• Title/Summary/Keyword: curing shrinkage

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Assesment of Renewable Energy (신재생 에너지 고찰)

  • Lee, Sang-Heon;Koo, Kyoung-Whan
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.2071-2072
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    • 2011
  • Withstand voltage characteristics of the nanocomposites, as a material with excellent abrasion resistance and water resistance, low shrinkage upon curing with moisture even in very good adhesion, workability is not lost. In this study, the fusion of nanoparticles and the high functionality epoxy nano-composite material produces the electricity. Degeneration of the unit based on this power structure and breakdown characteristics, efficiency and cross-measurement system as closely related organisms that can be applied to the power plant electrical efficiency of the nano-composite material is designed to develop skills.

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Comparison of polymerization shrinkage between halogen light curing unit and PAC

  • Lee, Jae-Ik;Park, Sung-Ho
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.583.2-583
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    • 2001
  • In these days, as the patients requirements on ethetics are getting greater, so the restorative materials which match well with natural teeth colors are being developed. One of those materials is the composite resin. When we fill the composite resin into the prepared cavity, it makes some clinical problems because it shrinks during the polymerization. To resolve these problems, first we must have sufficient understandings on the polymerization of composite resin.(omitted)

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Property Changes due to Numbers of Nitrogen Atom Bonded at Ethyl Group, Included in Main Chain of Curing Agents of DGEBGF/Linear Amino Systems (DGEBF/선형아민 계에서의 경화제 주쇄에 포함된 에틸기에 결합된 질소원자 개수에 따른 물성변화 연구)

  • Myung In-Ho;Lee Jae-Rock
    • Composites Research
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    • v.17 no.6
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    • pp.44-51
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    • 2004
  • To determine the effect of numbers of nitrogen atom bonded at ethyl group included in main chain of linear amine curing agents of epoxy-cure systems on the thermal and mechanical properties, standard epoxy resin DGEBF was cured with DETA, TETA and TEPA in a stoichiometrically equivalent ratio. From this work, the effect of curing agents of the DGEBF/amine systems oil the thermal and mechanical properties was significantly influenced by numbers of nitrogen atom of curing agents. The results showed that heat of reaction increased, and maximum exothermic temperature decreased with the decrease of numbers of nitrogen atom. In case of cured systems, density and maximum conversion(%) had no relation to numbers of nitrogen atom, but flexural modulus and tensile modulus increased with the decrease of numbers of nitrogen atom in main chain. Thermal stability, shrinkage(%), Tg, tensile and flexural strength showed irregular tendency having nothing to do with numbers of nitrogem atom at a sight. This findings imply that the differences in the maximum conversion(%) about the chain length of curing agents affect the thermal and mechanical properties.

Strength Properties of Concrete According to Types of High Early Strength Cement and Curing Method (조강형 시멘트의 종류 및 양생방법에 따른 콘크리트의 강도특성)

  • Chang, Chun-Ho;Lee, Wang-Sup;Jung, Yong-Wook;Chung, Youn-In
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.76-84
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    • 2017
  • This study selected a method which uses high early strength cement as a way to reduce the curing time and curing energy source of concrete secondary products and reviewed the improvement in the initial strength of concrete secondary products setting the target strength of the concrete capable of removing the form to 15MPa and the curing time to 6 hours. As a result of the test, the only specimen which achieved the form removal strength of 15 MPa only through atmospheric curing within the target curing time of 6hours was ACC-100, and the specimens of TRC-100 and TRC-50 satisfied the values of 6 hours and 15MPa through steam curing. However, we could see that it was difficult to secure workability in the case of the specimen of ACC-100 due to its high rapid setting property and a retarder such as anhydrous citric acid was required to be used to improve the workability. When we look into the pattern following changes in the water to binder ratio, while, in the case of stream curing, OPC-100, TRC-100, and TRC-50 were all found to satisfy achievement of the form removal strength within 6hours as the water to binder ratio decreased, in the case of atmospheric curing, TRC-100, and TRC-50 achieved 15MPa within 12hours.

A Study on the Development of Non-PC High-Early-Strength Concrete Without Steam Curing (증기양생이 불필요한 PC부재용 조강형 콘크리트 개발에 관한 연구)

  • Jun, Woo-Chul;Lee, Ji-Hwan;Park, Hee-Gon;Lee, Jae-Sam;Kim, Kyung-Min;Cho, In-Sung
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.2
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    • pp.156-162
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    • 2014
  • This study aims to develop a rapidly hardening type of concrete to achieve the removal of form intensity (more than 10MPa) using the method of curing at room temperature in order to solve some economic environmental problems by omitting the steam curing process involved in producing PC (Precast Concrete). Therefore, this study evaluated a rapidly hardening cement containing a high amunt of C3S, which is very responsive in expressing early intensity, and a rapidly hardening type of concrete which uses some hardening accelerator to increase thehydration reaction of $C_3S$. The results of the experiment on concrete using some hardening accelerator are asfollows. In the slump flow experiment for identifying the liquidity and the air test, the desired values were met. The compression strength showed rapid expression response by 12 hours, and met the desired value within 6~9 hours. Its drying shrinkage value and Autogenous shrinkage value were measured as below ($-754.5{\times}10^{-6}$),and satisfied the requirements. In addition, in the Semi-Adiabatic Temperature Test, it was found that the concrete rose to its peak temperature within 24 hours and then its temperature dropped.

