• Design & Manufacturing
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• 제7권1호
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• pp.60-63
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• 2013

Recently, Silicone that one of the thermo-sets is used to making optical products such as LED lenses because of excellent thermal properties. LED lenses are required to keep the precise dimensions, so they must be molded to have the minimum deformation. Thermo-sets have the expansion characteristic on the part of thermal property, it is important to optimize the cure condition so that the deformation of the part become minimum. In this study, to investigate the relationship between the shrinkage by the curing and expansion by the thermal properties of the resin, reactive injection experiment was performed by setting the variables such as mold setting temperature, cure time. As a result, it was confirmed that there was a interval while the thermal properties were transferred to more active during the cure process. It is expected to help in determining the reactive injection molding conditions of the thermo-set parts as well as LED lens in order to reduce the amount of deformation.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.659-664
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• 2001

This paper was studied to effects of fatigue by low flexural load on micro structures and carbonation of mortar. Mortar specimens cured at various conditions were first subjected to bending repeated loads, and it was made clear that insufficient cure reduced fatigue resistance of them. Next, fatigue tests that the stress levels are lower than the ones of fatigue rupture were carried out, The effect of curing conditions in early age on carbonation was furthermore studied using the scale, and it was made clear that insufficient cure is also susceptible to carbonation of them. Finally, the reason for rapid carbonation of fatigued mortars insufficiently outed was discussed from the view point of changes in pore structure of them.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.227-230
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• 1998

The effects of post curing conditions on thermal properties of alumina filled epoxy resin system DGEBA/MDA/SN were investigated. As the post curing time increased at 15$0^{\circ}C$, the glass transition temperature increased from 121 to 124, slightly. As the heating rate increased, high thermal decomposing temperature (T$_{d}$) and most decomposing temperature (T$_{p}$) increased. For the case of post-cured system at 15$0^{\circ}C$ for 4 days showed lower values than virgin system. At the post curing condition the system must have been thermally degraded.ded.

• Composites Research
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• 제31권4호
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• pp.171-176
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• 2018

인공 건식 접착 구조를 위한 새로운 마이크로-나노 계층구조 제작기법을 제안하였으며, 모세관법을 활용한 마이크로 구조 내 나노 소재 정렬에 대한 기초 연구를 수행하였다. 다중 벽 탄소나노튜브(MWCNT)와 폴리디메틸실록산(PDMS) 혼합물의 제작 조건에 따른 경화도 및 점도 특성을 분석하고, 이로부터 몇 가지 제작 조건을 결정하였다. MWCNT-PDMS 마이크로 구조 제작 후 단면 분석을 통해 PDMS내 MWCNT의 정렬 특성을 분석한 결과, 제작 온도와 상대 경화도가 낮을 경우 MWCNT의 정렬도가 우수하며, 단위 면적당 MWCNT의 밀도는 제작 온도나 상대 경화도에 영향을 적게 받는 것으로 확인되었다.

• Asian Pacific Journal of Cancer Prevention
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• 제15권22호
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• pp.9673-9678
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• 2014

Background: Breast cancer is a fatal disease and the most frequently diagnosed cancer in women with an increasing pattern worldwide. The burden is mostly attributed to metastatic cancers that occur in one-third of patients and the treatments are palliative. It is of great interest to determine factors affecting time from cancer diagnosis to secondary metastasis. Materials and Methods: Cure rate models assume a Poisson distribution for the number of unobservable metastatic-component cells that are completely deleted from the non-metastasis patient body but some may remain and result in metastasis. Time to metastasis is defined as a function of the number of these cells and the time for each cell to develop a detectable sign of metastasis. Covariates are introduced to the model via the rate of metastatic-component cells. We used non-mixture cure rate models with Weibull and log-logistic distributions in a Bayesian setting to assess the relationship between metastasis free survival and covariates. Results: The median of metastasis free survival was 76.9 months. Various models showed that from covariates in the study, lymph node involvement ratio and being progesterone receptor positive were significant, with an adverse and a beneficial effect on metastasis free survival, respectively. The estimated fraction of patients cured from metastasis was almost 48%. The Weibull model had a slightly better performance than log-logistic. Conclusions: Cure rate models are popular in survival studies and outperform other models under certain conditions. We explored the prognostic factors of metastatic breast cancer from a different viewpoint. In this study, metastasis sites were analyzed all together. Conducting similar studies in a larger sample of cancer patients as well as evaluating the prognostic value of covariates in metastasis to each site separately are recommended.

