• Title/Summary/Keyword: critical corrosion

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Effect of Retained Pre-construction Primer on the Corrosion Protection Properties of Epoxy Coatings

  • Lee, Chul-Hwan;Shin, Chil-Seok;Lee, Ho-Il;Chung, Mong-Kyu;Baek, Kwang-Ki
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.219-226
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    • 2007
  • Pre-construction primer (PCP), or shopprimer, have been applied to steel plates to control temporary corrosion during ship fabrication. For surface preparation at ship block stage, in common shipyard practices, welding beads, burnt and rusted areas shall be blasted or power tool cleaned and the contamination such as zinc salt shall be removed with blasting or power tool. Whereas, the sound film of PCP needs not to be removed or roughened as the paint having good compatibility with PCP is used for the first coat. In many cases, however, full blasting or sweep blasting on the sound PCP treated block assemblies was requested. There still has been argument about the legitimacy of this practice, thus, it is critical to evaluate the quality of the coating system applied on the sound PCP retained condition, comparing with the one applied on the full blasted or sweep blasted condition. In this study, two different epoxy systems for water ballast tank were applied on the surfaces with sound PCP condition, full blasted condition, and sweep blasted condition. Coating performances such as durability, anti-corrosion, cathodic disbondment resistance were evaluated. The test results clearly indicated that the sound film of PCP needed not to be removed or roughened as the paint having good compatibility with PCP based on inorganic zinc silicate.

An Evaluation of Slip Coefficient in High Strength Bolt Joint using Zn/Al Metal Spray Corrosion Resistance Method (Zn/Al 금속용사 방식공법을 적용한 고력볼트 접합부의 미끄럼계수 평가)

  • Kim, Tae-Soo;Lee, Han-Seung;Tae, Sung-Ho;Ahn, Hyun-Jin;Oh, Sang-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.5
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    • pp.114-122
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    • 2007
  • In high strength bolted joints, the corrosion of base material causes the reduction of slip resistance of the joints. In this study, tensile tests on slip-critical joints utilizing Zn/Al metal spraying corrosion resistance method were carried out in order to prevent the corrosion and meet the required mechanical characteristics of joints. In addition, slip coefficient and surface roughness were calculated. The key parameters were surface finishing condition and thickness of coating with the identical geometry in all specimens. From the results, it is found that the slip coefficient of the joints with coated finish after sand blast treatment as well as those of non-coated joints with only sand blast treatment were similar or superior to 0.45, which is a specification criteria of slip coefficient in friction-typed joints.

Automated detection of corrosion in used nuclear fuel dry storage canisters using residual neural networks

  • Papamarkou, Theodore;Guy, Hayley;Kroencke, Bryce;Miller, Jordan;Robinette, Preston;Schultz, Daniel;Hinkle, Jacob;Pullum, Laura;Schuman, Catherine;Renshaw, Jeremy;Chatzidakis, Stylianos
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.657-665
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    • 2021
  • Nondestructive evaluation methods play an important role in ensuring component integrity and safety in many industries. Operator fatigue can play a critical role in the reliability of such methods. This is important for inspecting high value assets or assets with a high consequence of failure, such as aerospace and nuclear components. Recent advances in convolution neural networks can support and automate these inspection efforts. This paper proposes using residual neural networks (ResNets) for real-time detection of corrosion, including iron oxide discoloration, pitting and stress corrosion cracking, in dry storage stainless steel canisters housing used nuclear fuel. The proposed approach crops nuclear canister images into smaller tiles, trains a ResNet on these tiles, and classifies images as corroded or intact using the per-image count of tiles predicted as corroded by the ResNet. The results demonstrate that such a deep learning approach allows to detect the locus of corrosion via smaller tiles, and at the same time to infer with high accuracy whether an image comes from a corroded canister. Thereby, the proposed approach holds promise to automate and speed up nuclear fuel canister inspections, to minimize inspection costs, and to partially replace human-conducted onsite inspections, thus reducing radiation doses to personnel.

