• Title/Summary/Keyword: cycleSolid

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Study on Reversible Electrolysis Characteristic of a Planar Type SOFC (평판형 고체산화물 연료전지의 양방향 수전해 특성 연구)

  • CHOI, YOUNGJAE;AHN, JINSOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.657-662
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    • 2017
  • This paper presents the reversible electrolysis characteristics of a solid oxide fuel cell (SOFC) using a $10{\times}10cm^2$ anode supported planar cell with an active area of $81cm^2$. In this work, current-voltage characteristic test and reversible electrolysis cycle test were carried out sequentially for 2,114 hours at a furnace temperature of $700^{\circ}C$. The current-voltage characteristics for reversible electrolysis mode was measured at a current of ${\pm}26.7A$ under various $H_2O$ utilization conditions. The reversible electrolysis cycle was performed 50 times at a current of ${\pm}32.4A$. As a result, The performance degradation of SOEC mode was larger than that of SOFC mode.

Manufacturing of Product by Semi-Solid Forging (반용융 단조품의 제조)

  • Park, Hyung-Jin;Kang, Chung-Gil;Kim, Byung-Min;Choi, Jae-Chan
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.6
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    • pp.45-51
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    • 1999
  • The semi-solid forging is a new forging technology in which the billet is heated to the semi-solid state coexisting liquid and solid phase for making globular microstructure and subsequently formed. As the semi-solid forging is compared with conventional casting such as die casting and squeeze casting for the characteristics of its process, the product without inner defects such as gas porosity and segregation can be obtained and its microstructure is globular grain. Simutaneously, its mechanical properties are improved by globular microstructure and the lower temperature of the slug causes the cycle time of manufacturing to be shortened and the die life to be lengthened. As it is compared with conventional cold and hot forging, it is possible to minimize the equipment of production owing to a lower forming load and reduce the number of process by a followed treatment for complex shaped product. Therefore it is needed to confirm the quality of a semi-solid forged product by defining its characteristics quantitatively under these advantages. This paper investigates the formability of a master cylinder by its forming variables. And the microstructural characteristics and mechanical property of it is also studied.

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Redox Behaviors of NiO/YSZ Anode Tube in Anode-Supported Flat Tubular Solid Oxide Fuel Cells (평관형 고체 산화물 연료전지의 연료극 지지체 NiO/YSZ의 환원 및 재산화 거동 특성)

  • Song, Rak-Hyun;Lee, Gil-Yong;Shin, Dong-Ryul
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.82-89
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    • 2006
  • The redox behaviors of anode-supported flat tube for solid oxide fuel cell has been studied. The mass change of the extruded NiO/YSZ anode flat tube during redox cycling was examined by thermogravimetric analysis(TGA). The result of TGA was shown a rapidly mass change in the range of $455\;-\;670^{\circ}C$ and the reoxidation of the NiO/YSZ anode was almost completed at $750^{\circ}C$. The starting temperature of reoxidation and the maximum temperature of oxidation rate decreased with increasing the reoxidation cycle, which is attributed to the increased porosity caused by volume change. Bending strengths of the NiO/YSZ anode after redox cycling were 96 - 80 MPa and the bending strength decreased slightly with increasing the redox cycle. On the other hand, the bending strength of the NiO/YSZ anode with electrolyte showed 130 MPa after first redox cycling but decreased rapidly with increasing the redox cycle. From the results of the bending test and the microstructure observation, we conclude that the crack initiation of the electrolyte-coated NiO/YSZ anode was induced easily at interface of electrolyte/anode tube and propagated cross the electrolyte.

Electrochemical Properties and Crystal Structure of $Li_{1+x}Mn_2O_4$($0\leqx\leq0.075$) Synthesized at Solid State Method (고상법에 의한 $Li_{1+x}Mn_2O_4$ ($0\leqx\leq0.075$) 의 결정구조와 전기화학적 특성)

  • 박종광;고건문;임성훈;황종선;한병성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.383-390
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    • 2001
  • We have investigated the L $i_{1+x}$M $n_2$ $O_4$system as a cathode material for lithium rechargeable batteries. To improve the cycle performance of spinel LiM $n_2$ $O_4$ as the cathode of 4V class lithium secondary batteries, spinel phase L $i_{1+x}$M $n_2$ $O_4$(x=0, 0.025, 0.05, 0.075) was prepared at 75$0^{\circ}C$ for 48h. The preparation of L $i_{1+x}$M $n_2$ $O_4$ from L $i_2$ $O_3$ and Mn $O_2$ under air is studied. The compounds were synthesized by using solid-state reaction. Structural refinements were carried out with a Rietveld-refinement program. Electrochemical properties were examined using the Li/L $i_{1+x}$M $n_2$ $O_4$ cells. The capacity of L $i_{1+x}$M $n_2$ $O_4$ decreases with increases lithium content, while the cycle life improves. The initial discharge capacity are 118mAh/g and 116mAh/g for LiM $n_2$ $O_4$ decreases with increases lithium content, while the cycle life improves. The initial discharge capacity are 118mAh/g and 116mAh/g for LiM $n_2$ $O_4$ and L $i_{1.025}$M $n_2$ $O_4$, respectively.pectively.

