• 제목/요약/키워드: curing agents

검색결과 163건 처리시간 0.029초

전기설비용 에폭시수지의 가열경화특성에 관한 연구 (A Study on the Thermosetting Properties of Epoxy Resins as Electrical Installation Materials)

  • 김태성;여인선;이진
    • 한국조명전기설비학회지:조명전기설비
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    • 제2권1호
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    • pp.75-82
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    • 1988
  • 각종 전기설비용 절연재료로 주목받는 Epoxy는 경화제와의 가교반응으로 전기절연특성이 우수한 경화물질을 얻을 수 있으며, 경화제의 종류와 격자 형성에 형태에 따라 경화된 Epoxy의 특성이 결정된다. 본 연구는 Epoxy의 경화시 분위기의 온도를 변화시켜 격자형성의 진행형태를 변화시키고, 경화된 Epoxy의 제반특성을 조사하여 전기절연특성이 가장 우수하게 되는 경화온도를 얻고자 한다. Epoxy를 분위기 온도 $20~50[^{\circ}C]$사이에서 $5^[{\circ}C]$ 간격으로 변화하면서 경화시킨 결과, 분위기 온도 $30[^{\circ}C]$에서 경화된 Epoxy의 전기절연특성 및 기계적 강도가 가장 우수하다고 판명되었다.

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Smear layer 제거와 금속 이온 처리가 광중합형 글라스아이오노머와 상아질간의 결합강도에 미치는 영향 (Effect of various cleaners and mordants to bond strength of light curing glass ionomer cements to dentin)

  • 이원섭;박상진
    • Restorative Dentistry and Endodontics
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    • 제19권1호
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    • pp.45-63
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    • 1994
  • 128 freshly extracted human molars were used to study the interaction between dentinal smear layer removal with various agents, and the shear bond strength of a light cured glass ionomer cement to dentin. It was proposed that the removal of smear layers using acidic cleaners followed by incorporation of Fe mordant with dentin could enhanced the infiltration of monomer component in light curing glass ionomer cement and resulted in a high bond strength. For the first treatment process for removal of smear layers on the surfaces of dentin, 50 % citric acid, 10% maleic acid and 10 % phosphoric acid were used, and for the second treatment process, 15% ferric chloride, 6.8% ferric oxalate or 30% potassium oxalate were used. Distilled water was used as a control. After double sequential treatment on dentin, a light curing glass ionomer cement was bonded to dentin. After being immersed in water at 31'C for 24 hours, shear bond strengths were measured Instron testing machine(Model No.4202, USA). Surface changes were also observed using SEM (Hitachi, S-2300, Japan) after treatment process with each agents. The following conclusions were drawn : 1. Dentin surface cleaned with maleic acid and treated with ferric oxalate showed the highest bond strength with light curing glass ionomer cement. 2. Bond strengths of glass ionomer cement to dentin treated with maleic acid or citric acid were the highest, and that treated with phosphoric acid showed the lowest. 3. The effect of ferric oxalate on shear bond strength to dentin was always higher than that of ferric chloride. 4. The smear layers were clearly removed and the orifices of dentinal tubules were opened widely by the citric acid, maleic acid and phosphoric acid. 5. The orifices of dentinal tubules opened after using the first solution were closed with the treatment of ferric chloride. 6. The precipitate like crystals were formed on dentin surfaces and tubules, but a significant decrease in bond strength of glass ionomer cement to dentin surface treated with potassium oxalate.

