• Title/Summary/Keyword: crystal

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Growth and Optoelectric Characterization of $ZnGa_{2}Se_{4}$ Sing1e Crystal Thin Films (Hot Wall Epitaxy (HWE)에 의한$ZnGa_{2}Se_{4}$단결정 박막 성장과 광전기적 특성)

  • 박창선;홍광준
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.163-166
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    • 2001
  • The stochiometric mix of evaporating materials for the ZnGa$_2$Se$_4$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, ZnGa$_2$Se$_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperature were 61$0^{\circ}C$ and 45$0^{\circ}C$, respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of ZnGa$_2$Se$_4$ single crystal thin films measured from Hall effect by van der Pauw method are 9.63x10$^{17}$ cm$^{-3}$ , 296 $\textrm{cm}^2$/V.s at 293 K, respectively, From the photocurrent spectrum by illumination of perpendicular light on the c-axis of the ZnGa$_2$Se$_4$ single crystal thin film, we have found that the values of spin orbit splitting $\Delta$So and the crystal field splitting $\Delta$Cr were 251.9 MeV and 183.2 meV at 10 K, respectively. From the photoluminescence measurement on ZnGa$_2$Se$_4$ single crystal thin film, we observed free excition (E$_{x}$) existing only high quality crystal and neutral bound excition (A$^{0}$ ,X) having very strong peak intensity. Then, the full-width-at-half-maximum(FWHM) and binding energy of neutral acceptor bound excition were 11 meV and 24.4 meV, respectivity. By Haynes rule, an activation energy of impurity was 122 meV.on energy of impurity was 122 meV.

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Effects of the crucible shape on the temperature of sapphire crystal and the shape of melt/crystal interface in heat exchanger method (열교환법에서 도가니 형상 변화가 사파이어 결정 온도와 고/액 계면 형태에 미치는 영향)

  • 임수진;왕종회;임종인
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.4
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    • pp.155-159
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    • 2004
  • Numerical analysis which is based on finite element techniques, implicit Euler method and frontal solving algorithm was performed to study the effects of the crucible shape on the temperature of sapphire crystal and the shape of the melt/crystal interface in heat exchanger method. The computer simulation described here and effective to solving the heat transport phenomena with the transition of the interface shape from hemispherical to planar. In the work, various crucibles with differently shaped corners at their bottom are considered to improve the deflection of the melt/crystal interface. The shape of the crucible should be considered as one of the variables for the process optimization.

Crystal Structure of Ca1.29Bi0.14VO4

  • Kim, Myung-Seab;Lah, Myoung-Soo;Kim, Ho-Kun
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.98-102
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    • 2002
  • The structure of a single crystal, grown by a slow cooling a melt of $Ca_{1.29}Bi_{0.14}VO_4$ composition, was analyzed. The crystals belong to the rhombohedral space group R3c and the dimensions of the unit cells are a = 10.848(1)${\AA}$, c = 38.048(6)${\AA}$, V = 3877.6(8)${\AA}^3$ for the pale yellow crystal, and a = 10.857(1), c = 38.063(6)${\AA}$, V = 3885.6(8)${\AA}^3$ for the yellow crystal, respectively. Unit cell dimensions of the crystal were larger than those of the host crystal, $Ca_3(VO_4)_2$, owing to the Bi that replaced Ca in the unit cell. Ca in the unit cell formed six, eight and nine coordinated polyhedra with O atoms and Bi replacing Ca entered the eight or nine coordinated Ca sites with different crystallographic environments in the unit cell. All the V in the unit cell formed four coordinated tetrahedra with O atoms, however V-O bond lengths in the tetrahedra were different from one another.

