• Title/Summary/Keyword: cross-link density

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Cross-link Density Measurement and Thermal Oxidative Degradation Analysis of a Carbon Black Compounded EPDM Rubber Hose (카본블랙을 충전한 EPDM 고무호스의 가교밀도 측정과 열가속 및 산소 노화거동)

  • Kwak, Seung-Bum;Choi, Nak-Sam;Kim, Jin-Kuk
    • Composites Research
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    • v.22 no.3
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    • pp.35-43
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    • 2009
  • In this study, for a radiator hose made of carbon black filled EPDM(ethylene-propylene diene monomer) rubber, a measuring method of crosslink density was established to analyze the aging behaviors under thermo-oxidative stresses. At $125^{\circ}C$, the crosslink density of the rubber specimens decreased slightly in the initial stage, but increased with increasing the aging time. Such variation in crosslink density was similar to that of tensile strength. This might be due to the formation of sulphoxide crosslinks as well as to additional crosslinks made by the reaction of unvalcunized sulfurs. A high temperature aging of rubber specimens at $180^{\circ}C$ caused a slight increase in crosslink density while it did a large decrease in tensile strength and elongation. With aging at high temperature, the formation of carbonyl groups in EPDM molecule chain and formation of sulphoxide crosslink, rather than the crosslink density variation itself, had a large influence on such changes in mechanical property.

An Overview: Current Control Technique for Propulsion Motor for EV (전기자동차 구동용 모터를 위한 전류 제어 기술)

  • Lee, Hee-Kwang;Nam, Kwang-Hee
    • The Transactions of the Korean Institute of Power Electronics
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    • v.21 no.5
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    • pp.388-395
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    • 2016
  • Electric vehicles (EV) and hybrid EVs (HEV) are designed and manufactured by GM, Toyota, Honda, and Hyundai motors. The propulsion system design process for EV requires integrating subsystem designs into an overall system model to maximize the performance of a given propulsion architecture. Therefore, high-power density and high-torque density are important attributes required for EV applications. To improve torque and power density, propulsion motors are designed for saturation during high-torque operation. The nonlinearity associated with core saturation is modeled by incorporating the cross-coupling inductances, which also behave nonlinearly. Furthermore, in EV environments, the battery is directly connected to the DC link, and the battery changes depending on the state of charge. It will be onerous if as many optimal current commands as different $V_{dc}$ were made. This paper presents the optimal current commands in the various operating condition and the current control technique in EV environments.

An Application of High-Power Ultrasound to Rubber Recycling

  • Hong, Chang-Kook;Isayev, A.I.
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.103-121
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    • 2003
  • The application of powerful ultrasound to rubber recycling is a very recent field of study. An ultrasonic field creates high frequency extension-contraction stresses by acoustic cavitation. The breakdown of rubber network occurs primarily around pulsating cavities due to the highest level of strain produced by high-power ultrasound. Stronger reductions of cross-link density were observed at a higher pressure, indicating an important role of pressure during ultrasonic recycling. Visible bubbles were observed during ultrasonic treatment as a proof of acoustic cavitation. Shearing effect has a significant influence on improving the efficiency of ultrasonic treatment. After the ultrasonic treatment, the cross-link densities of NR/SBR blends were lower than those of NR and SBR due to the reduced degree of unsaturation and chemical reactions. Carbon black fillers increase the probability of bond scission during ultrasonic treatment, due to the restricted mobility. The mechanical properties of ground tire rubber (GRT)/HDPE blends were improved by ultrasonic treatment and dynamic revulcanization. Ultrasonic treatment of GRT in the presence of HDPE matrix was found to give better mechanical properties due to the chemical reactions between rubber and plastic phases.