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에폭시 수지의 경화반응과 전기 절연특성 (Curing Reaction and Electrical Insulation Property of Epoxy Resin)

  • 이진;이은학;송희수;김재민;김태성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1989년도 춘계학술대회 논문집
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    • pp.43-46
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    • 1989
  • Epoxy, noticed as a new insulation material for electrical equipments, may become an excellent cured material from the crosslink reaction with some curing agents and accelerators. The characteristics of cured epoxy is determined by the method of lattice formation according to curing method. The purpose of this paper, varing the process of lattice formation by various surrounding temperatures and heating time during the curing process, is to obtain the optimum cured condition for electrical insulation from the results of investigation on the physical and dielectric properties of cured epoxy. In this investigation, it is found that the excessive temperature and heating time brings on the growth of metamorphic methyl and the insulating properties of cured epoxy is decreased by this phenomenon. As a result, it is concluded that the optimum dielectric characteristics can be obtained when cured at a curing temperature at 14$0^{\circ}C$ for one hour.

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Effects of Fine LWA and SAP as Internal Water Curing Agents

  • de Sensale, Gemma Rodriguez;Goncalves, Arlindo Freitas
    • International Journal of Concrete Structures and Materials
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    • 제8권3호
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    • pp.229-238
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    • 2014
  • Typical high-performance concrete (HPC) mixtures are characterized by low water-cementitious material ratios, high cement contents, and the incorporation of admixtures. In spite of its superior properties in the hardened state, HPC suffers from many practical difficulties such as its sensitivity to early-age cracking (which is associated with self-desiccation and autogenous shrinkage). In this context, conventional curing procedures are not sufficiently effective to address these limitations. In order to overcome this issue, two strategies,which are based on the use of internal reservoirs of water, have been recently developed.One of these strategies is based on the use of lightweight aggregates (LWA), while the other is based on the use of superabsorbent polymers (SAP). This paper studies and compares the efficiency of the LWA and SAP approaches.Moreover, some of the theoretical aspects that should be taken into account to optimize their application for internal curing of HPC are also discussed. Two fine LWA's and one SAP are studied in terms of autogenous deformation and compressive strength. Increasing the amounts of LWAor SAP can lead to a reduction of the autogenous deformation and compressive strength (especially when adding large amounts). By selecting appropriate materials and controlling their amount, size, and porosity, highly efficient internal water curing can be ensured.

Analysis of Quality and Color Properties according to the Gas Composition (Modified Atmosphere Packaging) of Pork Sous-Vide Ham Preserved in Natural Brine

  • Sol-Hee Lee;Hack-Youn Kim
    • 한국축산식품학회지
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    • 제43권4호
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    • pp.580-593
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    • 2023
  • The purpose of this study was to analyze whether seawater has positive effects on appearance characteristics, such as CIE a*, and to determine the gas composition concentration that is suitable for maintaining it. Pork hind meat was cured with four types of curing agent for 5 d at 4℃. The different curing agents comprised the control salt, control nitrite pickling salt (CN), treatment brine, and treatment bittern (BT). The cured hams were cooked at 65℃ for 4 h and packaged at O2:N2 gas ratios of 7:3, 8:2, and 9:1 for 3 wk. The physicochemical properties were assessed immediately after heating the sample, and the color properties were measured after a 3 wk storage period. Based on the correlation results of the physicochemical properties, BT had a higher curing and cooking yield than the other treatments, owing to its high salinity. Results of color properties for BT (7:3) and CN (8:2) showed similar color CIE L*, CIE a* chroma, and hue angle values. Therefore, BT can be said to be a sous-vide curing agent suitable for preserving the color of ham, and a high nitrogen concentration of 30% helps to maintain the appearance of seawater sous-vide ham.

UV중합성 수지와 알키드 수지 혼합물의 경화특성 및 상분리 구조에 관한 연구 (A Study on Curing Properties and Structures of Phase Separation for UV-Curable Resing and Alkyd Resin Blends)

  • 최정병
    • 한국인쇄학회지
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    • 제18권1호
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    • pp.13-24
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    • 2000
  • UV-curable resin has the properties of quick-drying, high productivity at low temperature, energy, space saving, solventless, non-polluting and low-stinking, and thus, UV-curing system has been widely used in the fields of printing inks, adhesives, paints and coating agents. This study has been executed to develop a new functionnal material by the polymerization induced phase separation. The results obtained were as follows. As for the curing properties of the monomer/prepolymer/alkyd resin blends, it was found out that there was a peak by the polymerization induced phase separation when measuring the changes of viscosity and elasticity. It was also found out that such polymerization phase separation occurred in case that the alkyd resin contents were 20wt% and 30wt% and not found at the contents of 40wt%. Therefore, it would be desirable to maintain the contents of alkyd resin at less than 30wt% in order to use the polymerization induced phase separation.