A Study on Entrapment Efficiency of Rosmarinic Acid Using Liquid Crystal Phosphatidylcholin (포스파티딜콜린의 액정형성을 이용한 로즈마린산 포집 효율연구)

  • Kang, Ki-Chun
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.132-137
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    • 2013
  • The liquid crystal form with phosphatidylcholine contents containing in the hydrogenated lecithin was confirmed. Composition ingredients of the liquid crystal vesicle were phospholipid, ethanol and water and the rosmarinic acid was encapsulated as index material. The mean particle size of the liquid crystal vesicle appeared to form various particles form 480 nm to $3{\mu}m$ depending upon the lipid composition and ultrasonic handling time. The liquid crystal vesicle compared with the liposome showed a very high encapsulation efficiency. The quantity of liquid crystal vesicle increased with respect to the increased quantity of lipid contents in the hydrogenated lecithin. The result from release experiments of the liquid crystal vesicle containing rosmarinic acid showed that the liquid crystal vesicle releases much less than that of liposome.

Electron Microscopic Evidence of Paraporal Crystal Inclusion Biogenesis in Bacillus sphaericus Strain 1593

  • Lee, Young-Ju;Lee, Hyung-Hoan
    • Journal of Microbiology and Biotechnology
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    • v.11 no.6
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    • pp.1106-1110
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    • 2001
  • The parasporal biogenesis of crystal inclusion during the sporulation of Bacillus sphaericus strain 1593 was observed using transmission electron microscopy. The crystal biogenesis and sporulation process involved a sequence of events talking about 10 h. The sporulation Precesses were found to be similar to previous findings. The crystal biogenesis of B. sphaericus was initiated at the start of engulfment and nearly completed by the time of exosporium formation. The crystal formation was clearly associated with the outer forespore membrane from stages III through VI, and the crystals grew from polypeptide-like chains originated from the outer forespore membrane. These observations are different from previous findings, which report no association with the forespore membrane. The crystals were located adjacent to the outer membrane of the spore until the release stage. The axes size of the bipyramidal crystal was approximately $0.25{\mu}m{\times}42{\mu}m$. During crystal biogenesis, the crystal development could be classified into four stages; initiation stage Cl (sporulation stage . III), growth stage C2 (sporulation III to V), envelopment and maturation C3 (sporulation V to V), and finally release stage C4 (sporulation Vll).

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The growth and applicatiion of LBO crystal (LBO 결정성장과 응용)

  • Jinghe Liu;Jianli Li;Kuisheng Yang;Xiyan Zhang;Yagui Lei;Mu Na;Yuqi Zou;Renhua Zhang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.3
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    • pp.230-237
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    • 1994
  • The paper studies the growth and application of LBO Crystal and points that thermodynamics and dynamics model of crystal growth should be developed in high-$\eta$(viscosity) melt. The measurement on properties of crystal resonator and press-controlled oscillator indicates that this kind of crystal is one kind of piezo-electric crystal materials which has large-market application potentiality.

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Growth and Characterization for $CdIn_2S_4/GaAs$ Epilayers ($CdIn_2S_4$ 에피레이어 성장과 특성)

  • Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.239-242
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    • 2004
  • A stoichiometric mixture of evaporating materials for $CdIn_2S_4$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, $CdIn_2S_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by hot wall epitaxy(HWE) system. The source and substrate temperatures were $630^{\circ}C$ and $420^{\circ}C$ respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of $CdIn_2S_4$ single crystal thin films measured from Hall effect by van der Pauw method are $9.01{\times}10^{16}\;cm^{-3}$ and $219\;cm^2/V{\cdot}s$ at 293 K, respectively. From the optical absorption measurement, the temperature dependence of energy band gap on $CdIn_2S_4$ single crystal thin films was found to be $E_g(T)\;=\;2.7116\;eV\;-\;(7.74{\times}10^{-4}\;eV)T^2/(T+434)$. After the as-grown $CdIn_2S_4$ single crystal thin films was annealed in Cd-, S-, and In-atmospheres, the origin of point defects of $CdIn_2S_4$ single crystal thin films has been investigated by the photoluminescence(PL) at 10 K.

