• 제목/요약/키워드: curable

검색결과 452건 처리시간 0.029초

이온빔 처리된 폴리머 표면의 자가나노구조화를 이용한 반사방지 필름 제조용 소프트 몰드 임프린팅 연구 (Soft Mold Imprinting Fabrication of Anti-reflection Film using Self-Organized Nanostructure Polymer Surfaces Irradiated by Ion Beams)

  • 이승훈;변은연;최주연;정성훈;유병길;김도근
    • 한국표면공학회지
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    • 제50권6호
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    • pp.480-485
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    • 2017
  • Soft mold imprinting method that uses nanostructured polymer mold was investigated for anti-reflection film fabrication. The nanostructured soft mold was polyethylene terephthalate(PET) irradiated by oxygen ion beams. The collisional energy transfer between oxygen ion and the polymer surface induced cross-linking and scission reactions, resulting in self-organized nanostructures with regular patterns of the wavenumber of $5{\mu}m^{-1}$. Post processes including ultra-violet curable resin coating and delamination fabricated anti-reflection films. The imprinted resin surface also showed the consistent wavenumber, $5{\mu}m^{-1}$. Pristine PET, oxygen ion beam treated PET, and imprinted replica sample showed total transmittance of 91.04, 93.25, and 93.57-93.88%, respectively.

고분자 표면 배향을 이용한 광학 보상 퍼짐 셀의 특성 향상 연구 (Study on Electro-optical Characteristics in the Optically Compensated Splay Cell using Polymer Surface Alignment)

  • 김성수;황성진;황성한;이명훈;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.424-425
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    • 2007
  • We have studied the optically compensated splay mode using reactive mesogen (RM) monomer to reduce setting voltage and phase transition time from initial bend to splay state. When the OCS cell has low pretilt angle close to $45^{\circ}C$, OCS state can be formed easily. The low pretilt angle was formed through the polymerization of UV curable reactive RM monomer at the surfaces. In this way, reorientation of the LC is well defined and thus the device shows better performances in setting voltage and phase transition time.

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졸-젤 공정을 이용한 광경화형 폴리우레탄 변형 아크릴레이트/실리카 하이브리드 필름의 제조 (Preparation of UV-Curable Polyurethane Modified $Acrylate/SiO_2$ Hybrid Film Using Sol-Gel Process)

  • 남대우;남병욱;차봉준;김백진
    • 폴리머
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    • 제31권2호
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    • pp.111-116
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    • 2007
  • 폴리우레탄 변형 아크릴레이트(PUA)/실리카 하이브리드 필름은 자외선 경화에 의해 제조되었고, 필름의 표면물성은 경도시험과 접착력 테스트를 통해 분석되었다. 이들 필름은 유기, 무기함량을 mole비로 조성하여 실험하였으며, 무기조성은 실리카 입자의 함량을 기준으로 설정하였다. 필름 층 내의 실리카 입자는 함량에 따라 혹은 분산정도에 따라 내스크래치성이나 필름자체 경도 등의 물성이 많은 차이를 보였는데, 이는 PUA필름 층 내의 실리카 입자들이 균일하게 분포되어 가교결합되어 있었기 때문이다.

하이브리드 쾌속 조형 시스템의 개발 및 나노 복합재 부품 제작 (Development of Hybrid RP System and Fabrication of Nano Composite parts)

  • 김성근;정우균;추원식;김형중;안성훈
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.220-223
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    • 2005
  • The rapid prototyping (RP) technology has been advanced for various applications such as verification of design, functional test. However, many RP machines still have low accuracy and limitation of applications for various materials. In this research, a hybrid RP system was developed to improve precision of micro parts. This hybrid system consists of deposition and material removal process by mechanical micro machining to fabricate nano composites using photo-curable polymer resin with various nano particles. In this work, using hybrid RP process with Multi-Walled Carbon Nano Tube (MWCNT) and hydroxyapatite, micro parts were fabricated. The precision of parts was evaluated based on the original CAD design, and to see the effect of nano particles on mechanical properties, tensile strength was measured. From the results of experiments, it was confirmed that the part made by hybrid process had higher precision, and the addition of nano particles improved mechanical properties.

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마이크로 광 조형에서 레이저 주사조건에 따른 광 경화성수지의 경화현상 (Photopolymer Solidification Phenomena Considering Laser Exposure Conditions in Micro-stereolithography Technology)

  • 이인환;조동우;이응숙
    • 한국정밀공학회지
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    • 제21권3호
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    • pp.171-179
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    • 2004
  • Micro-stereolithography technology has made it possible to fabricate a freeform 3D microslructure. This technology is based on conventional stereolithography, in which a UV laser beam irradiates the open surface of a UV-curable liquid photopolymer, causing it to solidify. In micro-stereolithography, a laser beam of a few $\mu m$ diameter is used to solidify a very small area of the photopolymer. This is one of the key technological elements, and can be achieved by using a focusing lens. Thus, the solidification phenomena of the liquid photopolymer must be carefully investigated. In this study, the photopolymer solidification phenomena in response to variations in the scanning pitch of a focused laser beam was investigated experimentally. The effect of layer thickness on the solidification width and depth was also examined. These studies were conducted under the conditions of relatively lower laser power and relatively higher scanning speed. Moreover, the photopolymer solidification phenomena for the relatively higher laser power and lower scanning speed was investigated, too. In this case, comparing to the case of lower laser power and higher scanning speed, the photopolymer absorbed large amount of irradiation energy of the laser beam. These results were compared with those obtained from a photopolymer solidification model. From these results, a new laser-scanning scheme was proposed according to the shape of the 3D model. Samples by each method were fabricated successfully.

