• 제목/요약/키워드: cross-link density

검색결과 23건 처리시간 0.032초

카본블랙을 충전한 EPDM 고무호스의 가교밀도 측정과 열가속 및 산소 노화거동 (Cross-link Density Measurement and Thermal Oxidative Degradation Analysis of a Carbon Black Compounded EPDM Rubber Hose)

  • 곽승범;최낙삼;김진국
    • Composites Research
    • /
    • 제22권3호
    • /
    • pp.35-43
    • /
    • 2009
  • 본 연구에서는 카본블랙이 충전된 ethylene-propylene dine monomer(EPDM) 고무에 대한 가교밀도 측정법을 확립하고 EPDM 고무호스에 대해 열가속 및 산소스트레스를 가하여 가교밀도 변화를 측정하였다. 노화 초반에는 산화황가교의 형성으로 고무의 가교밀도측정값이 약간 저하하였다가 노화시간이 지남에 따라 일부 미반응 황 분자들의 가황반응으로 추가적인 가교 결합을 형성하면서 가교밀도측정값은 점차 증가하였다. 이들 가교밀도 변화거동은 인장강도의 거동과 유사하였다. $180^{\circ}C$의 고온노화에서는 노화시간이 길어짐에 따라 노화에 따른 가교밀도의 증가폭은 그다지 크지 않았으나, 인장강도와 신장률은 크게 저하하였다. 즉, 온도가 높을 수록 EPDM 고무의 가교밀도의 변동보다는 EPDM 분자사슬에서의 산화물(carbonyl groups) 형성과, 가교점의 산화황 생성으로 기계적 물성의 열화가 일어난 것이다.

전기자동차 구동용 모터를 위한 전류 제어 기술 (An Overview: Current Control Technique for Propulsion Motor for EV)

  • 이희광;남광희
    • 전력전자학회논문지
    • /
    • 제21권5호
    • /
    • pp.388-395
    • /
    • 2016
  • Electric vehicles (EV) and hybrid EVs (HEV) are designed and manufactured by GM, Toyota, Honda, and Hyundai motors. The propulsion system design process for EV requires integrating subsystem designs into an overall system model to maximize the performance of a given propulsion architecture. Therefore, high-power density and high-torque density are important attributes required for EV applications. To improve torque and power density, propulsion motors are designed for saturation during high-torque operation. The nonlinearity associated with core saturation is modeled by incorporating the cross-coupling inductances, which also behave nonlinearly. Furthermore, in EV environments, the battery is directly connected to the DC link, and the battery changes depending on the state of charge. It will be onerous if as many optimal current commands as different $V_{dc}$ were made. This paper presents the optimal current commands in the various operating condition and the current control technique in EV environments.

An Application of High-Power Ultrasound to Rubber Recycling

  • Hong, Chang-Kook;Isayev, A.I.
    • Elastomers and Composites
    • /
    • 제38권2호
    • /
    • pp.103-121
    • /
    • 2003
  • The application of powerful ultrasound to rubber recycling is a very recent field of study. An ultrasonic field creates high frequency extension-contraction stresses by acoustic cavitation. The breakdown of rubber network occurs primarily around pulsating cavities due to the highest level of strain produced by high-power ultrasound. Stronger reductions of cross-link density were observed at a higher pressure, indicating an important role of pressure during ultrasonic recycling. Visible bubbles were observed during ultrasonic treatment as a proof of acoustic cavitation. Shearing effect has a significant influence on improving the efficiency of ultrasonic treatment. After the ultrasonic treatment, the cross-link densities of NR/SBR blends were lower than those of NR and SBR due to the reduced degree of unsaturation and chemical reactions. Carbon black fillers increase the probability of bond scission during ultrasonic treatment, due to the restricted mobility. The mechanical properties of ground tire rubber (GRT)/HDPE blends were improved by ultrasonic treatment and dynamic revulcanization. Ultrasonic treatment of GRT in the presence of HDPE matrix was found to give better mechanical properties due to the chemical reactions between rubber and plastic phases.

