• Title/Summary/Keyword: curing shrinkage

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Dental Restorative Composite Resins Containing Asymmetric Spiro Orthocarbonate for the Reduction of Volumetric Shrinkage (비대칭 스파이로 오르토카보네이트가 포함된 저수축 치아 수복재)

  • 황미선;김창근
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.321-327
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    • 2004
  • The applications of dental restorative composite resins containing 2,2-bis [4-(2-hydroxy-3-me-thacryloyloxy propoxy) phenyl] propane as a base resin, and triethylene glycol dimethacrylate, as a diluent, were often limited in dentistry due to the relatively large amount of volumetric shrinkage that occurs during the curing reaction. In this study, in order to reduce volumetric shrinkage of the current dental restorative composite resin, asymmetric spiro orthocarbonates were synthesized and then the characteristics of resin composites containing them were explored. The volumetric shrinkage of the dental composites containing spiro orthocarbonates was decreased approximately 45%. However, the curing characteristics and mechanical properties of the new dental composites were slightly poor than those of the commercially available dental composite.

Properties of Unsaturated Polyester Mortar Using Expanded Polystyrene as a Shrinkage-Reducing Additive (발포 폴리스티렌 수지를 수축저감제로 이용한 불포화 폴리에스테르 모르타르의 특성)

  • 조영국;최낙운;소양섭
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.30-37
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    • 2001
  • Generally, polymer mortar made with unsaturated polyester(UP) resin has a high curing shrinkage. This is an inadequate as repair material and construction products that have been widely used for years recently. To overcome these problems, polymer researchers and engineers have used shrinkage-reducing additives, which are usually specific thermoplastic polymers. The objective of this study is to evaluate the effects of shrinkage-reducing additive on the curing shrinkage and strengths of UP mortar. UP mortars are prepared with expanded polystyrene(EPS) ratio in styrene monomer(SM), (EPS/PS, PS=EPS+SM), and the ratio of total polystyrene resin(PS) to UP resin, (PS/UP). And it is tested for viscosity of UP resin, slump-flow, working life, flexural and compressive strengths, and curing shrinkage tests. From the test results, viscosity of resin for UP mortar increases with increasing PS content. Curing shrinkage of UP mortar is considerably smaller than that of plain UP mortar, nevertheless, reduction in the strengths is not recognized according to adding PS resin. In this study, we can obtain the optimum mix proportions of UP mortar using PS resin which made of waste expanded polystyrene.

Effects of Fine LWA and SAP as Internal Water Curing Agents

  • de Sensale, Gemma Rodriguez;Goncalves, Arlindo Freitas
    • International Journal of Concrete Structures and Materials
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    • v.8 no.3
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    • pp.229-238
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    • 2014
  • Typical high-performance concrete (HPC) mixtures are characterized by low water-cementitious material ratios, high cement contents, and the incorporation of admixtures. In spite of its superior properties in the hardened state, HPC suffers from many practical difficulties such as its sensitivity to early-age cracking (which is associated with self-desiccation and autogenous shrinkage). In this context, conventional curing procedures are not sufficiently effective to address these limitations. In order to overcome this issue, two strategies,which are based on the use of internal reservoirs of water, have been recently developed.One of these strategies is based on the use of lightweight aggregates (LWA), while the other is based on the use of superabsorbent polymers (SAP). This paper studies and compares the efficiency of the LWA and SAP approaches.Moreover, some of the theoretical aspects that should be taken into account to optimize their application for internal curing of HPC are also discussed. Two fine LWA's and one SAP are studied in terms of autogenous deformation and compressive strength. Increasing the amounts of LWAor SAP can lead to a reduction of the autogenous deformation and compressive strength (especially when adding large amounts). By selecting appropriate materials and controlling their amount, size, and porosity, highly efficient internal water curing can be ensured.

Durable Press Finishing of Silk/Cotton Fabrics with BTCA ( I ) - Effect of Treating Conditions on Physical Properties - (BTCA에 의한 실크/면 교직물의 DP 가공 (I) - 물리적 특성에 미치는 처리 조건의 영향 -)

  • 이문철;조석현
    • Textile Coloration and Finishing
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    • v.14 no.1
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    • pp.43-50
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    • 2002
  • Silk/Cotton fabrics were treated with butanetetracarboxylic acid(BTCA) to improve crease recovery and anti-shrinking properties at various curing temperatures and pH values. We investigated the effects of finishing conditions on add-on of BTCA, bending property(E, 2HB), wrinkle recovery angle, shrinkage, and dyeing properties. The Add-on of BTCA increased with increasing curing temperature and concentration. Crease recovery was improved with decreasing shrinkage. Maximum add-on of BTCA was showed at pH 2.5. In case of dyeing and mercerization, silk side treated with BTCA was more flexible than untreated, whereas cotton side was more stiff. In dyeing after mercerization, B and 2HB values were higher and K/S values were doubled nearly. The hand of fabric improved with decreasing B and 2HB by the BTCA treatment. BTCA treatment after reactive dyeing improved crease recovery, and caused no change of color difference. However, BTCA treatment after reactive dyeing didn't improve crease recovery, whereas B and 2HB were decreased considerably by the treatment.