Relationship between Printability and Rheological Properties of UV-curable Flexographic Ink

  • Jeong, Kyoung-Mo;Koseki, Ken'ichi
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.209-213
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    • 2006
  • Relationship between printability and rheological properties of UV flexographic (flexo) inks were investigated. UV flexo suspensions of carbon black in liquid medium having various binding materials such as acylate pre-polymer, di/multi-functional monomer, and diluents, were used as sample inks. Inks were characterized on a rheometer in terms of steady and dynamic behaviors. To understand the rheological properties of UV flexo inks, we must determine the specific rheological properties of chemical and/or physical interactions of their components (pigments, functional monomers, and pre-polymers). In particular, we discussed the influence of multi-functional monomers and the relationship between the rheological properties and transient networks formed by carbon black. In this study, we investigated the interrelationships between rheological properties of UV flexo inks and chemical and/or physical interactions of their components. To investigate correlations between the printability and the rheological behaviors induced by interfacial interactions between ink compositions, we carried out rheological tests of UV ink suspensions. The results were compared with printing tests so as to find out the relationship between printability and rheological properties of ink.

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카메라 렌즈 표면에 형성된 미세 패턴의 내구성 향상 기법 제안 (Proposed Approaches on Durability Enhancement of Small Structure fabricated on Camera Lens Surface)

  • 박홍주;최인범;김두인;정명영
    • 한국산업융합학회 논문집
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    • 제22권5호
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    • pp.467-473
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    • 2019
  • In this study, approached to improve durability of the multi-functional nano-pattern fabricated on the curved lens surface using nanoimprint lithography (NIL) was proposed, and the effects of the proposed methods on functionality after wear test were examined. To improve the mechanical property of ultraviolet(UV)-curable resin, UV-NIL was conducted at the elevated temperature around $60^{\circ}C$. In addition, micro/nano hierarchical structures was fabricated on the lens surface with a durable film mold. Analysis on the worn surfaces of nano-hole pattern and hierarchical structures and measurements on the static water contact angle and critical water volume for roll-off indicated that the UV curing process with elevated temperature is effective to maintain wettability by increasing hardness of resin. Also, it was found that the micro-scale pattern is effective to protect nano-pattern from damage during wear test.

Primary Amebic Meningoencephalitis: A Case Report

  • Chen, Minhua;Ruan, Wei;Zhang, Lingling;Hu, Bangchuan;Yang, Xianghong
    • Parasites, Hosts and Diseases
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    • 제57권3호
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    • pp.291-294
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    • 2019
  • Primary amebic encephalitis (PAM) is a devastating central nervous system infection caused by Naegleria fowleri, a free-living amoeba, which can survive in soil and warm fresh water. Here, a 43-year-old healthy male was exposed to warm freshwater 5 days before the symptom onset. He rapidly developed severe cerebral edema before the diagnosis of PAM and was treated with intravenous conventional amphotericin B while died of terminal cerebral hernia finally. Comparing the patients with PAM who has similar clinical symptoms to those with other common types of meningoencephalitis, this infection is probably curable if treated early and aggressively. PAM should be considered in the differential diagnosis of purulent meningoencephalitis, especially in patients with recent freshwater-related activities during the hot season.

수용해성 사이클로포스파젠 유도체를 이용한 면섬유의 내구성 방염가공 (Durable Flame-Retardant Finish of Cotton Fabrics Using a Water-soluble Cyclophosphazene Derivative)

  • 김정환;장진호
    • 한국염색가공학회지
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    • 제33권2호
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    • pp.64-71
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    • 2021
  • Large amount of formaldehyde could be released inevitably during the flame-retardant (FR) treatments or from the finished fabrics using Provatex reagent and Proban polymers which have been used as durable FRs for cotton. A water-soluble cyclophosphazene derivative was synthesized as an ecofriendly phosphorus-based FR for cotton fibers. Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) was synthesized through the substiutution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] methacrylamide at a mole ratio of 1 : 4, which can be cured dually by both alkaline treatment and UV irradiation. More crosslinked networks were produced through the addition of Triacryloyl hexahydrotriazine and Acrylamide as a UV-curable crosslinker and a comonomer respectively. Both flame retardancy and washing durability of the FR cotton were improved synergistically. The durability improvement may be caused by the covalent bond formation of the FR with cellulose and the high degree of polymerization of DCTDCP, which can be verified by the pyrolysis and combustion behaviors analyzed by LOI, TGA, and microcalorimeter.

광중합형 복합레진 충전 건강보험 급여화에 대한 보호자의 인식과 만족도 (Awareness & satisfaction of caregivers on the health insurance coverage of light-curable composite resin restoration)

  • 유슬아;이수영
    • 한국치위생학회지
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    • 제21권1호
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    • pp.89-98
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    • 2021
  • Objectives: The purpose of this study was to investigate the perception and satisfaction of caregivers and parents after being covered by health insurance for light-curing composite resin fillings, and to contribute to the settlement of the expansion and coverage of health insurance. Methods: A survey was conducted on caregivers who visited two dental institutions in the Gyeonggi-do area, and parents who joined internet cafes (online communities) in the Gyeonggi-do area from June 2 to September 2, 2020. 225 responses were collected eventually, and 212 valid responses were used as analysis data. Results: 67.0% of the study subjects were aware of the permanent teeth resin fillings being covered by health insurance and the satisfaction was relatively high (91.5%). There was a statistically significant difference in the perception of permanent tooth resin filling benefits according to the child's oral condition (p=0.025) and the parents' own interest in oral health (p=0.039). Conclusions: Based on the results of this study, it is necessary to increase the accessibility to the initial treatment for dental care of children through active promotion of detailed items of permanent teeth resin fillings.