입도분포해석에 의한 폐타이어 분말의 재활용 연구 (A Study on Recycling Technology of Waste Tire Powder by Particle Size Distribution Analysis)

  • 황성혁;정재흠;박소윤;김진국
    • Elastomers and Composites
    • /
    • 제38권2호
    • /
    • pp.128-138
    • /
    • 2003
  • 폐타이어의 증가로 인하여 환경문제가 날로 심각해지고 있다. 그러므로 효율적인 재활용을 통하여 이러한 문제를 해결하는데 많은 연구가 진행되고 있다. 본 연구에서는 폐타이어를 상온분쇄기를 제작하여 미세 분말화와 초음파로 처리를 통하여 기본물성을 높이는데 목적을 두었다. 폐고무 분말의 통계학적 분석에 의해서 미세화에 따른 물성의 변화와 물리적 성질을 조사하였고, 기계적 및 가교도 등의 물성을 조사하였다. 또한 광학현미경을 사용하여 표면을 확인함으로서 제품특성을 연구하였다.

Rock physics modeling in sand reservoir through well log analysis, Krishna-Godavari basin, India

  • Singha, Dip Kumar;Chatterjee, Rima
    • Geomechanics and Engineering
    • /
    • 제13권1호
    • /
    • pp.99-117
    • /
    • 2017
  • Rock physics modeling of sandstone reservoir from gas fields of Krishna-Godavari basin represents the link between reservoir parameters and seismic properties. The rock physics diagnostic models such as contact cement, constant cement and friable sand are chosen to characterize reservoir sands of two wells in this basin. Cementation is affected by the grain sorting and cement coating on the surface of the grain. The models show that the reservoir sands in two wells under examination have varying cementation from 2 to more than 6%. Distinct and separate velocity-porosity and elastic moduli-porosity trends are observed for reservoir zones of two wells. A methodology is adopted for generation of Rock Physics Template (RPT) based on fluid replacement modeling for Raghavapuram Shale and Gollapalli Sandstones of Early Cretaceous. The ratio of P-wave velocity to S-wave velocity (Vp/Vs) and P-impedance template, generated for this above formations is able to detect shale, brine sand and gas sand with varying water saturation and porosity from wells in the Endamuru and Suryaraopeta gas fields having same shallow marine depositional characters. This RPT predicted detection of water and gas sands are matched well with conventional neutron-density cross plot analysis.

Pentacene TFTs and Integrated Circuits with PVP as Gate Insulator

  • Xu, Yong-Xian;Byun, Hyun-Sook;Song, Chung-Kun
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
    • /
    • pp.1027-1029
    • /
    • 2004
  • In this paper, we have fabricated pentacene thin film transistors (TFTs) using polyvinylphenol (PVP) copolymer and cross-linked PVP as gate insulator on glass and plastic (PET) substrate. Depending on the density of PVP and cross-link material the performance has been changed. We obtained the best device performance with the mobility of 0.32cm2/V${\cdot}$sec and the on/off current ratio of 1.19${\times}$106 for the case of 10wt% PVP copolymer mixed with 5wt% poly (melamine-co-formaldehyde). Additionally using pentacene TFTs with the above PVP gate insulator, we fabricated the integrated circuits including inverter which produced the gain of 9.7.

  • PDF

The association of potassium intake with bone mineral density and the prevalence of osteoporosis among older Korean adults

  • Ha, Jinwoo;Kim, Seong-Ah;Lim, Kyungjoon;Shin, Sangah
    • Nutrition Research and Practice
    • /
    • 제14권1호
    • /
    • pp.55-61
    • /
    • 2020
  • BACKGROUND/OBJECTIVES: Osteoporosis is characterized by low bone mass and results in vulnerability to fracture. Calcium and vitamin D are known to play an important role in bone health. Recently, potassium has been identified as another important factor in skeletal health. We examined the link between potassium intake and bone health among the Korean older adult population. SUBJECTS/METHODS: This retrospective, cross-sectional study included 8,732 men and postmenopausal women over 50 years old who completed the Korean National Health and Nutrition Survey (KNHANES) between 2008 and 2011. Potassium consumption was evaluated using a 24-hour recall method. Bone mineral density (BMD) was measured at three sites (total hip, femur neck, and lumbar spine) by dual-energy X-ray absorptiometry (DEXA). Multinomial logistic regression was used to examine the link between potassium intake and prevalence of osteoporosis and osteopenia, after controlling for potential confounding variables. RESULTS: The BMD of the total femur and Ward's triangle were significantly different according to the potassium intake among men (P = 0.031 and P = 0.010, respectively). Women in the top tertile for potassium intake showed higher BMD than those in the bottom tertile at all measurement sites (all P < 0.05). Daily potassium intake was significantly related to a decreased risk of osteoporosis at the lumbar spine in postmenopausal women (odds ratios: 0.68, 95% confidence interval: 0.48-0.96, P trend = 0.031). However, the dietary potassium level was not related to the risk of osteoporosis in men. CONCLUSION: Current findings indicate that higher dietary potassium levels have a favorable effect on bone health and preventing osteoporosis in older Korean women.