Properties of Cement Paste Containing High Volume γ-C2S and MgO Subjected to CO2 Curing (γ-C2S 및 MgO를 다량 혼입한 시멘트 페이스트의 CO2 양생유무에 따른 특성변화)

  • Sung, Myung-Jin;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.281-289
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    • 2015
  • Carbonation of concrete causes reduction of pH and subsequently causes steel corrosion for reinforced concrete structure. However, for plain concrete structure or PC product, it can lead to a decrease in porosity, high density, improvement of concrete, shrinkage-compensation. Recently, based on this theory, research of $CO_2$ curing effect has been performed, but it was mainly focused on its effects on compressive strength using only ordinary portland cement. Researches on $CO_2$ curing effect for concrete containing $CO_2$ reactive materials such as ${\gamma}-C_2S$, MgO haven't been investigated. Therefore, this study has performed experiments under water-binder ratio 40%, and the replacement ratios of ${\gamma}-C_2S$ and MgO were 90%. Micro-chemical analysis, measurement of compressive strength according to admixtures and $CO_2$ curing were investigated. Results from this study revealed that higher strength was measured in case of $CO_2$ curing compared with none $CO_2$ curing for plain specimen indicating difference between 1.08 and 1.26 times, in case of ${\gamma}-C_2S$ 90, MgO 90 specimen, incorporating high volume replaced as much as 90%, it was proven that when applying $CO_2$ curing, higher strength which has difference between 14.56 and 45.7 times, and between 6.5 and 10.37 times was measured for each specimen compared to none $CO_2$ curing. Through micro-chemical analysis, massive amount of $CaCO_3$, $MgCO_3$ and decrease of porosity were appeared.

A COMPARATIVE STUDY ON THE COMPOSITE RESTORATION DESIGN AND PLACEMENT METHODS USING THREE DIMENSIONAL FINITE ELEMENT ANALYSIS (광중합 콤포짓트레진의 수복형태 및 방법에 관한 삼차원 유한요소분석법적 비교 연구)

  • Lee, Jung-Taek;Yim, Soon-Ho;Chang, Ik-Tae
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.1
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    • pp.133-149
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    • 1998
  • Clinical application of composite resin recently draw great concerns in dentistry. Especially due to advantages such as esthetics, adhesiveness, simple clinical procedures, various shapes and kinds of composite resins are widely being applied to prosthodontics, conservative dentistry, and orthodontics. But, clinical problems attributable to the polymerization shrinkage of composite resin have been proposed, and we have to regard clinical problems such as secondary caries, loss of restoration, fracture of the surrounding tooth structure, marginal discoloration, and tooth sensitivity, and many portions are remained to be overcome. Therefore, this study attempts to analyze stress distribution between resin and tooth structure which is generated during polymerization shrinkage of composite resin using three dimensional finite element method. Three dimensional finite element models with conventional box-shape cavity and erosion/abrasion type V-shape lesion cavity in upper central incisor were developed. These cavities were filled with four different types of placement techniques. (bulk filling, horizontal increment filling, oblique occlusal increment filling, oblique gingival increment filling) The stresses generated by polymerization shrinkage of composite resin were calculated. The results analyzed with three dimensional finite element method were as follows : 1. The increment filling technique showed the highest maximum normal stress in both conventional box-shape and V-shape cavities and showed a tendency to decrease after complete polymerization. 2. The bulk filling technique resulted in increased stresses during the curing process in both conventional box-shape and V-shape cavities and the highest maximum normal stress occurred after complete polymerization. 3. The bulk filling resulted in the lowest maximum normal stress in both box-shape and V-shape cavities 4. Regardless of placement method, in conventional box-shape cavity, the maximum normal stress increased in dentin floor, enamel, dentin sequence and in V-shape cavity, the maximum normal stress increased in enamel, dentin sequence.