A Study on Recycling Technology of Waste Tire Powder by Particle Size Distribution Analysis (입도분포해석에 의한 폐타이어 분말의 재활용 연구)

  • Hwang, Sung-Hyuk;Jung, Jae-Hum;Pack, So-Yoon;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.128-138
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    • 2003
  • It goes to be serious with environmental pollution because of great number of waste tires scrapped each you. That is why there are lots of studies for efficient recycle. We tried to reduce particle size of the waste tire powder using a new technology of self-designed grinding machine (SDGM) and ultrasonic treatment. The purpose of this study is to improve the physical properties of reduced waste tire powder. We investigated the fine powder by particle size distribution(PSD) analysis. And also we examined the physical and mechanical properties and cross-link density at various particle sire. Also we carried out morphological studies after making the products by SEM.

Rock physics modeling in sand reservoir through well log analysis, Krishna-Godavari basin, India

  • Singha, Dip Kumar;Chatterjee, Rima
    • Geomechanics and Engineering
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    • v.13 no.1
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    • pp.99-117
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    • 2017
  • Rock physics modeling of sandstone reservoir from gas fields of Krishna-Godavari basin represents the link between reservoir parameters and seismic properties. The rock physics diagnostic models such as contact cement, constant cement and friable sand are chosen to characterize reservoir sands of two wells in this basin. Cementation is affected by the grain sorting and cement coating on the surface of the grain. The models show that the reservoir sands in two wells under examination have varying cementation from 2 to more than 6%. Distinct and separate velocity-porosity and elastic moduli-porosity trends are observed for reservoir zones of two wells. A methodology is adopted for generation of Rock Physics Template (RPT) based on fluid replacement modeling for Raghavapuram Shale and Gollapalli Sandstones of Early Cretaceous. The ratio of P-wave velocity to S-wave velocity (Vp/Vs) and P-impedance template, generated for this above formations is able to detect shale, brine sand and gas sand with varying water saturation and porosity from wells in the Endamuru and Suryaraopeta gas fields having same shallow marine depositional characters. This RPT predicted detection of water and gas sands are matched well with conventional neutron-density cross plot analysis.

Pentacene TFTs and Integrated Circuits with PVP as Gate Insulator

  • Xu, Yong-Xian;Byun, Hyun-Sook;Song, Chung-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1027-1029
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    • 2004
  • In this paper, we have fabricated pentacene thin film transistors (TFTs) using polyvinylphenol (PVP) copolymer and cross-linked PVP as gate insulator on glass and plastic (PET) substrate. Depending on the density of PVP and cross-link material the performance has been changed. We obtained the best device performance with the mobility of 0.32cm2/V${\cdot}$sec and the on/off current ratio of 1.19${\times}$106 for the case of 10wt% PVP copolymer mixed with 5wt% poly (melamine-co-formaldehyde). Additionally using pentacene TFTs with the above PVP gate insulator, we fabricated the integrated circuits including inverter which produced the gain of 9.7.

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The association of potassium intake with bone mineral density and the prevalence of osteoporosis among older Korean adults

  • Ha, Jinwoo;Kim, Seong-Ah;Lim, Kyungjoon;Shin, Sangah
    • Nutrition Research and Practice
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    • v.14 no.1
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    • pp.55-61
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    • 2020
  • BACKGROUND/OBJECTIVES: Osteoporosis is characterized by low bone mass and results in vulnerability to fracture. Calcium and vitamin D are known to play an important role in bone health. Recently, potassium has been identified as another important factor in skeletal health. We examined the link between potassium intake and bone health among the Korean older adult population. SUBJECTS/METHODS: This retrospective, cross-sectional study included 8,732 men and postmenopausal women over 50 years old who completed the Korean National Health and Nutrition Survey (KNHANES) between 2008 and 2011. Potassium consumption was evaluated using a 24-hour recall method. Bone mineral density (BMD) was measured at three sites (total hip, femur neck, and lumbar spine) by dual-energy X-ray absorptiometry (DEXA). Multinomial logistic regression was used to examine the link between potassium intake and prevalence of osteoporosis and osteopenia, after controlling for potential confounding variables. RESULTS: The BMD of the total femur and Ward's triangle were significantly different according to the potassium intake among men (P = 0.031 and P = 0.010, respectively). Women in the top tertile for potassium intake showed higher BMD than those in the bottom tertile at all measurement sites (all P < 0.05). Daily potassium intake was significantly related to a decreased risk of osteoporosis at the lumbar spine in postmenopausal women (odds ratios: 0.68, 95% confidence interval: 0.48-0.96, P trend = 0.031). However, the dietary potassium level was not related to the risk of osteoporosis in men. CONCLUSION: Current findings indicate that higher dietary potassium levels have a favorable effect on bone health and preventing osteoporosis in older Korean women.