Quantification of Half Cell Potential with Mix Properties in RC Member under Long-Term Chloride Exposure Conditions (장기 염해에 노출된 RC 부재의 배합 특성을 고려한 반 전위의 정량화)

  • Yoon, Yong-Sik;Jeong, Gi-Chan;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.307-313
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    • 2022
  • In this study, the correlation between Half Cell Potential(HCP) and the corrosion influencing factors was analyzed with considering three levels of water-cement ratio, the concentration of chloride solution, and cover depth. As a result of long-term corrosion monitoring, HCP behavior was close to the critical corrosion potential(-350 mV) in all water-cement ratios in the case of 3.5 % and 7.0 % chloride concentration. Regarding the passed charge test in 548 curing days, the passed charge results were improved to 'Moderate' grade. Multiple regression analysis was performed to evaluate the correlation between corrosion influencing factors and HCP, and it was evaluated that the effects of influencing factors to HCP were in the order of chloride concentration, water-cement ratio, and cover depth. In the case of the relationship between HCP and the passed charge, the coefficient of determination showed a high level of 0.9, which yielded a close correlation between the passed charge and HCP.

The Effect of Compressive Residual Stress on Computer Corrosion Fatigue Crack of SAE 5155 (SAE 5155강의 컴퓨터부식피로 균열에 미치는 압축잔류응력의 영향)

  • Park, Sung-Mo;Moon, Kwang-Seok;Park, Kyung-Dong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.6 no.2
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    • pp.34-40
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    • 2007
  • Antifatigue failure technology take an important part of current industries. Currently, the shot peening is used for removing the defect from the surface of steel and improving the fatigue strength on surface. Therefore, this paper the effect of compressive residual stress and corrosion of spring steel(SAE 5155)by shot-peening on fatigue crack growth characteristics in stress ratio(R=0.05)was investigated with considering fracture mechanics. By using the methods mentioned above, We arrived at the following conclusions. The fatigue crack growth rate(da/dN) of the shot-peening material was lower than that of the un-peening material. And in stage I, ${\Delta}Kth$, the threshold stress intensity factor, of the shot-peen processed material is high in critical parts unlike the un-peening material. Also m, fatigue crack growth exponent and number of cycle of the shot-peening material was higher than that of the un-peening material. That is concluded from effect of da/dN. Finally fracture of shot-peening material and un-peening material was identified and discussed in this study.

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Effects of Electrolyte Concentration on Electrochemical Properties of Zinc-Air Batteries (전해질 농도에 따른 아연-공기 전지의 전기화학적 특성)

  • Han, Ji Woo;Jo, Yong Nam
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.798-803
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    • 2019
  • The self-discharge behavior of zinc-air batteries is a critical issue induced by corrosion and hydrogen evolution reaction (HER) of zinc anode. The corrosion reaction and HER can be controlled by a gelling agent and concentration of potassium hydroxide (KOH) solution. Various concentrations of KOH solution and polyacrylic acid have been used for gel electrolyte. The electrolyte solution is prepared with different concentrations of KOH (6 M, 7 M, 8 M, 9 M). Among studied materials, the cell assembled with 6 M KOH gel electrolyte exhibits the highest specific discharge capacity and poor capacity retention. Whereas, 9 M KOH gel electrolyte shows high capacity retention. However, a large amount of hydrogen gas is evolved with 9 M KOH solution. In general, the increase in concentration is related to ionic conductivity. At concentrations above 7 M, the viscosity increases and the conductivity decreases. As a result, compared to other studied materials, 7 M KOH gel electrolyte is suitable for Zn-air batteries because of its higher capacity retention (92.00 %) and specific discharge capacity (351.80 mAh/g) after 6 hr storage.

Effect of Latex on Corrosion Resistance of Steel Rebar in Concrete (콘크리트 내에서 보강철근의 부식저항성에 미치는 라텍스의 효과)

  • Park, Sung-Ki;Won, Jong-Pil;Sung, Sang-Kyung;Park, Chan-Gi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.409-412
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    • 2008
  • This study were evaluated the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC). Accelerated testing was accomplished to the evalate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC are effected on the mix proportion factor including latex content, and water-cement ratio.

