• Title/Summary/Keyword: critical region

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Mixed Micellar Properties Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide with Other Surfactants (Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide와 다른 계면활성제와의 혼합미셀화에 관한 연구)

  • Lee, Nam-Min;Lee, Byung-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.602-611
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    • 2014
  • The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.

Estimation on the Wave Transmission and Stability/Function Characteristics of the Submerged Rubble-Mound Breakwater (수중 잠제구조물의 파랑 전달율과 안정성 및 기능성 평가)

  • KIM Yong Woo;YOON Han Sam;RYU Cheong Ro;SOHN Byung Kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.5
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    • pp.528-534
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    • 2003
  • The 2-D hydraulic experimental results for the submerged rubble-mound structure, we have been concerned with the slability/function characteristics of the structures by the effects of wave force, scour/deposition at the toe and the wave transmission ratio at the lee-side sea. So, to investigate the variation characteristics of the wave transmission ratio which depended on a geometrical structure of the submerged breakwater profiles, the critical conditions for the depth of submergence and crest width were obviously presented. In summary, the results lead us to the conclusion that the wave control capabilities of submerged breakwaters by the variation of the submergence depth is higher than about 4 times the degree at the efficiency than the that of crest width. The destruction of the covering block at the crest generated at the region which was located between the maximum and minimum damage curve, and it's maximum damage/failure station from the toe of the structure was $0.2\;L_s.$ As the wave transmission coefficient and the slope of the structure increase, the damage/failure ratio and the maximum scour depth at the toe was extended, respectively. When the maximum scour depth happened, the destruction of the covering block which was located at the toe generated at the front of the submerged rubble-mound breakwater. Finally, it was found from the results that the optimization of the structure may be obtained by the efficient decision of the submergence depth and crest width in the permissible range of the wave transmission ratio.

Requirement of Fur for the Full Induction of dps Expression in Salmonella enterica Serovar Typhimurium

  • Yoo, Ah-Young;Kim, Sam-Woong;Yu, Jong-Earn;Kim, Young-Hee;Cha, Jae-Ho;Oh, Jeong-Il;Eo, Seong-Kug;Lee, John-Hwa;Kang, Ho-Young
    • Journal of Microbiology and Biotechnology
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    • v.17 no.9
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    • pp.1452-1459
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    • 2007
  • The Dps protein, which is overexpressed in harsh environments, is known to playa critical role in the protection of DNA against oxidative stresses. In this study, the roles of Fur in the expression of the dps gene in Salmonella and the protection mechanisms against oxidative stress in Salmonella cells preexposed to iron-stress were investigated. Two putative Fur boxes were predicted within the promoter region of the S. typhimurium dps gene. The profile of dps expression performed by the LacZ reporter assay revealed growth-phase dependency regardless of iron-status under the culture conditions. The fur mutant, $_X4659$, evidenced a reduced level of ${\beta}$-galactosidase as compared to the wild-type strain. The results observed after the measurement of the Dps protein in various Salmonella regulatory mutants were consistent with the results acquired in the reporter assay. This evidence suggested that Fur performs a function as a subsidiary regulator in the expression of dps. The survival ability of Salmonella strains after exposure to oxidative stress demonstrated that the Dps protein performs a pivotal function in the survival of stationary-phase S. typhimurium against oxidative stress. Salmonella cells grown in iron-restricted condition required Dps for full protection against oxidative stress. The CK24 (${\Delta}dps$) cells grown in iron-replete condition survived at a rate similar to that observed in the wild-type strain, thereby suggesting the induction of an unknown protection mechanism(s) other than Dps in this condition.

Rheological Measurement of Fiber Spinnability of PVA Solution Dopes in DMSO

  • Chae, Dong-Wook
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.187-193
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    • 2010
  • The effects of molecular weight (MW) and concentration on the rheological properties of poly(vinyl alcohol) (PVA) solutions in dimethyl sulfoxide (DMSO) were investigated at $30^{\circ}C$. Ubbelohde viscometer and rotational rheometer were employed for dilute and concentrated regime, respectively. In the dilute regime, the Mark-Houwink exponent ($\alpha$) of the solutions determined from three different MWs proved 0.73. The critical concentration (C*), in which the entanglement and overlap of polymer molecules began to take place, decreased with increasing the MW of PVA. Huggins constant ($K_H$) values ranged from 0.33 to 0.45 over the MW examined. In the log-log plot of $\eta_{sp}$ versus [$\eta$]C, the PVA with higher degree of polymerization (DP) gave a greater slope exhibiting the inflection point in the vicinity of C*. In the dynamic viscosity ($\eta'$) curve, the PVA solutions of DP 1700 presented Newtonian fluid behavior over most of the frequency range examined. However, the lower Newtonian flow region reduced with increasing the DP. As the PVA concentration increased, $\eta'$ was increased and the onset shear rate for pseudoplasticity was decreased. In the Cole-Cole plot, PVA solutions showed almost a single master curve in a slope of ca. 1.65 regardless of the DP. However, the increase of the concentration from 8 to 12 wt% for PVA solutions of DP 5000 decreased the slope from 1.73 to 1.57. In the tan $\delta$ curve, the onset frequency for sol-gel transition was shifted from 154 to 92 rad/s with increasing the DP from 3300 to 5000 and from 192 to 46 rad/s with increasing the concentration from 8 to 12 wt%. In addition, longer relaxation time ($\lambda$) was observed with increasing the DP and concentration.