Study on Mechanical and Thermal Properties of Tio2/Epoxy Resin Nanocomposites

  • Kim, Bu-Ahn;Moon, Chang-Kwon
    • International Journal of Ocean System Engineering
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    • v.3 no.2
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    • pp.102-110
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    • 2013
  • The purpose of this study was to improve the properties of epoxy resin using titanium oxide nanoparticles. The effects of particle weight fraction, dispersion agent, and curing agents with different molecular weights on the thermal and mechanical properties of titanium-oxide-reinforced epoxy resin were investigated. In addition, the effect of the particle dispersion condition on the mechanical properties of nanocomposites was studied. As a result, it was found that the glass transition temperature of film-shaped nanocomposites decreased with an in-crease in the nanoparticle content. Because nanoparticles interrupted the cross linkage between the epoxy resin and the amine curing agent, the cross-link density of the epoxy became lower and led to a decrease in $T_g$ in the nanocompo-sites. The tensile strength and modulus in film-shaped nanocomposites also increased with the particles content. But in the case of dog-bone-shaped nanocomposites, the values were not similar to the trend for the film-shaped nanocompo-sites. This was probably a result of the different nanoparticles dispersions in the epoxy resins resulting from the respective-thicknesses of the film and dog-bone-shaped samples.

Electric Properties of Silicone Rubber on Reinforcing Agent Dependence (보강제 변화에 따른 실리콘 고무의 전기 특성)

  • 이성일
    • Journal of the Korea Safety Management & Science
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    • v.6 no.1
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    • pp.301-309
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    • 2004
  • An inorganic filling agent, ATH (alumina trihydrate) was used to induce inorganic-organic coupling by mixing with stearic acid, acryl silane, vinyl silane as surface treatment agents in order to apply as a high voltage insulating material. Volumetric resistivity was shown to vary with surface treatment agents, and the highest value was obtained in case of the mixture with vinyl silane. The dielectric breakdown intensity was shown to decrease gradually and saturate to a stable value, possibly due to the increase of cross link density in the vinyl radicals introduced to silica surface, resulting in stable dielectric breakdown intensity in the final stages. Tracking and flame retardant properties were also shown to be the best among the samples investigated in this study.

A Study on the Preparation of the Eco-friendly Carbon Fibers-Reinforced Composites

  • Choi, Kyeong-Eun;Seo, Min-Kang
    • Carbon letters
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    • v.14 no.1
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    • pp.58-61
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    • 2013
  • In this work, the effect of catalysts on the mechanical properties of carbon fibers-reinforced epoxy matrix composites cured by cationic latent thermal catalysts, i.e., N-benzylpyrazinium hexafluoroantimonate (BPH) was studied. Differential scanning calorimetry was executed for thermal characterization of the epoxy matrix system. Mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and specific fracture energy ($G_{IC}$). As a result, the conversion of neat epoxy matrix cured by BPH was higher than that of one cured by diaminodiphenyl methane (DDM). The ILSS, $K_{IC}$, $G_{IC}$, and impact strength of the composites cured by BPH were also superior to those of the composites cured by DDM. This was probably the consequence of the effect of the substituted benzene group of BPH catalyst, resulting in an increase in the cross-link density and structural stability of the composites studied.