• Title/Summary/Keyword: critical corrosion

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Surface Preparation and Activation Only by Abrasion and Its Effect on Adhesion Strength

  • Ali Gursel;Salih Yildiz
    • Journal of Adhesion and Interface
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    • v.23 no.4
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    • pp.101-107
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    • 2022
  • Adhesive joints have many advantages such as weight savings, corrosion and fatigue resistance and now developed even withstand of high impact and dynamic loads. However, an adhesion has cumbersome and complicated surface preparation processes. The surface preparation step is critical in adhesive joint manufacturing in order to obtain the prescribed strength for adhesive joints. In this study, it was attempted to simplify and reduce the number of surface preparation steps, and abrasion and rapid adhesive application (ARAA) process is developed for an alternative solution. The abrasion processes are performed only for creating surface roughness in standard procedures (SP), although the abrasion processes cause surface activation itself. The results showed that there is no need the long procedures in laboratory or chemical agents for adhesion. After the abrasion process, the attracted and highly reactive fresh surface layer obtained, and its effect on bonding success is observed and analyzed in this research, in light of the essential physic and adhesion theories. Al 6061 aluminum adherends and epoxy-based adhesives were chosen for bonding processes, which is mostly used in light vehicle parts. The adherends were cleaned, treated and activated only with abrasion, and after the adhesive application the specimens were tested under quasi-static loading. The satisfied ARAA results were compared with that of the specimens fabricated by the standard procedure (SP) of adhesion processes of high impact loads.

Seismic behavior of thin-walled CFST pier-to-base connections with tube confined RC encasement

  • Xuanding Wang;Yue Liao;Jiepeng Liu;Ligui Yang;Xuhong Zhou
    • Steel and Composite Structures
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    • v.50 no.2
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    • pp.217-235
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    • 2024
  • Concrete-filled steel tubes (CFSTs) nowadays are widely used as the main parts of momentous structures, and its connection has gained increasing attention as the complexity in configuration and load transfer mechanism. This paper proposes a novel CFST pier-to-footing incorporating tube-confined RC encasement. Such an innovative approach offers several benefits, including expedited on-site assembly, effective confinement, and collision resistance and corrosion resistance. The seismic behavior of such CFST pier-to-footing connection was studied by testing eight specimens under quasi-static cyclic lateral load. In the experimental research, the influences on the seismic behavior and the order of plastic hinge formation were discussed in detail by changing the footing height, axial compression ratio, number and length of anchored bars, and type of confining tube. All the specimens showed sufficient ductility and energy dissipation, without significant strength degradation. There is no obvious failure in the confined footing, while local buckling can be found in the critical section of the pier. It suggests that the footing provides satisfactory strength protection for the connection.

A Study on the Oxidation Behaviors of Power Plant Valve Materials under the Ultra Super Critical Condition (초초 임계 화력 발전소용 밸브 소재의 산화 거동)

  • Lee, J.S.;Cho, T.Y.;Yoon, J.H.;Joo, Y.G.;Song, K.O.;Cho, J.Y.;Kang, J.H.;Lee, S.H.;Uhm, K.W.;Lee, J.W.
    • Journal of the Korean institute of surface engineering
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    • v.42 no.1
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    • pp.26-33
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    • 2009
  • Recently ultra-supercritical steam power plants operate at $1000^{\circ}F$ ($538^{\circ}C$) and 3500 psi (24.1 MPa). Thermal efficiency of power plant will be increased about 2% if steam temperature increases from $1000^{\circ}F$ to $1150^{\circ}F$ ($621^{\circ}C$). In this study valve materials Incoloy901 (IC901) and Inconel718 (IN718) were nitrided to improve the surface hardness and solid lubrication function of the valve materials. The hardness of both IC901 and IN718 increased about two times by ion nitriding. IC901, IN718 and their nitrided specimens were corroded under ultra super-critical condition (USC) of $621^{\circ}C$. and 3600 psi (24.8 MPa) for 2000 hours. Oxidations of both IC901 and IN718 were very small due to the formation of protective oxide layer on the surface. But the corrosion resistance of both nitrided specimens decreased because of the formation of non-protective nitride layer of $Fe_{4}N$, $Fe_{2}N$ and CrN on the surface layer. The hardness of both nitrided IC901 and IN718 at $20{\mu}m$ depth from the surface decreased about 30% and 20% respectively by USC 2000 hours.

