• Title/Summary/Keyword: curing-agent

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A Fundamental Study on the Antiwashout Underwater Concrete for the Underwater Work of Ocean (수중불분리성 콘크리트의 해양공사 적용에 관한 기초적 연구)

  • 김명식;윤재범;박세인
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.25-34
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    • 2000
  • When concrete is placed underwater, it is diluted with separating cementitious material and as a result the quality of concrete becomes poor. To solve this problem, antiwashout underwater concrete is increasingly used for the construction and repair of the concrete structure underwater. The objective of this study is to investigate the characteristics of antiwashout underwater concrete as to the mix proportion, casting and curing water through experimental researches. The unit weight of water and cement, water-cement ratio, fine aggregate ratio, unit weight of antiwashout underwater agent and superplasticizer, and casting and curing water were chosen to measure the suspended solids, pH, air contents, slump flow, unit weight of hardened concrete, and compressive strength. From this study, the incremental modulus at mix proportion design and unit weight of antiwashout underwater agent were increased more than fresh water, and it is a optimum mix proportion that the unit weight of water(and cement) is 230kg/$\textrm{m}^3$(460kg/$\textrm{m}^3$), waterOcement ratio is 50%, fine aggregate ratio is 40%, unit weight of antiwashout underwater agent is 1.2% of water contents per unit weight of concrete, and unit weight of supeplasticizer is 2.5% of cement contents per unit weight of concrete when the antiwashout underwater concrete is used for the underwater work of ocean.

Preparation of Glass-like High-density Carbon by Polymerization of Thermosetting Resin (열경화성 수지의 축중합에 의한 고밀도 유리상 탄소의 제조)

  • Kim, Ji-Hyun;Kim, Hee-Seok;Lim, Yun-Soo;Park, Hong-Soo;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.153-159
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    • 2001
  • Due to its low density, good mechanical properties and chemical inertness, glassy carbon(GC) has been studied for appications in several fields. A raw thermosetting resin of furanic resin was polymerized with a curing agent of p-toluenesulfonic acid monohydrate. The maximum yield of GC was obtained at the curing agent content of 1.0 wt% in furanic resin. In order to make thick GC, the affect of graphite filler addition to the furanic resin was investigated. The density and electrical resitivity of GC after graphitization were 1.45 $g/cm^{3}$ and 47 ${\times}10^{-4}$ ${\Omega}$ ${\cdot}$ cm respectively and the amorphous structure of GC was confirmed by XRD profiles with very broad peaks comparable to those of graphite at $206^{\circ}$ and $45^{\circ}$.

Synthesis and PSA Properties of Acryl Modified Resin for Semiconductor Wafer (반도체 웨이퍼용 아크릴 변성 수지의 합성 및 점착 특성)

  • Sim, Jong Bae;Shin, Kyoung Sub;Hwang, Taek Sung
    • Journal of Adhesion and Interface
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    • v.11 no.2
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    • pp.63-69
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    • 2010
  • In this study, acryl resin PSA containing hydroxyl group based on 2-EHA (2-ethyl hexyl acrylate), 2-EHMA (2-ethyl hexyl methacrylate), 2-HEA (2-Hydroxy ethyl acrylate), acrylic acid was synthesized and then, isocyanate modified acryl resin PSA prepared with adduct reaction according to the amount of MOI (Methacryloyloxyethyl isocyanate) or 2-isocyanatoethyl methacrylate that can improve the curing property. This research shows that the initial PSA and peel adhesion are decreased according to the increase of the amount of the MOI and isocyanate curing agent. After UV irradiating, the peel adhesion is decreased with increasing the amount of the MOI (Methacryloyloxyethyl isocyanate) and isocyanate curing agent, because of the high curing property.

Mock-up Test of Concrete Using AE Water Reducing Agent of Early-Strength Type in Construction Field (조기강도발현형 AE감수제를 사용한 콘크리트의 현장 Mock-up 실험)

  • 황인성;김기훈;김규동;이승훈;한천구
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2004.05a
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    • pp.1-4
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    • 2004
  • In this paper. applicability of high early strength type AE water reducing agent(HESAEWA) developed by the authors is discussed by applying Mock-up test. For fresh concrete properties, concrete using existing AE water reducing agent(EAEWRA) and HESAEW A meets the target slump and air content at jobsite. Setting time of concrete using HESAEWA is shorter than that using EAEWRA. Remarkable variance of bleeding and settlement is not observed with type of AE water reducing agent. For hardened concrete properties, use of HESAEW A results in higher strength development compared with that of EAEWRA at standard curing and in field curing condition. Reaching time to accomplish 5MPa of compressive strength. which is possible to remove side form. is taken using HESAEWA earlier than that of EAEWRA by 1day. Therefore, it is confirmed that use of HESAEWA can meet the requirements of general quality of concrete and achieve high early strength development as well as has a desirable field applicability.

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Effect of Stereoisomeric Structures of Curing Agents on Curing Behaviors, Thermal and Mechanical Properties of Epoxy Resins (경화제의 입체 이성질체 구조가 에폭시 수지의 경화 거동과 열 및 기계적 특성에 미치는 영향)

  • Lee, Minkyu;Kwon, Woong;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.30 no.3
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    • pp.180-189
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    • 2018
  • To study the effect of stereoisomeric structures of curing agents on curing behaviors, thermal and mechanical properties of epoxy resins, DGEBA(diglycidyl ether of bisphenol A) epoxy resin and 3,3'- and 4,4'-DDS(diaminodiphenyl sulfone) curing agents were selected. The curing initiation temperature and activation energy of DGEBA/3,3'-DDS was lower than DGEBA/4,4'-DDS. DGEBA/3,3'-DDS has a faster curing rate and higher degree of cure than DGEBA/4,4'-DDS, suggesting that 3,3'-DDS has higher reactivity than 4,4'-DDS. Tensile strength and fracture toughness of DGEBA/3,3'-DDS was lower than those of DGEBA/4,4'-DDS, indicating that mechanical properties of the epoxy resin can be different only by the stereoisomeric difference in chemical structure of the curing agent.

