• Clean Technology
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• v.24 no.4
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• pp.357-364
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• 2018

Studies on the production of biogas from third generation biomass, such as micro- and macroalgae, have been conducted through experiments of various scales. In this paper, we investigated the feasibility of commercialization of integrated combined heat and power (CHP) production using biogas derived from macroalgae, i.e., seaweed biomass. For this purpose, an integrated CHP plant of industrial scale, consisting of solid oxide fuel cells, gas turbine and organic Rankine cycle, was designed and simulated using a commercial process simulator. The cost of each equipment in the plant was estimated through the calculated heat and mass balances from simulation and then the techno-economic analysis was performed. The designed integrated CHP process produces 68.4 MW of power using $36ton\;h^{-1}$ of biogas from $62.5ton\;h^{-1}$ (dry basis) of brown algae. Based on these results, various scenarios were evaluated economically and the levelized electricity cost (LEC) was calculated. When the lifetime of SOFC is 5 years and its stack price is $$225kW^{-1}$, the LEC was 12.26 ¢ $kWh^{-1}$, which is comparable to the conventional fixed power generation.

• Korean Journal of Materials Research
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• v.32 no.9
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• pp.369-378
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• 2022

The recycling of solid waste materials to fabricate carbon-based electrode materials is of great interest for low-cost green supercapacitors. In this study, porous carbon foam (PCF) was prepared from waste floral foam (WFF) as an electrode material for supercapacitors. WFF was directly carbonized at various temperatures of 600, 800, and 1,000 ℃ under an inert atmosphere. The WFF-derived PCF (C-WFF) was found to have a specific surface area of 458.99 m²/g with multi-modal pore structures. The supercapacitive behavior of the prepared C-WFF was evaluated using a three-electrode system in a 6 M KOH aqueous electrolyte. As a result, the prepared C-WFF as an active material showed a high specific capacitance of 206 F/g at 1 A/g, a rate capability of 36.4 % at 20 A/g, a specific power density of 2,500 W/kg at an energy density of 2.68 Wh/kg, and a cycle stability of 99.96 % at 20 A/g after 10,000 cycles. These results indicate that the C-WFF prepared from WFF could be a promising candidate as an electrode material for high-performance green supercapacitors.

• Journal of Navigation and Port Research
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• v.47 no.2
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• pp.106-119
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• 2023

Due to global decarbonization movement and tightening of maritime emissions restrictions, the shipping industry is going to switch to alternative fuels. Among candidates of alternative fuel, methanol is promising for decreasing SOx and CO2 emissions, resulting in minimum climate change and meeting the goal of green shipping. In this study, a novel combined system of direct methanol solid oxide fuel cells (SOFC), proton exchange membrane fuel cells (PEMFC), gas turbine (GT), and organic Rankine cycle (ORC) targeted for marine vessels was proposed. The SOFC is the main power generator of the system, whereas the GT and PEMFC could recover waste heat from the SOFC to generate useful power and increase waste heat utilizing efficiency of the system. Thermodynamics model of the combined system and each component were established and analyzed. Energy and exergy efficiencies of subsystems and the entire system were estimated with participation of the first and second laws of thermodynamics. The energy and exergy efficiencies of the overall multigeneration system were estimated to be 76.2% and 30.3%, respectively. The combination of GT and PEMFC increased the energy efficiency by 18.91% compared to the SOFC stand-alone system. By changing the methanol distribution ratio from 0.05 to 0.4, energy and exergy efficiencies decreased by 15.49% and 5.41%, respectively. During the starting up and maneuvering period of vessels, a quick response from the power supply system and propulsion plant is necessary. Utilization of PEMFC coupled with SOFC has remarkable meaning and benefits.

• Earthquakes and Structures
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• v.26 no.4
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• pp.261-267
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• 2024

With the increase in the exploitation depth of offshore oil and gas, it is possible to control the global buckling of deep-sea pipelines by the snake lay method. Previous studies mainly focused on the analysis of critical buckling force and critical temperature of pipelines under the snake-like laying method, and pipelines often suffer structural failure due to seismic disasters during operation. Therefore, seismic action is a necessary factor in the design and analysis of submarine pipelines. In this paper, the seismic action of steel pipes in the operation stage after global buckling has occurred under the active control method is analyzed. Firstly, we have established a simplified finite element model for the entire process cycle and found that this modeling method is accurate and efficient, solving the problem of difficult convergence of seismic wave and soil coupling in previous solid analysis, and improving the efficiency of calculations. Secondly, through parameter analysis, it was found that under seismic action, the pipe diameter mainly affects the stress amplitude of the pipeline. When the pipe wall thickness increases from 0.05 m to 0.09 m, the critical buckling force increases by 150%, and the maximum axial stress decreases by 56%. In the pipe soil interaction, the greater the soil viscosity, the greater the pipe soil interaction force, the greater the soil constraint on the pipeline, and the safer the pipeline. Finally, the pipeline failure determination formula was obtained through dimensionless analysis and verified, and it was found that the formula was accurate.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.1
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• pp.94-131
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• 2007

