• Title/Summary/Keyword: cross linking

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우리 학회 활성화 방안

  • 한만청
    • Journal of Biomedical Engineering Research
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    • v.10 no.2
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    • pp.89-90
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    • 1989
  • To develop an artificial bone substitute that is gradually degraded and replaced by the regenerated natural bone, the authors designed and produced a composite that is consisted of calcium phosphate and collagen. Human umbilical cord origin pepsin treated type I atelocollagen was used as the structural matrix, by which sintered or non-sintered carbonate apatite was encapsulated to form an inorganic-organic composite. With cross linking atelocollagen by UV ray irradiation, the resistance to both compressive and tensile strength was increased. Collagen degradation by the collagenase induced collagenolysis was also decreased.

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Effect of cross-linking agents on the properties of copolyetherester elastomer (코폴리에테르에스테르 고무 탄성체의 물성에 미치는 가교제의 효과)

  • Jang, Young-Joo;Kim, Hae-Young;Baik, Doo-Hyun
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.355-358
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    • 2001
  • Copolyetheresters are us,ed as an engineering thermoplastic elastomer due to their excellent mechanical properties, thermooxidative stability up to high temperatures and a good resistance against many chemicals. However, fibers made from the copolyetheresters exhibited elastic recovery of about 80-85% after being stretched 200%, while spandex fibers usually showed 90-95% recovery. (omitted)

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STUDY PROCESSES OF INTUMESCENCE IN FIRE-PROTECTING COATINGS

  • Efremov, V.L.;Paltseva, N.G.;Leiman, Z.A.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.657-658
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    • 2005
  • Flame retard of polymers was studied for prevention from burning by various additives stimulated the char formation during heating and thermal degradation of polymer materials. Forming char have high porosity, low thermal conductivity and act as thermal shield for heat transmission from the flame to the polymer and. oxygen towards the polymer. The results showed that various additives may regulate the processes of intumecsence. The efficient fire protective intumescent char was result of processes of melting, gas evolution, cross-linking, carbonization etc.

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Formation of PVP- Based Organic Insulating Layers and Fabrication of OTFTs (PVP-기반 유기 절연막 형성과 OTFT 제작)

  • Jang, Ji-Geun;Seo, Dong-Gyoon;Lim, Yong-Gyu
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.302-307
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    • 2006
  • The formation and processing of organic insulators on the device performance have been studied in the fabrication of organic thin film transistors (OTFTs). The series of polyvinyls, poly-4-vinyl phenol(PVP) and polyvinyltoluene (PVT), were used as solutes and propylene glycol monomethyl ether acetate(PGMEA) as a solvent in the formation of organic insulators. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compound. The electrical characteristics measured in the metal-insulator-metal (MIM) structures showed that insulating properties of PVP layers were generally superior to those of PVT layers. Among the layers of PVP series: PVP(10 wt%) copolymer, 5 wt% cross-linked PVP(10 wt%), PVP(20 wt%) copolymer, 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%), the 10 wt% cross-linked PVP(20 wt%) layer showed the lowest leakage current characteristics. Finally, inverted staggered OTFTs using the PVP(20 wt%) copolymer, 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%) as gate insulators were fabricated on the polyether sulphone (PES) substrates. In our experiments, we could obtain the maximum field effect mobility of 0.31 $cm^2/Vs$ in the device from 5 wt% cross-linked PVP(20 wt%) and the highest on/off current ratio of $1.92{\times}10^5$ in the device from 10 wt% cross-linked PVP(20 wt%).

A New Alternative Hole-transporting Layer to PEDOT:PSS for Realizing Highly Efficient All Solution-processable PLEDs