Burning Properties of Uncured HTPB Propellant (HTPB 바인더를 이용한 미 경화 추진제의 연소 특성)

  • Kim, Nakhyun;Kim, Jungeun;Hong, Myungpyo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.1
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    • pp.37-42
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    • 2016
  • In this study, we examined the burning rate of the uncured propellant (with and without a curing agent application) in order to inspect the process of the HTPB solid propellant. The burning rate of the uncured propellant, that did not contain the curing agent, was approximately 9.7 mm/s at 1000 psi. In relation to the curing time, the burning rate was constant. The propellant, with the curing agent application, was approximately 8.1 mm/s showed a tendency of slowing as it burned. When the cure reaction rate was low, in accordance to the time, there were small changes in burn rate. However, when the cure reaction rate was high, the difference in burning rate was increased. The burning rate of a fully-cured propellant was approximately 6.8 mm/s, which appeared to be the lowest in order.

A Study on the resistance of acrylic rubber pressure sensitive adhesives with curing agents and tackifiers (경화제와 점착부여제가 아크릴 고무점착제의 내열성에 미치는 영향)

  • Nam, Kyong min;Kim, Chul Yong;Kim, Eun Seon;Kim, Kwang-Je;Choi, Woo Jin;Kim, Ki-Tae;Park, Myung-Chul
    • Journal of Adhesion and Interface
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    • v.18 no.4
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    • pp.166-170
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    • 2017
  • In this study, acrylic rubber pressure sensitive adhesives was polymerized with 2-ethylhexyl acrylate, styrene, butadiene, 2-hydroxyethyl acrylate, and acrylic acid by controlling the initiator content. The initial tackiness, peel strength, holding power, and heat resistance of the PSAs were investigated by changing the content of tackifier and curing agent. The results showed that the initial tackiness and peel strength increased as the content of tackifier increased, whereas the holding power decreased. Also, the results exhibited that that the initial tackiness, peel strength, and heat resistance decreased as the content of curing agent increased, whereas the holding power and decreased.

ANOVA for Water Repellent Finish data (발수가공 데이터의 분산분석)

  • Yun, Jung-Beom
    • Journal of Korean Society for Quality Management
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    • v.16 no.1
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    • pp.43-48
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    • 1988
  • Most of silicone used for water repellent finish is MHP (methyl hydrodiene polysiloxane), which is formed by hydrolysis and condensation polymerization of MHD (methyl hydrodiene dichlorosilane: Me H Si $Cl_2$). The cross-linking theory explains the water repellent mechanism of MHP. The silicone finish on fiber could improve in handle, softness, abrasion resistance, soil repellency, tear strength and crease resistance, as well as water repellency. According to using method silicone-water repellent finishing agents, could be devided into air dry type and curing type. MHP is the typical curing type of water repellent finishing agent, and this type requires the curing temperature above $150^{\circ}C$ at least. High curing temperature is the very drawback of this curing type. For this reason, there has been global interest in the lowering of its temperature. The objective of this study is to investigate merits of alkali treatment for silicone finishing by ANOVA and LSD (least significant difference).

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A Study on Curing Level Prediction Model for Varying Chemical Composition of Epoxy Asphalt Mixture (에폭시 아스팔트 혼합물의 에폭시 화학 조성에 따른 양생수준 예측)

  • Jo, Shin Haeng;Kim, Nakseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.2
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    • pp.465-470
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    • 2015
  • The curing of epoxy asphalt mixture depends on the chemical reaction of epoxy resin and the curing agent. The curing level of epoxy asphalt mixture needs to be predicted in order to decide traffic opening time and to establish further construction plans. In this study, chemical analysis of the prediction model was executed to expand the applicability of the previous prediction model. Consequently, the curing level prediction model of epoxy asphalt concrete mixture was proposed using the concentration ratio and the acid value ratio. According to the results of outdoor curing experiments, the final prediction model showed that the correlation coefficient is greater than 0.971. Precise prediction results of different composition epoxy asphalt were obtained by reflecting the chemical composition ratios in the curing level prediction model.

Analysis of Setting Delay Performance Change of Super Retarding Agent According to the Change of Mixing Rate at 20℃ (20℃ 조건에서 초지연제 혼입율 변화에 따른 응결지연 성능 변화 분석)

  • Lim, Gun-Su;Han, Soo-Hwan;Hyun, Seung-Yong;Kim, Jong;Han, Min-Choel;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.127-128
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    • 2020
  • This research is part of the research for unifying the mass concrete and utilizing the rate of super retarding agent. We analyzed the performance of super retarding agent 20℃ conditions. It was found that there was no deterioration in fluidity and air quality due to the change in the super retarding agent mixing rate. It was found that when super retarding agent was mixed up to 0.5 %, it was delayed for 22.3 hours at 20℃. Therefore in order to ensure the performance required at the site, the super retarding agent mixing rate must be determined by fully considering the situation at the site. In addition it will be analyzed that super retarding agent performance analysis at high temperature will be required in subsequent studies.

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