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Effect of micro-silica on mechanical and durability properties of high volume fly ash recycled aggregate concretes (HVFA-RAC)

  • Shaikh, Faiz;Kerai, Sachin;Kerai, Shailesh
    • Advances in concrete construction
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    • v.3 no.4
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    • pp.317-331
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    • 2015
  • This paper presents the effect of different micro-silica (MS) contents of 5, 10 and 15 wt.% as partial replacement of cement on mechanical and durability properties of high volume fly ash - recycled aggregate concretes (HVFA-RAC) containing 50% class F fly ash (FA) and 35% recycled coarse aggregate (RCA) as partial replacement of cement and natural coarse aggregate (NCA), respectively. The measured mechanical and durability properties are compressive strength, indirect tensile strength, elastic modulus, drying shrinkage, water sorptivity and chloride permeability. The effects of different curing ages of 7, 28, 56 and 91 days on above properties are also considered in this study. The results show that the addition of MS up to 10% improved the early age (7 days) strength properties of HVFA-RAC, however, at later ages (e.g. 28-91 days) the above mechanical properties are improved for all MS contents. The 5% MS exhibited the best performance among all MS contents for all mechanical properties of HVFA-RAC. In the case of measured durability properties, mix results are obtained, where 10% and 5% MS exhibited the lowest sorptivity and drying shrinkage, respectively at all ages. However, in the case of chloride ion permeability a decreasing trend is observed with increase in MS contents and curing ages. Strong correlations of indirect tensile strength and modulus of elasticity with square root of compressive strength are also observed in HVFA-RAC. Nevertheless, it is established in this study that MS contributes to the sustainability of HVFA-RAC significantly by improving the mechanical and durability properties of concrete containing 50%less cement and 35% less natural coarse aggregates.

A comparative study on the accuracies of resin denture bases and metal denture bases

  • Park Hwee-Woong;Kim Chang-Whe;Kim Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.3
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    • pp.250-259
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    • 2001
  • Since the late 1930s, acrylic resins have been the materials of choice for the fabrication of complete denture bases. It has excellent esthetic properties, adequate strength, low water sorption, and low solubility. But acrylic resin has disadvantage of processing shrinkage that reduces denture retention and accuracy of denture occlusion. Metals also have been used in denture base material. Metals used in denture bases display excellent strength and dimensional stability. The major disadvantages associated with metal denture bases include increased cost, difficulty in fabrication, compromised esthetic qualities, and inability to re-base. The purpose of this study is to compare the artificial tooth movements of complete dentures with resin bases and metal bases after curing, deflasking, polishing immersion in water for 1 week and 4 weeks. Twenty-four maxillary complete resin denture bases with artificial teeth were fabricated. Twelve of them were resin based and other twelve of them were metal based. Fine crosses were marked on the incisal edges of right central incisors and distobuccal cusps of be second molars. Measurements were done for the changes of distances of reference points at the time of wax denture, after deflasking after decasting after polishing after immersion in water for 1 week and 4 weeks Meaurements were done to the accuracy of 0.001mm with a measuring microscope. The results were as follows : 1. Metal base showed significantly less tooth movement than resin base after curing and decasting (p<0.01). 2. Metal base showed significantly less tooth movement than resin base after polishing (p<0.01). 3. After immersion in water for 1 week and 4 weeks, metal base showed less movement than resin base. Difference was significant for anterior-posterior distances (p<0.01), but not significant for molar-to-molar distance (p>0.01). 4. 1 week and 4 weeks of immersion failed to compensate the initial processing shrinkage of metal and resin bases (p>0.01).

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Effect of ages and season temperatures on bi-surface shear behavior of HESUHPC-NSC composite

  • Yang Zhang;Yanping Zhu;Pengfei Ma;Shuilong He;Xudong Shao
    • Advances in concrete construction
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    • v.15 no.6
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    • pp.359-376
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    • 2023
  • Ultra-high-performance concrete (UHPC) has become an attractive cast-in-place repairing material for existing engineering structures. The present study aims to investigate age-dependent high-early-strength UHPC (HESUHPC) material properties (i.e., compressive strength, elastic modulus, flexural strength, and tensile strength) as well as interfacial shear properties of HESUHPC-normal strength concrete (NSC) composites cured at different season temperatures (i.e., summer, autumn, and winter). The typical temperatures were kept for at least seven days in different seasons from weather forecasting to guarantee an approximately consistent curing and testing condition (i.e., temperature and relative humidity) for specimens at different ages. The HESUHPC material properties are tested through standardized testing methods, and the interfacial bond performance is tested through a bi-surface shear testing method. The test results quantify the positive development of HESUHPC material properties at the early age, and the increasing amplitude decreases from summer to winter. Three-day mechanical properties in winter (with the lowest curing temperature) still gain more than 60% of the 28-day mechanical properties, and the impact of season temperatures becomes small at the later age. The HESUHPC shrinkage mainly occurs at the early age, and the final shrinkage value is not significant. The HESUHPC-NSC interface exhibits sound shear performance, the interface in most specimens does not fail, and most interfacial shear strengths are higher than the NSC-NSC composite. The HESUHPC-NSC composites at the shear failure do not exhibit a large relative slip and present a significant brittleness at the failure. The typical failures are characterized by thin-layer NSC debonding near the interface, and NSC pure shear failure. Two load-slip development patterns, and two types of main crack location are identified for the HESUHPC-NSC composites tested in different ages and seasons. In addition, shear capacity of the HESUHPC-NSC composite develops rapidly at the early age, and the increasing amplitude decreases as the season temperature decreases. This study will promote the HESUHPC application in practical engineering as a cast-in-place repairing material subjected to different natural environments.