A study on the Shrinkage Reduction and Strengths of Unsaturated Polyester Mortar (불포화 폴리에스테르 레진 모르타르의 수축저감 및 강도특성에 관한 연구)

  • 최낙운;최길섭;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.343-348
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    • 1999
  • The purpose of this study is to evaluated the effects of added expanded polystyrene on the basic properties of UP mortar. Polyester resin mortars are prepared with expanded polystyrene ratio in styrene monomer (EPS/PS), and the ratio of total polystyrene resin to UP resin (PS/UP). And it is tested for viscosity of UP resin added PS resin, slump-flow test, working life, flexural and compressive strengths, and curing shrinkage test. From the test result, Viscosity of resin for polymer mortar increases with increasing PS content. Curing shrinkage of UP mortar is considerably smaller than that of plain UP mortar, nevertheless, reduction in the strengths is not recognized according to adding PS resin. In this study, we can obtain the optimum mix proportions of polymer mortar using PS resin.

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Influences of Construction Conditions on the Properties of Cement Mortars in Floors Using Expansion Agent (팽창재를 사용하는 바닥 모르타르의 특성에 미치는 시공요인의 영향)

  • 표대수;정성철;송명신;홍상희;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.925-928
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    • 2000
  • In this paper, physical properties of cement mortar for floor using expansion agent are discussed varied with mixing time and curing temperature, delivery time and content of added water for preventing fluidity loss. According to experimental results, slump loss shows high with elapse of time And as curing temperature goes up, it also show high when curing temperature goes up and time lag between mixing and casting increases. As curing temperature goes down, drying shrinkage shows to be decreased. But it shows decline tendency with increase of added water content.

The effect of curing conditions on the cracking properties of flyash concrete (양생조건에 따른 플라이애쉬 콘크리트 균열특성에 미치는 영향)

  • Park, Jong-Hwa;Lee, Man-Ik;Nam, Jae-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.825-828
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    • 2006
  • In this paper, experimental studies are performed to find out properties of crack according to the change of curing conditions of flyash concrete. To study the effect of curing conditions on flyash concrete, slump, bleeding, air content and hydration temperature of fresh concrete are measured according to various curing conditions. In addition, the effect of caring conditions on compressive strength, tensile strength and Plastic drying shrinkage cracking of hardened concrete is also considered.

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An Experimental Study on the Creep and Shrinkage for the Segment Concrete in PSC Box Girder Bridge (PSC 박스거더 교량에 사용된 세그먼트 콘크리트의 크리프 및 건조수축에 관한 실험적 연구)

  • 최한태;윤영수;이만섭
    • Journal of the Korea Concrete Institute
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    • v.11 no.3
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    • pp.23-34
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    • 1999
  • In designing PSC box girder bridge, the dead load, prestressing force, creep and shrinkage of concrete are the main factors which influence the camber and deflection of segmental concrete structure under construction. Among these factors the creep and shrinkage are the functions of the time-dependent property which, therefore, must considered with time. The prediction model for estimating creep and shrinkage of concrete has been suggested by ACI, CEB/FIP, JSCE and KSCE design code. In this study the creep and shrinkage test were carried out for four curing ages of concrete which was applied to the pretressed concrete box-girder bridge at a construction site, and the results of test were compared to the values of prediction by the design code. Shrinkage test shows that the test results are similar to KSCE-96 and JSCE-96 but very higher than other prediction model and creep test results are generally similar to ACI-209 and DSCE-96 but lower than other prediction models in contrast to shrinkage test.

Effect on the Residual Stress of Cure Profiles, Fillers and Mold Constraints in an Epoxy System

  • Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.23 no.4
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    • pp.1-5
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    • 2009
  • A dilatometer was used to investigate the effect of cure conditions, mold types and the presence of filler in an epoxy system. These studies showed shrinkage in the cured epoxy when heating it through the glass transition temperature region. The magnitude of the shrinkage, related to stress build up in the epoxy during curing, was influenced by the processing conditions, filler presence and the nature of the mold used to contain the resin. Cure and cyclic cure at a lower temperature, prior to a post cure, decreased the magnitude of observed shrinkage. Cure shrinkage decreased with the number of cyclic cures. Post cured samples outside the mold led to less shrinkage compared with samples in the mold. Sample cured in a silicon mold represented less shrinkage than sample cured in an aluminum mold. Sample containing kaolin filler showed less shrinkage than unfilled sample.

A Study on the Properties of Cement Mortar with the Content of Expansive Additives Under Various Curing Method (팽창재량 및 양생방법에 따른 시멘트 모르터의 특성에 관한 연구)

  • 한성수;김정진;김효구;홍상희;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.181-186
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    • 1999
  • When the expansive additives are used in concrete to reduce the shrinkage cracking, it shows variable properties with the curing method and curing temperature. Therefore, in this study, the experiments are perfomed to present the expansion of cement mortar by varying the unit additions of expansive additives and the curing method. According to the test results, the order of expansion by curing method, which is caused by hydration heat of cement, is follows ; curing at water > curing at air after curing at water for 7 days > curing at air. Cement mortar using expansive additives shows that high expansion is place with rise of temperature.

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