  • Kang, Beom-Goo;Kang, Hong-Kyu;Lee, Kwang-Hee;Lee, Chang-Lyoul;Lee, Jae-Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.362-363
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    • 2012
  • A new cross-linkable polymer, cross-linked d-PBAB, which has the triphenylamine as the hole transporting moiety and ethynyl group as the thermal cross-linker is firstly synthesized by the combination of anionic polymerization and deprotection process. The thermal cross-linking reaction was performed at $240^{\circ}C$ for 50 min and cross-linked d-PBAB layer showed smooth surface and is not soluble at organic solvent under spin-coating of emitting layer (EML). The solution-processed PLED which was fabricated with cross-linked d-PBAB as HTL showed approximately two times higher Lmax and four times higher LEmax than those obtained from PLED with PEDOT:PSS as the HTL. These result is ascribed to better ability of cross-linked d-PBAB to block electrons and to prevent exciton-quenching than those of PEDOT : PSS at the EML interface. This results strongly suggested that cross-linked d-PBAB can be a promising material to replace conventional PEDOT : PSS. It can be suspected that PLEDwith cross-linked d-PBAB would show longer lifetime compared with that of PLED with PEDOT : PSS, and thus further studies are under investigation.

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Immobilization of β-Glucosidase from Exiguobacterium sp. DAU5 on Chitosan Bead for Improved Enzymatic Properties (효소 특성 개선을 위한 Exiguobacterium sp. β-glucosidase의 키토산 비드에 효소 고정화)

  • Chang, Jie;Park, In-Hye;Lee, Yong-Seok;Chung, Soo-Yeol;Fang, Shu Jun;Chandra, M. Subhosh;Choi, Yong-Lark
    • Journal of Life Science
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    • v.20 no.11
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    • pp.1589-1594
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    • 2010
  • Glutaraldehyde was used to cross-link chitosan beads to immobilize the crude enzyme $\beta$-glucosidase from Exiguobacterium sp. DAU5. The conditions for preparing cross-linking chitosan beads and immobilization such as concentration of glutaradehyde, cross-linking time, immobilization pH and time were optimized. The chitosan beads were cross-linked with 1.5% glutaraldehyde for 1.5 hr. The immobilized $\beta$-glucosidase had an overall yield of 20% and specific activity of 5.22 U/g. The optimized pH and temperature were 9.0 and $55^{\circ}C$, respectively. More than 80% of its activity at pH 7.0-10.0, 80% at $40^{\circ}C$ for 2 hr and 48% at $50^{\circ}C$ for 1 hr, were retained. However, the immobilization product showed higher pH and thermal stabilities than free enzymes. It also showed high hydrolyzing activity on soybean isoflavone glycoside linkage. These results suggest the broad application prospects of immobilization enzymes.

Cycling Performance of Li4Ti5O12 Electrodes in Ionic Liquid-Based Gel Polymer Electrolytes

  • Kim, Jin-Hee;Kang, Yong-Ku;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.608-612
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    • 2012
  • We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

A Practice of Reading to Learn Linking the Subject Learning (교과학습과 연계한 학습독서의 실제)

  • Song, Gi-Ho
    • Journal of Korean Library and Information Science Society
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    • v.38 no.1
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    • pp.423-441
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    • 2007
  • Reading abilities are the key for students' problem-solving, self-directed learning and lifelong competency. Reading to learn is usually created through resources-based learning or inquiry-based learning. This study shows a integrated cross-curriculum approach as a alternative method of the reading to learn and it is completed In collaboration with classroom teachers. In this study especially, the model for reading-based information problem solving is introduced as a specific learning strategy of a integrated cross-curriculum and team-teaching.

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Cross-Linked Enzyme Crystal(CLEC);Stability of Horse Liver Alcohol Dehydrogenase CLEC against Electron Transfer Mediators (격자화 효소결정;전자이동 중개체에 대한 알콜 탈수소격자화 효소결정의 안정도)

  • Lee, Kang Min
    • Journal of the Korean Chemical Society
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    • v.45 no.1
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    • pp.61-66
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    • 2001
  • Stabilized Cross-linking Enzyme Crystals(CLEC) can be used as not only biocatalysts but also as enzyme sensors. PMS(Phenylmethyl Sulfate)was shown more efficience than any other electron mediator transfers toward HLADH(Horse Liver Alcohol Dehydrogenase)that were examined. NQS(naphtoquinonesulphonate), phenothiazine and ferrocene aldehyde had respectively just 52%, 37%, 35% electron transfer efficiency as compared to PMS . HLADH-CLEC was very stable toward elctron transfer mediators such as PMS, NQS and ferrocene aldehyde in which HLADH-solution was unstable.

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