• Title/Summary/Keyword: critical region

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Determination of Similar Exposure Groups Using Weekday Time Activity Patterns of Urban Populations (평일 시간활동패턴을 활용한 도시 인구의 유사노출집단 분류)

  • Hwang, Yunhyung;Lee, Kiyoung;Yoon, Chung-Sik;Yang, Wonho;Yu, Seungdo;Kim, Guenbae
    • Journal of Environmental Health Sciences
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    • v.42 no.6
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    • pp.353-364
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    • 2016
  • Objectives: Determining the time activity patterns of urban populations is critical when performing an exposure assessment. The purposes of this study were to classify urban populations in Korea by their time activity patterns and to identify factors that influence these patterns. Methods: The time activity patterns of 31,634 and 20,263 individuals were obtained from two national databases collected in 2004 and 2009, respectively. The two largest metropolitan cities in Korea, Seoul and Busan, were selected for this analysis. For each city, multivariate linear regressions were performed to determine factors affecting the time spent in a residence and in transit. We also used cluster analysis to classify each urban population by activity pattern. Results: Nine distinctive activity patterns were identified in the Seoul and Busan populations, respectively, and the resulting classified population groups had specific characteristics. The identified patterns were similar for Seoul and Busan. The most significant factors affecting time spent in a residence were employment status, age, marriage status, education, and gender. Gender, education, employment status, and monthly income were significant factors affecting time spent in transit. Conclusion: These results indicate that, in addition to region, exposure scientists in Korea should consider classifying populations based on age, gender, and occupation.

Study on the Solubilization of Phenoxide Anion by Mixed Surfactant Systems of CTAB and TTAB (CTAB/TTAB 혼합계면활성제에 의한 Phenoxide 음이온의 가용화에 대한 연구)

  • Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.44 no.3
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    • pp.177-183
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    • 2000
  • The interaction of phenoxide anion with .the mixed micelles of CTAB(Cetyl-trimethylammonium bromide) and TTAB(Tetradecyltrimethylammonium bromide) was studied by UV/Vis spectrophotometric method. The solubilization constants($K_s$) of phenoxide anion into the mixed micellar phase and the critical micellar concentrations(CMC) of those mixed surfactant systems have been measured and analyzed with the change of overall mole fraction of CTAB($\alpha_{CTAB}$) The effects of additives(n-pentanol and NaBr) on the solubilization of phenoxide anion by those mixed surfactant systems have been also measured. There was a great decrease on the values of solubilization constant and CMC with these additives. For the thermodynamic study, the dependence of $K_s$ values on temperature has been measured and various thermodynamic parameters(${\Delta}G^0_s$, ${\Delta}H^0_s$ and ${\Delta}S^0_s$) have been also calculated. The results show that all the values of ${\Delta}G^0_s$ and ${\Delta}H^0_s$ are negative within the measured temperature region but the values of ${\Delta}S^0_s$ are positive.

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Influence of Ag nano-powder additions on the superconducting properties of Mg $B_2$ materials

  • K. J. Song;Park, S. J.;Kim, S. W.;Park, C.;J. H. Joo;Kim, H. J.;J. K. Chung;R. K. Ko;H. S. Ha
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.3
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    • pp.6-10
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    • 2003
  • Silver nano-powder was added to Ma $B_2$ to make (Ag)$_{(x)wt.%}$(Mg $B_2$)$_{(l00-x)wt.%}$ (A $g_{x}$-Mg $B_2$) (10 $\leq$ x $\leq$ 50) composite superconductors to investigate the effect of the Ag nano-powder on the vortex pinning. Pellets made out of the mixed powder were put inside stainless steel tubes, which were sintered at 85$0^{\circ}C$ in Ar atmosphere. No impurity phase was identified for as-rolled samples. However, both the Mg $B_2$ and the A $g_{x}$-Mg $B_2$ composite pellets, when sintered, contain small amount of Mg $B_4$ and MgAg impurity phases. From the magnetization study, it was found that the flux pinning was improved in the high magnetic field region (> 3 T) only when 10w/o Ag was added to Mg $B_2$. The "two step" structures in ZFC M(T) curve gradually increased as the amount of Ag added increased. Pinning centers can be created by adding a suitable amount of Ag nano-powder which is not too large to increase the decoupling between the Mg $B_2$ grains.crease the decoupling between the Mg $B_2$ grains.