Investigation of Frozen Rock Failure using Thermal Infrared Image (열적외선영상을 이용한 동결된 암석의 파괴특성 연구)

  • Park, Jihwan;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.25 no.2
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    • pp.144-154
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    • 2015
  • Mechanical energy is accumulated in the object when stress is exerted on rock specimens, and the failure is occurred when the stress is larger than critical stress. The accumulated energy is emitted as various forms including physical deformation, light, heat and sound. Uniaxial compression strength test and point load strength test were carried out in low temperature environment, and thermal variation of rock specimens were observed and analyzed quantitatively using thermal infrared camera images. Temperature of failure plane was increased just before the failure because of concentration of stress, and was rapidly increased at the moment of the failure because of the emission of thermal energy. The variations of temperature were larger in diorite and basalt specimens which were strong and fresh than in tuff specimens which were weak and weathered. This study can be applied to prevent disasters in rock slope, tunnel and mine in cold regions and to analyze satellite image for predicting earthquake in cold regions.

A Study on the Stability Evaluation and Numerical Simulation of Toppling Failure on a Cut-Slope (절토사면의 전도파괴에 대한 안정성 평가 및 수치해석적 고찰)

  • Choi, Ji-Yong;Kim, Seung-Hyun;Koo, Ho-Bon
    • The Journal of Engineering Geology
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    • v.20 no.1
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    • pp.13-23
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    • 2010
  • Toppling failure of a slope is defined as failure behavior accompanying the rotation of rock block which is different from other failure such as sliding along with discontinuities and so on. It generally occurs in the region that discontinuities were developed with inverse dip direction to a slope and it could play a critical role in judging stability of slope. In this study, the stability evaluation was performed about toppling failure on a jointed road cut-slope. To check the deformation behavior, numerical analysis is widely used. However common analysis programs are based on continuum model. Recently, many methods that discontinuity properties can be considered in continuum analysis are suggested. In this study, numerical analysis based on FEM(Finite Element Method) was performed using interface element applied in heterogeneous boundary to simulate effects of discontinuities.

Morphologic and Genetic Identification of Diphyllobothrium nihonkaiense in Korea

  • Jeon, Hyeong-Kyu;Kim, Kyu-Heon;Huh, Sun;Chai, Jong-Yil;Min, Duk-Young;Rim, Han-Jong;Eom, Kee-Seon S.
    • Parasites, Hosts and Diseases
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    • v.47 no.4
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    • pp.369-375
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    • 2009
  • Diphyllobothrium nihonkaiense was first described by Yamane in 1986 but the taxonomical features have been obscure due to lack of critical morphologic criteria in its larval and adult stages. In Korea, this tapeworm had long been known as Diphyllobothrium latum. In this study, we observed 62 specimens collected from Korean residents and analyzed them by morphological features and nucleotide sequences of mitochondrial cox1 gene as well as the ITS1 region. Adult tapeworms were examined after carmine or trichrome stain. Longitudinal sections of the gravid proglottids showed an obtuse angle of about 150 degree between the cirrus sac and seminal vesicle. This angle is known as a major differential point compared with that of D. latum. Nucleotide sequence differences between D. latum and the specimens from Koreans represented 17.3% in mitochondrial DNA cox1 gene. Sequence divergence of ITS1 among 4 Korean isolates was 0.3% and similarity was 99.7% with D. nihonkaiense and D. klebanovskii. All of the Korean specimens analyzed in this study were identified as being D. nihonkaiense (n = 62). We propose its Korean name as "Dong-hae-gin-chon-chung" which means 'long tapeworm of the East Sea' for this newly analyzed diphyllobothriid tapeworm in Korea.