Strength Properties and Elastic Waves Characteristics of Silicon Carbide with Damage-Healing Ability (손상치유 능력을 가지는 탄화규소의 강도 특성과 탄성파 특성)

  • KIM MI-KYUNG;AHN BYUNG-GUN;KIM JIN-WOOK;PARK IN-DUCK;AHN SEOK-HWAN;NAM KI-Woo
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.337-341
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    • 2004
  • Engineering ceramics have superior heat resistance, corrosion resistance, and wear resistance. Consequently, these art significant candidates for hot-section structural components of heat engine and the inner containment of nuclear fusion reactor. Besides, some of them have the ability to heal cracks and great benefit can be anticipated with great benefit the structural engineering field. Especially, law fracture toughness of ceramics supplement with self-healing ability. In the present study, we have been noticed some practically important points for the healing behavior of silicon nitride, alumina, mullite with SiC particle and whisker. The presence of silicon carbide (SiC) in ceramic compound is very important for crack-healing behavior. However, self-healing of SiC has not been investigated well in detail yet. In this study, commercial SiC was selected as sample, which can be anticipated in the excellent crack healing ability. The specimens were produced three-point bending specimen with a critical semi-circular crack of which size that is about $50-700{\mu}m$. Three-point bending test and static fatigue test were performed cracked and healed SiC specimens. A monotonic bending load was applied to cracked specimens by three-point loading at different temperature. The purpose of this paper is to report Strength Properties and Elastic Waves Characteristics of Silicon Carbide with Crack Healing Ability.

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Numerical technique for chloride ingress with cover concrete property and time effect

  • Lee, Bang Yeon;Ismail, Mohamed A.;Kim, Hyeok-Jung;Yoo, Sung-Won;Kwon, Seung-Jun
    • Computers and Concrete
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    • v.20 no.2
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    • pp.185-196
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    • 2017
  • Durability problems initiated from steel corrosion are unseen but critical issues, so that many researches are focused on chloride penetration evaluation. Even if RC (Reinforced Concrete) structures are exposed to normal environment, chloride ingress varies with concrete surface conditions and exposed period. This paper presents an analysis technique for chloride behavior evaluation considering time effect on diffusion and surface conditions assumed as double-layered system. For evaluation of deteriorated surface condition, field investigation was performed for concrete pavement exposed to deicing agent for 18 years. In order to consider enhanced surface concrete, chloride profiles in surface-impregnated concretes exposed to chloride attack for 2 years from previous research were investigated. Through reverse analysis, effectively deteriorated/enhanced depth of surface and the related reduced/enlarged diffusion coefficient in the depth are simulated. The proposed analysis technique was evaluated to handle the chloride behavior more accurately considering changes of chloride ingress within surface layer and decreased diffusion coefficient with time. For the concrete surface exposed to deicing agent, the deteriorated depth and enlarged diffusion coefficient are evaluated to be 12.5~15.0 mm and 200% increasing diffusion coefficient, respectively. The results in concrete containing enhanced cover show 10.0~12.5 mm of impregnated depth and 85% reduction of chloride diffusion in tidal and submerged conditions.

Reliability analysis of proposed capacity equation for predicting the behavior of steel-tube concrete columns confined with CFRP sheets

  • Raza, Ali;Khan, Qaiser uz Zaman;Ahmad, Afaq
    • Computers and Concrete
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    • v.25 no.5
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    • pp.383-400
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    • 2020
  • Due to higher stiffness to weight, higher corrosion resistance, higher strength to weight ratios and good durability, concrete composite structures provide many advantages as compared with conventional materials. Thus, they have wide applications in the field of concrete construction. This research focuses on the structural behavior of steel-tube CFRP confined concrete (STCCC) columns under axial concentric loading. A nonlinear finite element analysis (NLFEA) model of STCCC columns was simulated using ABAQUS which was then, calibrated for different material and geometric models of concrete, steel tube and CFRP material using the experimental results from the literature. The comparative study of the NLFEA predictions and the experimental results indicated that the proposed constitutive NLFEA model can accurately predict the structural performance of STCCC columns. After the calibration of NLFEA model, an extensive parametric study was performed to examine the effects of different critical parameters of composite columns such as; (i) unconfined concrete strength, (ii) number of CFRP layers, (iii) thickness of steel tube and (iv) concrete core diameter, on the axial load capacity. Furthermore, a large database of axial strength of 700 confined concrete compression members was developed from the previous researches to give an analytical model that predicts the ultimate axial strength of composite columns accurately. The comparison of the predictions of the proposed analytical model was done with the predictions of 216 NLFEA models from the parametric study. A close agreement was represented by the predictions of the proposed constitutive NLFEA model and the analytical model.

Alloy Design and Properties of Ni based Superalloy LESS 1: I. Alloy Design and Phase Stability at High Temperature (Ni기 초내열 합금 LESS 1의 합금설계 및 평가: I. 합금 설계 및 고온 상 안정성 평가)

  • Youn, Jeong Il;Kang, Byung Il;Choi, Bong Jae;Kim, Young Jig
    • Journal of Korea Foundry Society
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    • v.33 no.5
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    • pp.215-225
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    • 2013
  • The alloys required for fossil power plants are altered from stainless steel that has been used below $600^{\circ}C$ to Ni-based alloys that can operate at $700^{\circ}C$ for Hyper Super Critical (HSC) steam turbine. The IN740 alloy (Special Metals Co. USA) is proposed for improved rupture strength and corrosion resistance at high temperature. However, previous studies with experiments and simulations on stable phases at about $700^{\circ}C$ indicated the formation of the eta phase with the wasting of a gamma prime phase, which is the most important reinforced phase in precipitation hardened Ni alloys, and this resulted in the formation of precipitation free zones to decrease the strength. On the basis of thermodynamic calculation, the new Ni-based superalloy named LESS 1 (Low Eta Sigma Superalloy) was designed in this study to improve the strengthening effect and structure stability by depressing the formation of topologically close packed phases, especially sigma and eta phases at high temperature. A thermal exposure test was carried out to determine the microstructure stability of LESS 1 in comparison with IN740 at $800^{\circ}C$ for 300 hrs. The experimental results show that a needle-shaped eta phase was formed in the grin boundary and it grew to intragrain, and a precipitation free zone was also observed in IN740, but these defects were entirely controlled in LESS 1.