A review on the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering in 2004 and 2005 has been done. Focus has been put on current status of research in the aspect of heating, cooling, air-conditioning, ventilation, sanitation and building environment. The conclusions are as follows. (1) Most of fundamental studies on fluid flow were related with heat transportation of facilities. Drop formation and rivulet flow on solid surfaces were interesting topics related with condensation augmentation. Research on micro environment considering flow, heat, humidity was also interesting for comfortable living environment. It can be extended considering biological aspects. Development of fans and blowers of high performance and low noise were continuing topics. Well developed CFD and flow visualization(PIV, PTV and LDV methods) technologies were widely applied for developing facilities and their systems. (2) The research trends of the previous two yews are surveyed as groups of natural convection, forced convection, electronic cooling, heat transfer enhancement, frosting and defrosting, thermal properties, etc. New research topics introduced include natural convection heat transfer enhancement using nanofluid, supercritical cooling performance or oil miscibility of $CO_2$, enthalpy heat exchanger for heat recovery, heat transfer enhancement in a plate heat exchanger using fluid resonance. (3) The literature for the last two years($2004{\sim}2005$) is reviewed in the areas of heat pump, ice and water storage, cycle analysis and reused energy including geothermal, solar and unused energy). The research on cycle analysis and experiments for $CO_2$ was extensively carried out to replace the Ozone depleting and global warming refrigerants such as HFC and HCFC refrigerants. From the year of 2005, the Gas Engine Heat Pump(GHP) has been paid attention from the viewpoint of the gas cooling application. The heat pipe was focused on the performance improvement by the parametric analysis and the heat recovery applications. The storage systems were studied on the performance enhancement of the storage tank and cost analysis for heating and cooling applications. In the area of unused energy, the hybrid systems were extensively introduced and the life cycle cost analysis(LCCA) for the unused energy systems was also intensively carried out. (4) Recent studies of various refrigeration and air-conditioning systems have focused on the system performance and efficiency enhancement. Heat transfer characteristics during evaporation and condensation are investigated for several tube shapes and of alternative refrigerants including carbon dioxide. Efficiency of various compressors and expansion devices are also dealt with for better modeling and, in particular, performance improvement. Thermoelectric module and cooling systems are analyzed theoretically and experimentally. (5) According to the review of recent studies on ventilation systems, an appropriate ventilation systems including machenical and natural are required to satisfied the level of IAQ. Also, an recent studies on air-conditioning and absorption refrigeration systems, it has mainly focused on distribution and dehumidification of indoor air to improve the performance were carried out. (6) Based on a review of recent studies on indoor environment and building service systems, it is noticed that research issues have mainly focused on optimal thermal comfort, improvement of indoor air Quality and many innovative systems such as air-barrier type perimeter-less system with UFAC, radiant floor heating and cooling system and etc. New approaches are highlighted for improving indoor environmental condition as well as minimizing energy consumption, various activities of building control and operation strategy and energy performance analysis for economic evaluation.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.592-602
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• 2014

In the Integrated Gasification Combined Cycle (IGCC), the stability of the gasifier has strong influences on the rest of the plant as it supplies the feed to the rest of the power generation system. In order to ensure a safe and stable operation of the entrained-flow gasifier and for protection of the gasifier wall from the high internal temperature, the solid slag layer thickness should be regulated tightly but its control is hampered by the lack of on-line measurement for it. In this study, a previously published dynamic simulation model of a Shell-type gasifier is reproduced and two different linear model predictive control strategies are simulated and compared for multivariable control of the entrained-flow gasifier. The first approach is to control a measured secondary variable as a surrogate to the unmeasured slag thickness. The control results of this approach depended strongly on the unmeasured disturbance type. In other words, the slag thickness could not be controlled tightly for a certain type of unmeasured disturbance. The second approach is to estimate the unmeasured slag thickness through the Kalman filter and to use the estimate to predict and control the slag thickness directly. Using the second approach, the slag thickness could be controlled well regardless of the type of unmeasured disturbances.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.131.1-131.1
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• 2010