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Effect of Lateral Diffusion on Hydrogen Permeation Measurement in Thick Steel Specimens

  • Traidia, A.;El-Sherik, A.M.;Attar, H.;Enezi, A.
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.201-208
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    • 2017
  • A finite element analysis is proposed to study the effect of specimen dimensions on lateral diffusion of hydrogen during hydrogen permeation flux measurements. The error of measurement on thick specimens because of 1D diffusion approximation may be as much as 70%. A critical condition for accurate measurements is to designate the area of hydrogen monitoring/exit surface smaller than the area of hydrogen charging/entry surface. For thin to medium thickness specimens (ratio of thickness to specimen radius of 5:10 and below), the charging surface should be maximized and the monitoring surface should be minimized. In case of relatively thick specimens (ratio of thickness to specimen radius above of 5:10), use of a hydrogen-diffusion barrier on the specimen boundaries is recommended. It would completely eliminate lateral losses of hydrogen, but cannot eliminate the deviation towards 2D diffusion near the side edges. In such a case, the charging surface should be maximized and the monitoring surface should be as closer in dimension as the charging surface. A regression analysis was carried out and an analytical relationship between the maximum measurement error and the specimen dimensions is proposed.

Service life prediction of a reinforced concrete bridge exposed to chloride induced deterioration

  • Papadakis, Vagelis G.
    • Advances in concrete construction
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    • v.1 no.3
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    • pp.201-213
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    • 2013
  • While recognizing the problem of reinforcement corrosion and premature structural deterioration of reinforced concrete (RC) structures as a combined effect of mechanical and environmental actions (carbonation, ingress of chlorides), emphasis is given on the effect of the latter, as most severe and unpredictable action. In this study, a simulation tool, based on proven predictive models utilizing principles of chemical and material engineering, for the estimation of concrete service life is applied on an existing reinforced concrete bridge (${\O}$resund Link) located in a chloride environment. After a brief introduction to the structure of the models used, emphasis is given on the physicochemical processes in concrete leading to chloride induced corrosion of the embedded reinforcement. By taking under consideration the concrete, structural and environmental properties of the bridge investigated, an accurate prediction of its service life is taking place. It was observed that the proposed, and already used, relationship of service lifetime- cover is almost identical with a mean line between the lines derived from the minimum and maximum critical values considered for corrosion initiation. Thus, an excellent agreement with the project specifications is observed despite the different ways used to approach the problem. Furthermore, different scenarios of concrete cover failure, in the case when a coating is utilized, and extreme deicing salts attack are also investigated.

Electrochemical Properties of Austenitic Stainless Steel with Initial Delay Time and Surface Roughness in Electropolishing Solution (전해연마 용액에서 안정화 시간과 표면 거칠기에 따른 오스테나이트 스테인리스강의 전기화학적 특성)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.158-169
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    • 2022
  • The objective of this study was to investigate the electrochemical behavior and damage degree of metal surface under different conditions by performing a potentiodynamic polarization experiment using an electropolishing solution for UNS S31603 based on initial delay time and surface roughness (parameters). A second anodic peak occurred at initial delay time of 0s and 100s. However, it was not discovered at 1000s and 3600s. This research referred to an increase in current density due to hydrogen oxidation reaction among various hypotheses for the second anodic peak. After the experiment, both critical current density and corrosion current density decreased when the initial delay time (immersion time) was longer. As a result of surface analysis, characteristics of the potentiodynamic polarization behavior were similar with roughness, although the degree of damage was clearly different. With an increase in surface roughness value, the degree of surface damage was precisely observed. As such, electrochemical properties were different according to the immersion time in the electropolishing solution. To select electropolishing conditions such as applied current density, voltage, and immersion time, 1000s for initial delay time on the potentiodynamic polarization behavior was the most appropriate in this experiment.