Correlation between terahertz characteristics and defect states in LTG-InGaAs

  • Park, Dong-U;Kim, Jun-O;Lee, Sang-Jun;Kim, Chang-Su;Lee, Dae-Su;No, Sam-Gyu;Gang, Cheol;Gi, Cheol-Sik;Kim, Jin-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.243-243
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    • 2010
  • Low-temperature grown (LTG) InGaAs epilayers were grown by MBE technique for studying a correlation between terahertz (THz) emission and the intrinsic defects. The 1.2-um-thick Be-compensated LTG-InGaAs epilayers were prepared on SI-InP:Fe substrate at $200-250^{\circ}C$, and subsequently in-situ annealed under As environment at $550^{\circ}C$ for 5-30 minutes. The carrier concentration/mobility and the crystalline structure were analyzed by the Hall effect and the x-ray diffraction (XRD), respectively, and the carrier lifetime were determined by the fs time-resolved pump-probe spectroscopy. THz generation from LTG-InGaAs was carried out by a Ti-sapphire laser (800 nm) of a pulse width of 190 fs at a repetition of 76 MHz. Figure shows the spectral amplitude of generated waves in the THz region. As the growth temperature of epilayer increases, the amplitude is enhanced. However, two samples grown at $200^{\circ}C$, as-grown and annealed, show almost no difference in the spectral amplitude. This suggests that the growth temperature is critical in the formation of defect states involved in THz emission. We are now investigating the correlations between the XRD band attributed to defects, the Hall parameter, and the spectral amplitude of generated THz wave.

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Influences of boron and silicon in insert alloys on microstructure and isothermal solidification during TLP bonding of a duplex stainless steel using MBF-35 and MBF-30

  • Yuan, Xinjian;Kim, Myung-Bok;Kang, Chung-Yun
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.59-59
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    • 2009
  • The influences of B and Si in the filler metals on microstructure and isothermal solidification during transient liquid-phase (TLP) bonding of a nitrogen-containing duplex stainless steel with MBF-30 (Ni-4.5wt.%Si-3.2wt.%B) and MBF-35 (Ni-7.3wt.%Si-2.2wt.%B), were studied at the temperature range of $1030-1090^{\circ}C$ with various times from 60 s to 3600 s under a vacuum of approximately $10^{-5}$ Torr. In case of the former, BN, $Ni_3B$ and $Ni_3Si$ precipitates were formed in the bonding region. BN and $Ni_3Si$ secondary phases were present in the joint for the latter case. The formation of $Ni_3B$ within the joint centerline is dependent on B content. The morphology of $Ni_3Si$ is dominated by Si concentration. A difference between the times for complete isothermal solidification obtained by the experiments and the conventional TLP bonding diffusion model was observed when using MBF-35. According to the simulated results, the isothermal solidification completion time for MBF-35 case was smaller than that in MBF-30. However, this experimental value obtained using MBF-35 was notably larger than that obtained using MBF-30. Isothermal solidification of liquid MBF-30 is controlled by the first isothermal solidification regime dependent on B diffusion model, whereas that of liquid MBF-35 experiences two isothermal solidification regimes and is mainly controlled by the second isothermal solidification dependent on Si diffusion model. In addition, only if Si content exceeds a critical value, the slower 2nd solidification regime will commence.

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Determination of Strategic Business Units in the Health Promotion Service Adreas of Health Center (보건소 건강증진사업에서의 전략적 사업영역 결정)

  • 이선희;조희숙;박혜숙;박영숙;김한중;손명세;이지전;이상욱
    • Health Policy and Management
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    • v.8 no.2
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    • pp.110-124
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    • 1998
  • Determining of Strategic Business Units in the organization is a major critical process for improving the organizational performance. On increasing the demands for extension in function of health center, many health centers are trying to provide the various services. But most health center determined the kind and level of service without scientific considerations. The purposes of this study are to develope the model for determination of strategic business units in health center and to test the availability of implementation for it. Our model is rooted from the McKinsey matrix analysis of Product Portfolio Analysis which used widely in marketing field. We modified the evaluation criteria of the McKinsey matrix analysis for health care field appropriately. Our evaluation criteria are categorized into two concepts; contribution of service, availability of service. At first, in terms of contribution of service, market size, market growth rate, needs and demands of regional people, existences of alternative services in that region, correspondence with health policy. The other component, availability of service are included the availability of manpower, financial availability, the level of knowhow on service, acceptance of health care manpower. In the result of analysis, we could conclude that antismoking and antialcoholics education programs, health screening program are important strategically in that aspects of contributions and availability of services. Also, vaccination program is important in that aspect of service availability and diet and exercise program, health library are meaningful in the aspect of service contribution. Therefore, we think that efforts to investigate the evaluation criteria for priority setting or determination of service area in health center are useful challenges.

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