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Preparation and Curing Studies of Maleimide Bisphenol-A Based Epoxy Resins

  • Nanjunda Gowda, Shivananda Kammasandra;Mahendra, Kadidal Nagappa
    • Bulletin of the Korean Chemical Society
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    • 제27권10호
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    • pp.1542-1548
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    • 2006
  • Maleimide modified epoxy compounds were prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with diglycidylether of bisphenol-A. Triphenylphosphine was used as catalyst and methylethylketone as solvent. The resulting compound possessed both the oxirane ring and maleimide group. The curing reaction of the maleimide epoxy compound with amine curing agents such as 1-(2-aminoethyl) piperazine (AEP) and 5-amino-1,3,3-trimethylcyclohexane methylamine isophorone diamine, IPDA) were studied. Incorporation of maleimide groups in the epoxy resin provides cyclic imide structure and high cross-linking density to the cured resins. The cured samples were found to have good thermal stability, chemical resistance (acid/alkali/solvent) and water absorption resistance.

첨가제 및 경화조건 변화에 따른 에폭시 복합체의 DC 절연파괴특성에 관한 연구 (DC Dielectric Breakdown Properties of Epoxy Composites with Variation of Additives and Curing Conditions)

  • 정규희;최운식;왕종배;김홍철;이준웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.883-885
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    • 1992
  • DC dielectric breakdown properties of epoxy composites with various additives rates and curing conditions were investigated at the temperature range from 20[$^{\circ}C$] to 180[$^{\circ}C$]. At low temperature an improvement of the characteristics is observed due to curing agents. The additions of filter is lower the temperature dependences of the breakdown strength. Samples treated with silan have a higher breakdown strength than non-treating filled samples.

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내한성 혼화제를 이용한 시멘트 모르타르의 초기양생 온도변화에 따른 강도증진 특성 (Properties of Strength Development Under Various Curing Condition at Early Age of Cement Mortar Using Agent for Enduring Cold Weather)

  • 한천구;홍상희;김현우
    • 한국구조물진단유지관리공학회 논문집
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    • 제5권2호
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    • pp.191-197
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    • 2001
  • In this study, the admixtures for agents for enduring cold weather used widely are collected and applied to cement mortar to analyze the strength development due to variation of curing temperature at early age. The test results show that anti-freezing admixture have some problems due to high chloride content, which may cause the corrosion of reinforcement embedded in concrete. However, the mortar applied by accelerator and another kind of agent for enduring cold weather produced by S company lead to delay of strength development in low temperature. Also, it is clarified that there are no significant problems for cement mortar in strength development due to low temperature if a suitable kind of agent enduring cold weather is used and cement mortar is cured for more than $7.5^{\circ}D.D$ at early age.

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Effects of Curing Agent on the Corrosion Protection of Diglycidyl Ether Bisphenol-A Based Epoxy Coating

  • Shon, MinYoung;Kwon, HyukSang
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.344-349
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    • 2008
  • Epoxy coatings were prepared to give a different corrosion protection by reacting it with two different kinds of curing agent, and then effects of the curing agents on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protection of epoxy coatings were examined using hygrothermal cyclic test, and impedance analysis. In the results of EIS, the corrosion protection of epoxy coating cured by polyamide shows better than epoxy coating cured by polyamide epoxy adduct. It was well agreed with its water transport behavior and hydrophobic tendency.