Properties of Malonyl-CoA Decarboxylase from Rhizobium trifolii

  • An, Jae-Hyung;Lee, Gha-Young;Song, Jong-Hee;Lee, Dai-Woon;Kim, Yu-Sam
    • BMB Reports
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    • v.32 no.4
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    • pp.414-418
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    • 1999
  • A novel gene for malonyl-CoA decarboxylase was discovered in the mat operon, which encodes a set of genes involved in the malonate metabolism of Rhizobium trifolii (An and Kim, 1998). The subunit mass determined by SDS-PAGE was 53 kDa, which correspond to the deduced mass from the sequence data. The molecular mass of the native enzyme determined by field flow fractionation was 208 kDa, indicating that R. trifolii malonyl-CoA decarboxylase is homotetrameric. R. trifolii malonyl-CoA decarboxylase converted malonyl-CoA to acetyl-CoA with a specific activity of 100 unit/mg protein. Methylmalonyl-CoA was decarboxylated with a specific activity of 0.1 unit/mg protein. p-Chloromercuribenzoate inhibited this enzyme activity, suggesting that thiol group(s) is(are) essential for this enzyme catalysis. Database analysis showed that malonyl-CoA decarboxylase from R. trifolii shared 32.7% and 28.1% identity in amino acid sequence with those from goose and human, respectively, and it would be located in the cytoplasm. However, there is no sequence homology between this enzyme and that from Saccharopolyspora erythreus, suggesting that malonyl-CoA decarboxylases from human, goose, and R. trifolii are in the same class, whereas that from S. erythreus is in a different class or even a different enzyme, methylmalonyl-CoA decarboxylase. According to the homology analysis, Cys-214 among three cysteine residues in the enzyme was found in the homologous region, suggesting that the cysteine was located at or near the active site and plays a critical role in catalysis.

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Nondestructive Microfailure and Interfacial Evaluation of Plasma-Treated PBO and Kevlar Fibers/Epoxy Composites using Micromechanical Test and Acoustic Emission (Micromechanical 시험법과 음향방출을 이용한 플라즈마 처리된 PBO와 Kevlar 섬유강화 Epoxy 복합재료의 비파괴적 파단특성 및 계면물성 평가)

  • 박종만;김대식;김성룡
    • Composites Research
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    • v.16 no.4
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    • pp.74-79
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    • 2003
  • Comparison of interfacial properties and microfailure mechanisms of oxygen-plasma treated poly(p-phenylene-2,6-benzobisoxazole(PBO. Zylon) and poly(p-phenylene terephthalamide)(PPTA, Kevlar) fibers/ epoxy composites were investigated using micromechanical technique and nondestructive acoustic emission(AE). Interfacial shear strength(IFSS) and work of adhesion, Wa of PBO or Kevlar fibers/epoxy composites increased by oxygen-plasma treatment. Plasma-treated Kevlar fiber shooed the maximum critical surface tension and polar term, whereas the untreated PBO fiber showed the minimum value. Microfibril fracture pattern of plasma-treated Kevlar fiber appeared obviously. Based on the propagation of microfibril failure toward core region. the number of AE events for plasma-treated PBO and Kevlar fibers increased significantly. The results oi nondestructive AE were consistent well with microfailure modes by optical observation in microdroplet and two-fiber composites tests.

An Experimental Study on Heat Transfer and Pressure Drop Characteristics of Carbon Dioxide During Gas Cooling Process in a Hellically Coiled Tube

  • Oh, Hoo-Kyu;Son, Chang-Hyo;Yu, Tae-Geun;Kim, Dae-Hui
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.3
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    • pp.263-271
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    • 2007
  • The heat transfer coefficient and pressure drop during 9as cooling process of $CO_2$ (R744) in a helically coiled copper tube with the inner diameter of 4.55 mm and outer diameter of 6.35 mm were investigated experimentally. The main components of the refrigerant loop are a receiver, a variable-speed pump. a mass flow meter a pre-heater and a helically coiled type gas cooler (test section). The refrigerant mass fluxes are varied from 200 to $800kg/m^2s$ and the inlet pressures of gas cooler are 7.5 to 10.0 MPa. The heat transfer coefficients of $CO_2$ in a helically coiled tube are higher than those in a horizontal tube. The Pressure drop of $CO_2$ in the gas cooler shows a relatively good agreement with those predicted by Ito's correlation developed for single-phase in a helically coiled tube. The local heat transfer coefficient of $CO_2$ agrees well with the correlation by Pitla et al. However. at the region near pseudo-critical temperature. the experiments indicate higher values than the Pitla et al correlation. Therefore, various experiments in helically coiled tubes have to be conducted and it is necessary to develop the reliable and accurate prediction determining the heat transfer and pressure drop of $CO_2$ in a helically coiled tube.

Grid Based Nonpoint Source Pollution Load Modelling

  • Niaraki, Abolghasem Sadeghi;Park, Jae-Min;Kim, Kye-Hyun;Lee, Chul-Yong
    • 한국공간정보시스템학회:학술대회논문집
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    • 2007.06a
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    • pp.246-251
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    • 2007
  • The purpose of this study is to develop a grid based model for calculating the critical nonpoint source (NPS) pollution load (BOD, TN, TP) in Nak-dong area in South Korea. In the last two decades, NPS pollution has become a topic for research that resulted in the development of numerous modeling techniques. Watershed researchers need to be able to emphasis on the characterization of water quality, including NPS pollution loads estimates. Geographic Information System (GIS) has been designed for the assessment of NPS pollution in a watershed. It uses different data such as DEM, precipitation, stream network, discharge, and land use data sets and utilizes a grid representation of a watershed for the approximation of average annual pollution loads and concentrations. The difficulty in traditional NPS modeling is the problem of identifying sources and quantifying the loads. This research is intended to investigate the correlation of NPS pollution concentrations with land uses in a watershed by calculating Expected Mean Concentrations (EMC). This work was accomplished using a grid based modelling technique that encompasses three stages. The first step includes estimating runoff grid by means of the precipitation grid and runoff coefficient. The second step is deriving the gird based model for calculating NPS pollution loads. The last step is validating the gird based model with traditional pollution loads calculation by applying statistical t-test method. The results on real data, illustrate the merits of the grid based modelling approach. Therefore, this model investigates a method of estimating and simulating point loads along with the spatially distributed NPS pollution loads. The pollutant concentration from local runoff is supposed to be directly related to land use in the region and is not considered to vary from event to event or within areas of similar land uses. By consideration of this point, it is anticipated that a single mean estimated pollutant concentration is assigned to all land uses rather than taking into account unique concentrations for different soil types, crops, and so on.