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Anti-proliferative Effect of Paclitaxel in Multicellular Layers of Human Cancer Cells (다층 배양된 암세포에서 파크리탁셀의 항증식효과 분석)

  • Kang, Choon-Mo;Lee, Joo-Ho;Cha, Jung-Ho;Kuh, Hyo-Jeong
    • Journal of Pharmaceutical Investigation
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    • v.36 no.1
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    • pp.1-9
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    • 2006
  • Human solid tumors exhibit a multicellular resistance (MCR) resulting from limited drug penetration and decreased sensitivity of tumor cells when interacting with their microenvironments. Multicellular cultures represent solid tumor condition in vivo and provide clinically relevant data. There is little data on antitumor effect of paclitaxel (PTX) in multicellular cultures although its MCR has been demonstrated. In the present study, we evaluated antiproliferative effects of PTX in multicellular layers (MCL) of DLD-1 human colorectal carcinoma cells. BrdU labeling index (LI), thickness of MCL, cell cycle distribution and cellular uptake of calcein were measured before and after exposure to PTX at 0.1 to 50 ${\mu}M$ for 24, 48 and 72 hrs. BrdU LI and thickness of MCL showed a concentration- and time-dependent decrease and the changes in both parameters were similar, i.e., 34.2% and 40.6% decrease in BrdU LI and thickness, respectively, when exposed to $50\;{\mu}M$ for 72 hr. The DLD-1 cells grown in MCL showed increase in $%G_{0}/G_{1}$ and resistance to cell cycle arrest and apoptosis compared to monolayers. Calcein uptake in MCL did not change upon PTX exposure, indicating technical problems in multicellular system. Overall, these data indicate that antitumor activity of PTX may be limited in human solid tumors (a multicellular system) and MCL may be an appropriate model to study further pharmacodynamics of PTX.

AC TO AC Direct Voltage Conversion Using A Solid State Transformer

  • Um, Keehong
    • International Journal of Internet, Broadcasting and Communication
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    • v.5 no.1
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    • pp.6-8
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    • 2013
  • In this paper, we present an intelligent digital controller circuit which can be applied to automatic voltage regulation. The proposed solid state transformer with Pspice simulation model shows that our approach is very efficient and produces the desirable output. It is comparable to an ordinary magnetic coupled autotransformer.

Solid Oxide Fuel Cells Designs, Materials, and Applications

  • Singhal Subhash C.
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.777-786
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    • 2005
  • The Solid Oxide Fuel Cell (SOFC) is an electrochemical device to convert chemical energy of a fuel into electricity at temperatures from about 600 to $1000^{\circ}C$. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use CO as a fuel rather than being poisoned by it, and high grade exhaust heat for combined heat and power, or combined cycle gas turbine applications. This paper reviews the operating principle, materials for different cell and stack components, cell designs, and applications of SOFCs. Among all designs of Solid Oxide Fuel Cells (SOFCs), the most progress has been achieved with the tubular design. However, the electrical resistance of tubular SOFCs is high, and specific power output $(W/cm^2)$ and volumetric power density $(W/cm^3)$ low. Planar SOFCs, in contrast, are capable of achieving very high power densities.

Electrochemical Performances of LiMn2O4:Al Synthesized by Solid State Method (고상법으로 합성한 LiMn2O4:Al의 전기화학적 특성)

  • Park, Hye-Jung;Park, Sun-Min;Roh, Gwang-Chul;Han, Cheong-Hwa
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.531-536
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    • 2011
  • Al doped $LiMn_2O_4$ ($LiMn_2O_4:Al$) synthesized by several Al doping process and Solid State method. The Al contents in $Mn_{1-x}Al_xO_2$ for $LiMn_2O_4:Al$ were analyzed 1.7 wt% by EDS. The $LiMn_2O_4:Al$ confirmed cubic spinel structure and approximately 5 ${\mu}m$ particles regardless of three kinds of doping process by solid state method. In the result of electrochemical performances, initial discharge capacity had 115 mAh/g in case of $LiMn_2O_4$ and 111 mAh/g of $LiMn_2O_4:Al$ after 100th cycle at room temperature. But the capacity retention results showed that $LiMn_2O_4$ and $LiMn_2O_4:Al$ were 44% and 69% respectively in the 100th cycle at 60$^{\circ}C$. Therefore we are confirmed that $LiMn_2O_4:Al$ increased the capacity retention about 25% than $LiMn_2O_4$, thus the effect of Al dopping on $LiMn_2O_4$ capacity retention.

Effects on Performance of Deployable Solid Antenna for Panel Misalignment (패널오차에 의한 전개형 솔리드 안테나 성능 영향)

  • Lee, Ji-Yong;Lee, Kyo-Il;Yoon, Seong-Sik;Lee, Taek-Kyung;Lee, Jae-Wook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.8
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    • pp.603-609
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    • 2017
  • In the deployable solid surface antennas, the effects on the performances of antenna due to the structural errors that occur during the deployment are analyzed. The deployable solid surface antennas employed in a satellite are launched in folded configuration and those are deployed in the space environment, and the effects on the antenna performance are calculated depending on the type of surface errors. When the deviation error occurs in one panel, the degradation of performance appears in the side where the incomplete deployment of panel occurs. By assuming that the panel error distribution is in cosine function, the effect of errors are calculated and analyzed with regard to the types and the magnitude of the error. If the antena panel error is uniform, the gain is reduced and pattern is symmetric. For the panel error of cosine 1 or 3 cycle, the main lobe tilts while the pattern is symmetric and the gain reduces for 2 or 4 cycle error.