• 제목/요약/키워드: crystallization characteristics

검색결과 433건 처리시간 0.023초

폴리락트산/폴리카프로락톤 블렌드의 결정화 거동 (Crystallization Behavior of Poly(lactic acid) / Poly($\varepsilon$-caprolactone) Blends)

  • 이종록;천상욱;강호종
    • 폴리머
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    • 제27권4호
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    • pp.285-292
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    • 2003
  • 폴리락트산/폴리카프로락톤 (PLA/PCL) 블렌드의 조성비에 따른 상용성 및 결정화 거동을 살펴보았다. 특히 triphenyl phosphite (TPP)가 반응 상용화제로써 이들 블렌드의 상용성과 결정화 거동에 미치는 영향을 중점적으로 고찰하였다. PLA/PCL 블렌드의 열적 특성을 살펴보아 이들 블렌드가 비상용성 블렌드임을 확인하였으며 블렌드의 조성비에 따라 상용성 정도가 달라졌다. 블렌드에 TPP를 첨가하는 경우 TPP가 반응 상용화제로 작용하여 블렌드의 상용성을 증가시키며 상용화제 함량 증가에 따라 상용성이 우수해졌다. PLA에 PCL을 첨가하는 경우, 블렌드 조성비에 따른 비상용 특성에 의한 계면 형성이 구정 형성에 필요한 기핵 발현 정도를 변화시켜 결정화 속도가 달라졌다. TPP는 이들 블렌드의 상용성의 개선과 동시에 구정 성장을 촉진하여 PLA의 결정화 속도를 증가시킴을 확인하였다.

아연결정유약의 결정 생성 및 제어를 위한 Zn2TiO4 활용 연구 (Application of Zn2TiO4 for nucleation and control of willemite crystalline glaze)

  • 이현수
    • 한국결정성장학회지
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    • 제27권4호
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    • pp.154-161
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    • 2017
  • Anatase 형 $TiO_2$에 의해 저온에서 생성되는 $Zn_2TiO_4$는 willemite($Zn_2SiO_4$) 결정 전구체로 유약 내 willemite 생성에 매우 큰 영향을 준다. 안정적인 willemite 생성 및 위치 제어를 위해 $Zn_2TiO_4$를 활용하였다. 합성된 $Zn_2TiO_4$를 화장토(engobe)에 15 wt% 첨가하여 도포하면 유약 내에 결정의 생성과 위치를 조절할 수 있다. 발색제가 고용된 $Zn_2TiO_4$를 화장토에 적용하면 결정부분에만 발색효과를 얻을 수 있다. $Zn_2TiO_4$를 화장토(engobe)로 적용하면 한 번의 시유로 결정의 생성유무와, 위치, 색상 등을 임의로 조절할 수 있고 유약의 장식 효과를 높일 수 있다.

Effects of Nucleating Agents on Preparation of Polypropylene Hollow Fiber Membranes by Melt Spinning Process

  • Kim, Bong-Tae;Kigook Song;Kim, Sung-Soo
    • Macromolecular Research
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    • 제10권2호
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    • pp.127-134
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    • 2002
  • Microporous polypropylene hollow fiber membrane was fabricated from isotactic polypropylene-soybean oil system by melt spinning process. Addition of nucleating agent accelerated the crystallization rate and elevated the crystallization temperature. Nucleating agent increased the number of nuclei and spherulites, which offered more inter-spherulitic amorphous sites for stretching. Benzoic acid, adipic acid, and dibenzylidene sorbitol were selected as nucleating agents, and their characteristics and effects were investigated by thermal and optical analyses. Spherulite growth and micropore formation characteristics were correlated with the kind of nucleating agent. Benzoic acid and adipic acid showed the remarkable nucleating effect, while dibenzylidene sorbitol was less effective than those. Nucleating agents also helped the sample have uniform microporous structure. Increase of nucleating agent composition enhanced the nucleation effect to some extent. Nucleating agents played very important roles in enhancing the membrane porosity and water flux.

레이저 결정화 방법을 적용한 3차원 적층 CMOS 인버터의 전기적 특성 개선 (Electrical characteristics of 3-D stacked CMOS Inverters using laser crystallization method)

  • 이우현;조원주;오순영;안창근;정종완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.118-119
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    • 2007
  • High performance three-dimensional (3-D) stacked poly-Si complementary metal-oxide semiconductor (CMOS) inverters with a high quality laser crystallized channel were fabricated. Low temperature crystallization methods of a-Si film using the excimer-laser annealing (ELA) and sequential lateral solidification (SLS) were performed. The NMOS thin-film-transistor (TFT) at lower layer of CMOS was fabricated on oxidized bulk Si substrate, and the PMOS TFT at upper layer of CMOS was fabricated on interlayer dielectric film. The 3-D stacked poly-Si CMOS inverter showed excellent electrical characteristics and was enough for the vertical integrated CMOS applications.

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Phase Change Characteristics of Sb-Based Phase Change Materials

  • Park, Sung-Jin;Kim, In-Soo;Kim, Sang-Kyun;Choi, Se-Young
    • 한국재료학회지
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    • 제18권2호
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    • pp.61-64
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    • 2008
  • Electrical optical switching and structural transformation of $Ge_{15}Sb_{85}$, $Sb_{65}Se_{35}$ and N2.0 sccm doped $Sb_{83}Si_{17}$ were studied to investigate the phase change characteristics for PRAM application. Sb-based materials were deposited by a RF magnetron co-sputtering system and the phase change characteristics were analyzed using an X-ray diffractometer (XRD), a static tester and a four-point probe. Doping Ge, Se or Si atoms reinforced the amorphous stability of the Sb-based materials, which affected the switching characteristics. The crystallization temperature of the Sb-based materials increased as the concentration of the Ge, Se or Si increased. The minimum time of $Ge_{15}Sb_{85}$, $Sb_{65}Se_{35}$ and N2.0 sccm doped $Sb_{83}Si_{17}$ for crystallization was 120, 50 and 90 ns at 12 mW, respectively. $Sb_{65}Se_{35}$ was crystallized at $170^{\circ}C$. In addition, the difference in the sheet resistances between amorphous and crystalline states was higher than $10^4{\Omega}/{\gamma}$.