Study on Mechanical and Thermal Properties of Tio2/Epoxy Resin Nanocomposites

  • Kim, Bu-Ahn;Moon, Chang-Kwon
    • International Journal of Ocean System Engineering
    • /
    • 제3권2호
    • /
    • pp.102-110
    • /
    • 2013
  • The purpose of this study was to improve the properties of epoxy resin using titanium oxide nanoparticles. The effects of particle weight fraction, dispersion agent, and curing agents with different molecular weights on the thermal and mechanical properties of titanium-oxide-reinforced epoxy resin were investigated. In addition, the effect of the particle dispersion condition on the mechanical properties of nanocomposites was studied. As a result, it was found that the glass transition temperature of film-shaped nanocomposites decreased with an in-crease in the nanoparticle content. Because nanoparticles interrupted the cross linkage between the epoxy resin and the amine curing agent, the cross-link density of the epoxy became lower and led to a decrease in $T_g$ in the nanocompo-sites. The tensile strength and modulus in film-shaped nanocomposites also increased with the particles content. But in the case of dog-bone-shaped nanocomposites, the values were not similar to the trend for the film-shaped nanocompo-sites. This was probably a result of the different nanoparticles dispersions in the epoxy resins resulting from the respective-thicknesses of the film and dog-bone-shaped samples.

보강제 변화에 따른 실리콘 고무의 전기 특성 (Electric Properties of Silicone Rubber on Reinforcing Agent Dependence)

  • 이성일
    • 대한안전경영과학회지
    • /
    • 제6권1호
    • /
    • pp.301-309
    • /
    • 2004
  • An inorganic filling agent, ATH (alumina trihydrate) was used to induce inorganic-organic coupling by mixing with stearic acid, acryl silane, vinyl silane as surface treatment agents in order to apply as a high voltage insulating material. Volumetric resistivity was shown to vary with surface treatment agents, and the highest value was obtained in case of the mixture with vinyl silane. The dielectric breakdown intensity was shown to decrease gradually and saturate to a stable value, possibly due to the increase of cross link density in the vinyl radicals introduced to silica surface, resulting in stable dielectric breakdown intensity in the final stages. Tracking and flame retardant properties were also shown to be the best among the samples investigated in this study.

A Study on the Preparation of the Eco-friendly Carbon Fibers-Reinforced Composites

  • Choi, Kyeong-Eun;Seo, Min-Kang
    • Carbon letters
    • /
    • 제14권1호
    • /
    • pp.58-61
    • /
    • 2013
  • In this work, the effect of catalysts on the mechanical properties of carbon fibers-reinforced epoxy matrix composites cured by cationic latent thermal catalysts, i.e., N-benzylpyrazinium hexafluoroantimonate (BPH) was studied. Differential scanning calorimetry was executed for thermal characterization of the epoxy matrix system. Mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and specific fracture energy ($G_{IC}$). As a result, the conversion of neat epoxy matrix cured by BPH was higher than that of one cured by diaminodiphenyl methane (DDM). The ILSS, $K_{IC}$, $G_{IC}$, and impact strength of the composites cured by BPH were also superior to those of the composites cured by DDM. This was probably the consequence of the effect of the substituted benzene group of BPH catalyst, resulting in an increase in the cross-link density and structural stability of the composites studied.