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UBET Analysis of Combined Forging of Non-Axisymmetric Shapes With Inclined Protrusion (경사진 돌출부가 있는 비축대칭 복합단조의 상계요소해석)

  • 윤정호;양동열
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.1-12
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    • 1990
  • The study is concerned with the analysis of combined forging of non-axisymmetric shapes with inclined protrusions by UBET technique. Work hardening is considered for the given range of strain rate during the forging process. A complex shape with inclined cavities is analyzed by subdividing the workpiece into finite UBET elements for which simple velocity fields are applicable. An experimental set-up was designed and manufactured for the experiment, and experiments are carried out with lead billets. The devised set-up can be used for closed-die forging of complex shapes with protrusions in which the dies can be separated automatically for easy removal of the forged products. Based on the derived kinematically admissible velocity fields for corresponding UBET elements, general computer programs have been developed. Since the energy dissipation rate for each elemental region is provided by subprograms (Subroutine or Function), the developed program can be applied to the forging problems of various shapes. The present study has shown that the method developed can be effectively applied to forging of non-axisymmetric shapes with complicated protrusions.

A Hydrological Analysis of Current Status of Turbid Water in Soyang River and Its Mitigation (소양강 탁수 현황과 저감에 대한 수리학적 분석)

  • Lee, Jin-Yong
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.85-92
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    • 2008
  • Water in Soyang River is an essential source for citizens of Chuncheon and Seoul areas. In 2006, turbid water in Soyang River aggravated by the typhoon Ewiniar, sustained for over 280 days unlike conventional years, then which interrupted water supply of Chuncheon and Seoul areas. Soil erosion derived from high cool lands constituting about 55% of Soyang River area is considered one of main causes for the turbid water, including imprudent development of mountainous area, road expansion, and road construction for forestry. According to analysis of turbidity, precipitation and reservoir level in Soyang River region for June 2006${\sim}$August 2008, the turbidity showed a peak correlation (r = 0.28) at a lag time of 49 days and especially did an excellent correlation (r = 0.60) with the reservoir level at a lag of 4 days. In the meantime, a critical turbidity of 31 NTU at Soyanggang Dam was estimated, over which would cause turbid water at Paldang Dam. In addition, a master recession curve was suggested, from which sustaining time of turbid water can be predicted.

Importance of Leu-5 and Pro-6 in the Inhibitory Activity of the Serratia marcescens Metalloprotease Inhibitor (SmaPI)

  • Bae, Kwang-Hee;Kim, Dong-Min;Kim, Sun-Taek;Kim, Tae-Hoon;Shin, Yong-Chul;Byun, Si-Myung
    • BMB Reports
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    • v.34 no.2
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    • pp.109-113
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    • 2001
  • The Serratia marcescens metalloprotease inhibitor (SmaPI) is a proteinase inhibitor toward Serratia marcescens metalloprotease (SMP). The three-dimensional structure of SmaPI was calculated by computer modeling using the structure complex between SMP and the Erwinia chrysanthemi inhibitor as a template. Based on this model structure, the substitution of the amino acid residues, Ala4, Leu-5, Pro-6, and Thr-7, were located at the hinge region of the N-terminal segment by site-directed mutagenesis. Although the A4R and T7A mutant SmaPIs showed a nearly full inhibitory activity, the inhibitory activity of SmaPI decreased significantly when the Leu-5 was converted to Ala, Gly, Ile, or Val. Surprisingly, the L5I and L5V mutant SmaPIs showed less inhibitory activities than the L5A mutant. From these results, we suggested that the orientations and positions of respective aliphatic groups in the side-chain of position 5 mainly affected the inhibitory activity of SmaPI. The overall side-chain hydrophobicity was only slightly affected. The side-chain of the Leu-5 residue contributed approximately 0.79 kcal/mol out of 8.44 kcal/mol to the binding of SmaPI with SMP The inhibitory activities of P6A and F6G were also severely decreased. The Pro-6 may have a critical role in maintaining the strict conformation of the N-terminal portion that may be important in the inhibitory activity of SmaPI. In conclusion, Leu-5 and Pro-6 have crucial roles in the inhibitory function of SmaPI toward SMP.

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