• Title/Summary/Keyword: critical concentration

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The Effect of Sludge Settling Characteristics on Sludge-Water Interface Height Change Model (슬러지계면층 높이변화모델에서 슬러지 침전특성에 대한 영향)

  • Park, Suk Gyun;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.147-155
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    • 2006
  • For the further study of the solids flux theory, several researchers have proposed models to predict sludge settling velocity for each different concentration by using sludge indexes, SVI, SSVI and $SSVI_{3.5}$. It is difficult to apply the above models to predict sludge-water interface height in a batch column because sludge settling velocity changes while sludge settle down. While sludge settle down in a batch column, sludge concentration becomes high. The sludge concentration change is one of the most critical causes of the change of sludge settling velocity. Also, sludge concentration change causes of sludge index to change. SVI is more sensitive than SSVI or $SSVI_{3.5}$ to the change of sludge concentration. Each sludge has physical characteristics of its own which makes the settling velocity for each sludge different. The purpose of this study is to establish the correction factors that are able to compensate the errors derived from each different sludge settling characteristic by using sludge indexes, therefore the correction factors are applicable to the model for the change of sludge-water interface height.

The Influence of Glutaraldehyde Concentration on Electron Microscopic Multiple Immunostaining

  • Bae, Jae Seok;Yeo, Eun Jin;Bae, Yong Chul
    • International Journal of Oral Biology
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    • v.40 no.4
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    • pp.183-187
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    • 2015
  • The present study was aimed to evaluate the influence of glutaraldehyde (GA) concentration on multiple electron microscopic (EM) immunostaining using pre-embedding peroxidase and post-embedding immunogold method. Influence of various concentrations of GA included in the fixative on immuoreactivity was assessed in the multiple immunostaining using antisera against anti-transient receptor potential vanilloid 1 (TRPV1) for peroxidase staining and anti-GABA for immunogold labeling in the rat trigeminal caudal nucleus. Anti-TRPV1 antiserum had specificity in pre-embedding peroxidase staining when tissues were fixed with fixative containing paraformaldehyde (PFA) alone. Immunoreactivity for TRPV1 was specific in tissues fixed with fixative containing 0.5% GA at both perfusion and postfixation steps, though the immunoreactivity was weaker than in tissues fixed with fixative containing PFA alone. Tissues fixed with fixative containing 0.5% GA at the perfusion and postfixation steps showed specific immunogold staining for GABA. The results of the present study indicate that GA concentration is critical for immunoreactivity to antigens such as TRPV1 and GABA. This study also suggests that the appropriate GA concentration is 0.5% for multiple immunostaining with peroxidase labeling for TRPV1 and immunogold labeling for GABA.

Effect of Na Substitution for the Ca Site in the Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ Superconductors (Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ 산화물 고온초전도체의 Ca 위치에 Na 치환 효과)

  • 이민수;송승용;이종용;송기영;최봉수
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1007-1013
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    • 1998
  • The samples of Bi2Sr2Ca1-xNaxCu2O8+y with various carrier concentration were synthesized by substituting Na for Ca ion. The superconducting properties hall coefficients and X-ray powder diffraction were measur-ed the sampled. Single phase samples were obtained for 0$\leq$x<0.3 of Bi2Sr2Ca1-xNaxCu2O8+y In the single phase the critical temperature. {{{{ { T}_{c } }} and carrier concentration increase with the increase of Na concentration pass through a maximum and then decreases. In the range of x$\geq$0.7 to the Na doped samples however we observed the metal-semiconductor transition. The c-axis seemed to decrease and a and b-axes increase with increasing Na concentration in the single phase. Decreasing of c-axis while increasing x is due to the smaller size of {{{{ {Na}^{+1 } }} ions to the {{{{ { Ca}^{+2 } }} ions. In the range of x>0.3 however the trend becomes ambiguous due to the inclusion of the 10K phase and impurity phase.

