test are performed for 1/4 scale test specimens. It is observed that natural period which means vibration response characteristics is shifted, and damping ratio is increased about 15~30% which means that system is effective to reduce structural vibration through vibration test. Also load-displacement relation and stiffness change rate of the columns are examined, and it is shown that ductility and energy dissipation capacity is increased. From test results, it is found that vibration non-transmissible system which is applied to column member enable to maintains structural function.