• 한국산학기술학회논문지
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• 제10권7호
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• pp.1661-1667
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• 2009

TGA 열분석법을 이용하여 LCD 백라이트 램프 홀더용으로 사용되는 실리콘 고무성형품샘플에 대하여 서로 다른 몇 가지 온도에서의 등온 후가교 특성을 연구하였다. 특히 실제 사용 환경에서의 내열조건과 관련된 후가교 특성 및 적정 후가교 조건에 대하여 촛점을 맞추어 연구하였고 시간-온도중첩원리를 응용하는 촉진 실험법의 적용 가능성을 알아보았다. LCD 램프홀더용의 실리콘 재료의 실제 사용 환경을 고려할 때, 휘발성 물질의 배출에 의한 중량감소가 처음 시작되는 온도인 Ti가 가장 중요한 고려 요인이며, 이를 고려하여 도출되는 후가교 조건은 $250^{\circ}C$, 2시간이 적절한 것으로 생각되었다. 시간-온도 중첩원리와 실험적으로 결정된 이동인자는 Arrhenius식을 잘 만족함을 보여 주었으며 이로부터 후가교과정은 활성화에너지 108.25kJ/mol의 값을 가지는 단일 메커니즘으로 진행됨을 알 수 있었다.

• Restorative Dentistry and Endodontics
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• 제23권1호
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• pp.68-93
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• 1998

The physical properties of polymer are greatly influenced by the extent to which a resin cures. The presence of un reacted monomer can, have a plasticizing effect on the polymer, thereby altering the physical and mechanical properties of dentin bonding agent (DBA). If the DBA does not polymerize sufficiently, it will leave a weak bonding layer and lead to lower bond strength. The purpose of this study was to evaluate the shear bond strengths(SBS) and the degree of conversion (DC) of 4 commercialy avilable dentin bonding systems which are composed of 2 multi-bottle systems [Scotchbond Multi-Purpose (SMP), AeliteBond(AB)] and 2 onebottle systems [SingleBond(SB), One-Step(OS)]. For shear bond strength measurement, labial surfaces of freshly extracted bovine incisors were ground with # 600 grit SiC paper to expose dentin. Four different groups of samples were formed, with 10 samples. being made for each of the 4 commercial DBA in each group according to the curing sequences of DBA and overlayer thickness of composites: Group I (standard cure and 1mm thick composites) : The DBA was light cured and the composites of 1mm thickness was applied ; Group II (standard cure and 2mm thick composites) : The DBA was light cured and the composites of 2mm thickness was applied; Group III (simultaneous cure and 1mm thick composites) : The DBA was not light-cured and simultaneously cured with composites of 1mm thickness; Group N (simultaneous cure and 2mm thick composites) : The DBA was. not light-cured and simultaneously cured with composites of 2mm thickness. The SBS was measured immediately after the composites was bonded to the bovine dentin using an Instron machine. The DC of the DBA was examined in a thin film under simulated conditions of the experimental groups according to the curing sequences and overlayer thickness of composites in the SBS test. using a Fourier transform Infrared(FTIR) spectrometer. The following results were obtained from SBS tests and DC measurements 1. In SBS tests, the multi-bottle DBA(SMP, AB) had a generally higher bond strength values than the one bottle DBA(SB, OS). In DC measurements, the one bottle DBA(SB, OS) had a significantly higher DC than the multi-bottle DBA(SMP, AB). 2. In all DBAs except OS, there was no significant difference between the bond strength of group I (standard cure and 1mm thick composites) and that of group III (simultaneous cure and 1mm thick composites). SMP, SB in Group I had a significantly higher DC than those in group III, but AB, OS in group I had a significantly lower DC than those in group III 3. All DBAs in Goup II (standard cure and 2mm thick composites) had significantly higher bond strength and DC than those in Group N (simultaneous cure and 2mm thick composites). 4. In all DBAs, there was no significantly different SBS and DC between Group I and Group II, but all DBAs in Group III had significantly higher SBS and DC than those in Group IV.

