• Title/Summary/Keyword: curable

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Development of UV curable polymer and curing characteristics estimation for UV nanoimprint (UV 나노임프린트를 위한 UV 경화성 수지 개발 및 경화 특성 평가)

  • 이진우;이승재;이응숙;정준호;조동우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1220-1223
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    • 2003
  • The UV nanoimprint technology uses the UV light as the energy source. Because the imprint process is carried out in room temperature and low pressure, this technology has its own merits compared to the thermal nanoimprint. However, in UV nanoimprint technology, a resin which has low viscosity is essential for the improvement of accuracy. In this research, a resin (named as IMS01) which has relatively low viscosity was developed. And a measurement system was developed in order to measure the degree of cure of the resin. The measurement system which is composed of FT-IR, UV light source and optical guide can measure the degree of cure in real time. From the experimental results, it was found that the IMS01 is cured more rapidly than existing resin (PAK01).

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Electrochemical Properties of Lithium-Ion Polymer Battery with PMMA IPN-Based Gel Polymer Electrolyte (PMMA IPN계 겔폴리머전해질을 채용한 리튬이온폴리머전지의 전기화학적 특성)

  • 김현수;신정한;나성환;엄승욱;문성인;김상필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.994-1000
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    • 2003
  • In this study, gel polymer electrolytes (GPE) with semi-interpenerating network of poly (methyl methacrylate) and hexanediol dimethacrylate were synthesized and their electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing 5 vol% curable mixture had a low viscosity relatively. GPE showed good electrochemical stability up to potential of 4.8 V vs. Li/Li$\^$+/. Ionic conductivity of the gel polymer electrolyte at room temperature and -20$^{\circ}C$ was ca. 5.9 and 1.4${\times}$10$\^$-3/ Scm$\^$-1/, respectively. LiCoO$_2$/GPE/graphite cells showed good rate capability, low-temperature performance and cycleability.

Studies on the m-Toluate Degradating Plasmid in Pseudomonas (m-Tluate를 분해하는 Peudomonas의 분리 및 Dgradative Pasmid와의 연관성에 관하여)

  • 박순희;하영칠;홍순우
    • Korean Journal of Microbiology
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    • v.17 no.1
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    • pp.25-41
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    • 1979
  • A strain able to grow up m-toluate minimal medium has been isolated after selective enrichment and given the name T81X, which was later identified as pseudomonase putida according to its morphological and biochemical characteristics. After treatment with plasmied specific curing agent, mitomycin C, followed by replica plating on m-toluate and xylene minimal agar plate, T81Xstrain has been shown to harbour a curable plasmid relating to the m-toluate and xylene metabolism. Spontaneous curing frquency of this plasmid was also greatly enhanced by growing on benzoate minimal medium. After then, it was also xylene metabogrowing on benzoate minimal medium. After then, it was found to be conjugally nontransmissible. From the comparative investigation of catechol 1,2-oxygenase and catechol 2,3-oxygenase activities in wild type and cured strain on various growth substrate, it appeared that T81X strain has both of these two enzymes while cured strain has catechol 1,2-oxygenase only. Growing on m-toluate minimal medium T81X strain should carry the genetic information necessary for coding the catechol 1,2-oxygense induced by m-toluate or benzoate, on that curable plasmid.

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Electrochemical Properties of Cross-linked Polyurethane Acrylate-Based Gel Polymer Electrolyte

  • Kim, Hyun-Soo;Kim, Sung-Il;Choi, Gwan-Young;Moon, Seong-In;Kim, Sang-Pil
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.197-201
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    • 2002
  • In this study, a gel polymer electrolyte was prepared from urethane acrylate and its electrochemical performances were evaluated. And, $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. Ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.7\times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed electrochemical stability up to potential of 4.5V vs. $Li/Li^+.LiCoO_2/GPE/graphite$ cell showed a good high-rate and a low-temperature performance.

Electro-optical characteristics of PVA (Z-shape) mode using the UV curable reactive mesogen (RM) (광경화성 단분자를 이용한 Z-shape PVA 모드에서의 투과율 향상에 관한 연구)

  • Cho, In-Young;Hwang, Seong-Jin;Kim, Sung-Min;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.437-438
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    • 2008
  • The Conventional patterned vertical alignment (PVA) device shows a very high contrast ratio at normal direction and does not require rubbing process. However it has a disclination area in which the liquid crystal can be collision in the boundary domain region. In this paper, we studied PVA(Z-shape) device in which the liquid crystal can be tilted down in multiple directions stably because the surface pretilt angle is controlled by photopolymerization of the UV - curable reactive mesogen (RM) under a proper condition. Consequently, the device shows improved electro optical properties as compared to conventional PVA mode.

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Relationship between Structure and Properties of UV-Curable Polyurethane Acrylate Ionomers

  • 김태우;김한도
    • Proceedings of the Korean Fiber Society Conference
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    • 1996.10a
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    • pp.468-472
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    • 1996
  • A series of UV-curable polyurethane acrylate ionomer were synthesized from isophorone diisocyanate(IPDI), poly(tetramethylene ether glycol)(PTMG), 2,2-bis(hydroxymethyl)propionic acid (CMPA), triethylamine(TEA), 2-hydroxy ethyl acrylate (HEA), and dibutyl tin dilaurate (DBT) as a catalyst. 2,2-dimethoxy-2-phenyl acetophenone(DMPAP) was used as a photoinitiator. The films of UV-cured polyurethane acylate ionomer were prepared by casting the formulated materials onto a glass plate at room temperature and cured using a medium pressure mercury lamp (80 W/cm, max = 365nm). Effects of DMPA content, molecular weight of PTMG and degree of neutralization on the properties were invesigated. It is found that the storage modulus increased with increasing DMPA content. The glass transition temperature of sample A shifted to higher temperature as the content of DMPA was increased. Tensile modulus also increased with increasing DMPA content. Modulus and Tg decreased with increasing molecular weight of PTMG form 650 to 2000. With increasing the degree of nutralizaion, ionomers exhibited improved modulu.

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Properties of Coating Films Synthesized from Colloidal Silica and UV-curable Acrylate resin (UV경화형 아크릴 수지와 콜로이드 실리카로 합성된 코팅막의 특성)

  • Kang, Young-Taec;Kang, Dong-Pil;Han, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.551-552
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    • 2007
  • Coating films were prepared from silane-terminated Colloidal silaca(CS) and UV-curable acrylate resin. The silane-terminated CSs were synthesized from CS and methyltrimethoxysilane(MTMS) and then treated with 3-methacryloxypropyltrimethoxysilane(MAPTMS)/3-glycidoxypropyltrimethoxysilane( GPTMS)/vinyltrimethoxysilane(VTMS) by sol-gel process, respectively. The silane-terminated CS and acrylate resin were hybridized using UV-curing system. Thin films of hybrid material were prepared using spin coater on the glass. Their hardness, contact angle and transmittance improved with the addition of silane-terminated CS.

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