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The Evaluation of Multiplane-Parallel Chamber Using Crystal Plate as Ionization Medium for Therapeutic Radiation Beams

  • Young W. Vahc;Park, Kyung R.;Kim, Sookil;Chul W. Joh;Kim, Tae H.
    • Progress in Medical Physics
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    • v.9 no.1
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    • pp.29-35
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    • 1998
  • There has been necessity of an air free ionization chamber using the gold-crystal-aluminium plates, henceforth called the crystal chamber. The crystal chamber formed of parallel plates is very small in size and has more response for absorbed dose of therapeutic radiation beams. The gold plate on the crystal facing the photon and electron beam acts as an intensifier of signals and crystal plate as an ionization medium respectively. Both the copper guard ring and the aluminum collecting electrode are connected to an electrometer. Using high energy photon (6, 15 MV) and electron (9, 12, 15, 18 MeV) beams, the responses of the crystal chamber are evaluated against a PTW Farmer-type chamber at a field size of 10${\times}$10cm$^2$ and 100 cm SSD. The responses of crystal chamber for therapeutic radiation electron and photon beams are greater in magnitude by several order than Farmer. The crystal chamber has good linearity without correction factor C$\_$t,p/ with respect to the signals, a reading reproduction with good accuracy and precision less than 0.5%, and has other useful functions in measuring radiation beams.

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Consideration on Various Conditions of Two-Dimensional Crystal Arrays for the Next Generation PET Detector

  • Tsuda, Tomoaki;Murayama, Hideo;Kawai, Hideyuki;Inadama, Naoko;Umehara, Takaya;Kasahara, Takehiro;Orita, Narimichi
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2002.09a
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    • pp.318-321
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    • 2002
  • As a part of the next generation PET project, we have developed a depth of interaction detector which is consist of three-dimensional arrays of GSO crystal elements sized 2.9mm ${\times}$ 2.9mm ${\times}$ 7.5mm. The basic structure of a detector block is 4-stages in depth, one stage is composed of 2 by 2 array of the crystal elements. The blocks are optically coupled to a position sensitive photomultiplier tube. Each crystal element can be in different conditions; rough or chemical etching for the crystal surface. The effect of the difference of crystal surface condition on the detector performance was analyzed in one-dimensional crystal array as a basic study for the three-dimensional detector by a simple model which is considered only probabilities of transmission, reflect and absorption of photons are in a crystal. As the next step, we investigated the effect of different crystal surface condition in a "U shaped detector" which is an array of stacked crystals bending at the center.

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Y2BaCuO4 Segregarion , a Possibility of Multi-Seeding and the Origin of Diagonal Line in YBa2Cu3O7-$\delta$ Superconductor Single Crystal (YBa_{2}Cu_{3}O_{7-\delta} 고온초전도체 단결정에서의 Y_{2}BaCuO_{5} 편석과 Multi-Seeding의 가능성, 대각선 흔적의 형성 원인)

  • 성현태
    • Progress in Superconductivity and Cryogenics
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    • v.1 no.1
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    • pp.1-6
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    • 1999
  • The microstructures of top seed mult processde $\textrm{YBa}_2\textrm{Cu}_3\textrm{O}_7$.$\delta$ single crystal were studied. Although shape of the seed was not faceted. the growth shape of Y123 single crystal was faceted. It was observed that Y211 phases were trapped in specific spaces of the faceted region. From the microstructural investigation. it was suggested that the segregation of Y211 is due to the difference of growth rates in crystal direction. When a single crystal was grown by the single seed with stepped multi surfaces. a microstrue was grown from multi-seed. The microstructure show the possibility of multi-seed growth. Corn kernel like structure without Y211 phase was observed and seemed to be formed by the diffusion reaction between Y211 phase in crystal and liquid wetted on the crystal. the diagonal line on Y123 crystal was observed that it was formed by the corn kernel like structure.

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