• 한국건축시공학회지
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• 제5권4호
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• pp.115-120
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• 2005

In recent years, polymer-modified mortars using polymer dispersions have been widely used as finish and repair materials in the construction industry because of their excellent properties compares to those of ordinary cement mortar. Especially, the adhesion improvement of ordinary cement mortar and concrete has attracted a great deal of attention from researchers, and several unique and simply applicable techniques for the adhesion improvement have been developed. The purpose of this study is to evaluate the abrasion resistance of polymer-modified mortar according various curing methods. The polymer-modified mortar are prepared with various polymer-cement ratios, and are subjected to three curing methods such as dry rure, standard cure and freezing and thawing cure after two curing methods, and then tested for abrasion. From the test results, the polymer-modified mortars with various polymer-cement ratios have some superior abrasion resistance compared with plain mortar. The abrasion resistance of polymer-modified mortars increase with an increase in the polymer-cement ratio, and is better under water cure than any other curing methods. It is concluded that the abrasion resistance of cement mortar is markedly improved by modifying of polymer dispersion.

• 대한소아치과학회지
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• 제25권4호
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• pp.731-748
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• 1998

The purpose of this study was to test the hypothesis that the more thorough cure of lightactivated composite resin could be obtained if a new way of delivering the light source deep through the resin body is developed when compared to the conventional bulk cure or incremental cure. Using cylindrical resin blocks and natural teeth, various curing conditions were tested for their effects on the degree of microleakage and microhardness. Data were analyzed statistically using One-Way ANOVA and Scheff's Multiple Range test. The results of the present study were as follows: 1. The increment of reduction in microhardness with depth was shown to be higher in group I and II than in group II and V. 2. At the level of lower inner surface and the bottom surface, significantly lower microhardness values were obtained in group I and II when compared to group III, IV and V. Group IV showed the lowest value among three groups(III, IV, V) representing the only statistically significant difference from group V(p<05). 3. Differences between groups in the degree of microleakage detected were shown to be statistically significant (p<05) with the exception of group IV and V at both occlusal and gingival margins. 4. Based upon the above-mentioned results, commonly cited recommendation of incremental curing is strongly supported and the light-transmitting wedge insertion method can be considered as a effective and feasible clinical procedure for the better curing of composite resin. However, more studies under a variety of conditions should be completed before this method is applied actually to the clinical setting.

• E2M - 전기 전자와 첨단 소재
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• 제10권6호
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• pp.519-527
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• 1997

The micro crack was occurred where the stress concentrated by the thermal stress which was induced during the cooling period after molding process or by the various reliability tests. In order to estimate the possibility of development from inside micro crack to outside fracture, the fracture toughness of EMC should be measured under the various applicable condition. But study was conducted very rarely for the above area. In order to provide a was to decide the fracture resistance of EMC (Epoxy Molding Compound) of plastic package which is produced by using transfer molding method, measuring fracture is studied. The specimens were made with various EMC material. The diverse combination of test conditions, such as different temperature, temperature /humidity conditions, different filler shapes, and post cure treatment, were tried to examine the effects of environmental condition on the fracture toughness. This study proposed a way which could improve the reliability of LOC(Lead On Chip) type package by comparing the measured $J_{IC}$ of EMC and the calculated J-integral value from FEM(Finite Element Method). The measured $K_{IC}$ value of EMC above glass transition temperature dropped sharply as the temperature increased. The $K_{IC}$ was observed to be higher before the post cure treatment than after the post cure treatment. The change of $J_{IC}$ was significant by time change. J-integral was calculated to have maximum value the angle of the direction of fracture at the lead tip was 0 degree in SOJ package and -30 degree in TSOP package. The results FEM simulation were well agreed with the results of measurement within 5% tolerance. The package crack was proved to be affected more by the structure than by the composing material of package. The structure and the composing material are the variables to reduce the package crack.ack.