This study was conducted for engineering optimization for the gasification process which is the key factor for success of Taean IGCC gasification plant which has been driven forward under the government support in order to expand to supply new and renewable energy and diminish the burden of the responsibility for the reduction of the green house gas emission. The gasification process consists of coal milling and drying, pressurization and feeding, gasification, quenching and HP syngas cooling, slag removal system, dry flyash removal system, wet scrubbing system, and primary water treatment system. The configuration optimization is essential for the high efficiency and the cost saving. For this purpose, it was designed to have syngas cooler to recover the sensible heat as much as possible from the hot syngas produced from the gasifier which is the dry-feeding and entrained bed slagging type and also applied with the oxygen combustion and the first stage cylindrical upward gas flow. The pressure condition inside of the gasifier is around 40~45Mpg and the temperature condition is up to $1500{\sim}1700^{\circ}C$. It was designed for about 70% out of fly ash to be drained out throughout the quenching water in the bottom part of the gasifier as a type of molten slag flowing down on the membrane wall and finally become a byproduct over the slag removal system. The flyash removal system to capture solid particulates is applied with HPHT ceramic candle filter to stand up against the high pressure and temperature. When it comes to the residual tiny particles after the flyash removal system, wet scurbbing system is applied to finally clean up the solids. The washed-up syngas through the wet scrubber will keep around $130{\sim}135^{\circ}C$, 40~42Mpg and 250 ppmv of hydrochloric acid(HCl) and hydrofluoric acid(HF) at maximum and it is turned over to the gas treatment system for removing toxic gases out of the syngas to comply with the conditions requested from the gas turbine. The result of this study will be utilized to the detailed engineering, procurement and manufacturing of equipments, and construction for the Taean IGCC plant and furthermore it is the baseline technology applicable for the poly-generation such as coal gasification(SNG) and liquefaction(CTL) to reinforce national energy security and create new business models.

• Bulletin of the Korean Chemical Society
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• v.27 no.9
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• pp.1310-1314
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• 2006

Sulfur-substituted $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$ $(0\;\leq\;x\;\leq\;0.1)$ layered oxides have been prepared by solid state reaction under inert atmosphere. From powder X-ray diffraction analyses, all the present lithium manganates were found to be crystallized with monoclinic-layered structure. Electrochemical measurements clearly demonstrated that, in comparison with the pristine $LiMn_{0.9}Cr_{0.1}O_2$, the sulfur-substituted derivatives exhibit smaller discharge capacities for the entire cycle range but the recovery of discharge capacity after the initial several cycles becomes faster upon sulfur substitution. The effect of the sulfur substitution on the chemical bonding nature of $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$has been investigated using X-ray absorption spectroscopic (XAS) analyses at Mn and Cr K-edges. According to Mn K-edge XAS results, the trivalent oxidation state of manganese ion remains unchanged before and after the substitution whereas the local structure around manganese ions becomes more distorted with increasing the substitution rate of sulfur. On the other hand, the replacement of oxygen with sulfur has negligible influence on the local atomic arrangement around chromium ions, which is surely due to the high octahedral stabilization energy of $Cr^{+III} $ ions. Based on the present experimental findings, we have suggested that the decrease of discharge capacity upon sulfur substitution is ascribable to the enhanced structural distortion of $MnO_6$ octahedra and/or to the formation of covalent Li-S bonds, and the accompanying improvement of cyclability would be related to the depression of Mn migration and/or to the pillaring effect of larger sulfur anion.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.3
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• pp.171-180
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• 2015

This study was performed on the removal of Cs, one of the main high- radioactive nuclides contained in the high-radioactive seawater waste (HSW), by adsorption with IE911 (crystalline silicotitanate type). For the effective removal of Cs and the minimization of secondary solid waste generation, adsorption of Cs by IE911 (hereafter denoted as IE911-Cs) was effective to carry out in the m/V (ratio of absorbent weight to solution volume) ratio of 2.5 g/L, and the adsorption time of 1 hour. In these conditions, Cs and Sr were adsorbed about 99% and less than 5%, respectively. IE911-Cs could be also expressed as a Langmuir isotherm and a pseudo-second order rate equation. The adsorption rate constants (k₂) were decreased with increasing initial Cs concentrations and particle sizes, and increased with increasing ratios of m/V, solution temperatures and agitation speeds. The activation energy of IE911-Cs was about 79.9 kJ/mol. It was suggested that IE911-Cs was dominated by a chemical adsorption having a strong bonding form. From the negative values of Gibbs free energy and enthalpy, it was indicated that the reaction of IE911-Cs was a forward, exothermic and relatively active at lower temperatures. Additionally, the negative entropy values were seen that the adsorbed Cs was evenly distributed on the IE911.

• Korean Journal of Food Science and Technology
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• v.43 no.1
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• pp.98-104
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• 2011

The storage quality of fresh buckwheat sprouts, as influenced by pretreatment and packaging within processing steps, was investigated to establish appropriate postharvest handling treatment for the commodity. After harvest, the sprouts were dipped in chlorine water (100 ppm), rinsed twice with clean water, pre-cooled with iced water, de-watered, and packed in plastic trays. Sprout samples taken from each processing step were stored at $5^{\circ}C$ for 6 days to measure quality attributes. Viable cell counts of mesophilic aerobes and coliform bacteria were lower by about 1 log scale in the postharvest treated samples compared to an untreated control, although the initial microbial reduction due to the postharvest treatments was offset by cell growth during storage. All sprout samples showed a decrease of fresh weight by approximately 4% after 6 days of storage. However, moisture and soluble solid contents were maintained at the initial levels of the sprouts. No significant difference in surface color was observed among sample treatments. For sensory properties including discoloration, wilting, decay, and visual quality, there were no significant differences among sample treatments. The present results suggest that proper postharvest processing treatments can exert positive effects on extending the shelf-life of fresh buckwheat sprout.