Development of High Entropy Alloy Film using Magnetron Sputtering

  • Kim, Young Seok;Lim, Ki Seong;Kim, Ki Buem
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.129-129
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    • 2018
  • Hard coating application is effective way of cutting tool for hard-to-machine materials such as Inconel, Ti and composite materials focused on high-tech industries which are widely employed in aerospace, automobile and the medical device industry also Information Technology. In cutting tool for hard-to-machine materials, high hardness is one of necessary condition along with high temperature stability and wear resistance. In recent years, high-entropy alloys (HEAs) which consist of five or more principal elements having an equi-atomic percentage were reported by Yeh. The main features of novel HEAs reveal thermodynamically stable, high strength, corrosion resistance and wear resistance by four characteristic features called high entropy, sluggish diffusion, several-lattice distortion and cocktail effect. It can be possible to significantly extend the field of application such as cutting tool for difficult-to-machine materials in extreme conditions. Base on this understanding, surface coatings using HEAs more recently have been developed with considerable interest due to their useful properties such as high hardness and phase transformation stability of high temperature. In present study, the nanocomposite coating layers with high hardness on WC substrate are investigated using high entropy alloy target made a powder metallurgy. Among the many surface coating methods, reactive magnetron sputtering is considered to be a proper process because of homogeneity of microstructure, improvement of productivity and simplicity of independent control for several critical deposition parameters. The N2 is applied to reactive gas to make nitride system with transition metals which is much harder than only alloy systems. The acceleration voltage from 100W to 300W is controlled by direct current power with various deposition times. The coating layers are systemically investigated by structural identification (XRD), evaluation of microstructure (FE-SEM, TEM) and mechanical properties (Nano-indenter).

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The Effect of In-Outlet Differential Pressure on a Valve Body Stress and Deformation by the Blow-by Gas Flow Characteristic in the PCV valve for Automobile (자동차용 PCV밸브내 유통특성에 의한 밸브응력 및 변형에 미치는 입출구 차압의 영향)

  • Kwon Oh-Heon;Lee Yeon-Won;Song Sang-Min;Lee Jong-Hoon;Kang Ji-Woong
    • Journal of the Korean Society of Safety
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    • v.20 no.1 s.69
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    • pp.36-41
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    • 2005
  • PCV(Positive Crankcase Ventilation) valve acts as a flow control valve to get a re-combustion of blow-by gas by having it flow from a crankcase to an inlet manifold suction tube. The blow-by gas of the crankcase should be eliminated or taken properly because it cause corrosion to critical parts, and contributes to increase crankcase pressure that can cause a drop in efficiency. The excessive stress and strain on the PCV valve that remove these harmful gas would be bring the difficult on the flow rate control and failure of the valve. Those condition inevitably induce the accident. Therefore, this study purpose is FEM evaluation of the stresses and deformation in the X3 PCV model according to the change of the differential pressure between inlet and outlet. From results, the maximum equivalent stresses increased linearly according to the increase of the differential pressure at the about 50mm from the inlet position and were under the yield strength of the valve. And the deformations were relatively small regardless of the in-outlet differential pressure variation.

Prediction of the Flow Coefficient of a PFA Lined Ball Valve Using the CFD Simulation Method (CFD 해석방법을 이용한 PFA 라이닝 볼밸브의 유량계수 예측)

  • Jeon, Hong-Pil;Lee, Won-Seob;Kim, Chul-Soo;Lee, Jong-Chul
    • The KSFM Journal of Fluid Machinery
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    • v.19 no.4
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    • pp.35-38
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    • 2016
  • A PFA lined ball valve, which is machined with fluorinated resin PFA to its inner part for improving corrosion resistance, non-stickness, heat-resistance, has been widely used in semiconductor/LCD manufacturing processes with the high purity chemicals as working fluid. Due to the safety concerns, the experiments for measuring the flow coefficient of a PFA lined ball valve should be conducted with water at room temperature according to IEC standards. However, it is required to know the real flow coefficient with the real working fluid, because the flow coefficient is critical to correctly design valves in piping system. In this study, we calculated the flow coefficient of a PFA lined ball valve 40A with hydrochloric acid ($40^{\circ}C$ 36% HCl) as the working fluid using a commercial CFD package, ANSYS CFX v15. The computational results had a good agreement with the measured data and showed a little difference between water and hydrochloric acid as the working fluid of a PFA lined ball valve.