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Theoretical Analysis of Critical Chloride Content in (Non)Carbonated Concrete Based on Characteristics of Hydration of Cement (시멘트 수화 특성 및 탄산화를 고려한 콘크리트의 임계 염소이온량에 대한 해석 기법)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.367-375
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    • 2007
  • Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.

Study of Methodology for Estimating PM10 Concentration of Asian Dust Using Visibility Data (시정자료를 이용한 황사의 미세먼지 농도추정 방법 연구)

  • Lee, Hyo-Jung;Lee, Eun-Hee;Lee, Sang-Sam;Kim, Seungbum
    • Atmosphere
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    • v.22 no.1
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    • pp.13-28
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    • 2012
  • The $PM_{10}$ concentration data is useful for indentifying intensity and a transport way of Asian dust. However, it is difficult to identify them properly due to the limited spatial resolution and coverage. Therefore, a methodology to estimate $PM_{10}$ concentration using visibility data obtained from synoptic observation was developed. To derive the converting function, correlation between visibility and $PM_{10}$ concentration is investigated using visibility and $PM_{10}$ concentration data observed at 20 stations in Korea from 2005 to 2009. To minimize bias due to atmospheric moisture, data with higher relative humidity over a critical value were eliminated while deriving $PM_{10}$-visibility relationship. As a result, an exponentially decreasing function of visibility is obtained under the condition that relative humidity is less than 82%. Verification of the visibility converting function to $PM_{10}$ concentration was carried out for the dust cases in 2010. It was found that spatial distributions of $PM_{10}$ calculated by visibility are in good agreement with the observed $PM_{10}$ distribution, especially for the strong dust cases in 2010. And correlation between the derived and observed $PM_{10}$ concentration was 0.63. We applied the function to obtain distributions of $PM_{10}$ concentration over North Korea, in which concentration data are not available, and compared them with satellite derived dust index, IODI distributions for dust cases in 2010. It is shown that the visibility function estimates quite similar patterns of dust concentration with IODI image, which suggests that it can contribute for prediction by indentifying transport route of Asian dust.

The Effects of $Mg^{2+}$ on the Micelle Formation of Nonionic Surfactants (비이온성 계면활성제의 미셀 형성에 미치는 $Mg^{2+}$의 영향)

  • Kwon, Oh-Yun;Kim, Jung-Sung;Paek, U-Hyon
    • Journal of the Korean Chemical Society
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    • v.37 no.9
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    • pp.781-786
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    • 1993
  • In the presence of $Mg^{2+}$, the interaction of nonionic surfactants, $nonylphenol-(ethylene oxide)_n$[NP-nEO; n = 12, 40, 100] with iodine in aqueous solution were investigated by UV-visible spectrophotometer. CMC (critical micelle concentration) was decreased with increasing $Mg^{2+}$ concentration, and those effects depend upon EO (ethylene oxide) numbers. Above CMC, the intensity of interaction peaks by the addition of $Mg^{2+}$ increased and then decreased. The increase in the intensity of the interaction peaks were attributed to the compactness of micelle in the presence of $Mg^{2+}$. These phenomena may be explained by the fact that the linear ethylene oxide chains, to be free configuration in aqueous solution, could form a psuedo-crown ether structures capable of forming complex with $Mg^{2+}$.

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Effects of Ethephon Treatments on Accelerating of Maturity of Sweet Persimmon 'Nishimurawase' Cultivar (서촌조생 단감의 숙기촉진에 관한 에세폰 효과)

  • Kim, In-Ha;Seo, Kwang-Ki;Ahn, Kwang-Hwan;Yoon, Young-Whang;Kim, Sung-Chul;Shon, Gil-Man;Ro, Chi-Woong
    • Korean Journal of Environmental Agriculture
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    • v.18 no.4
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    • pp.339-343
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    • 1999
  • This study was carried out to investigate the effects of treatments and adequate concentration of ethephon on coloring promotion of peel of sweet persimmon 'Nishimurawase' cultivar. High concentration(30 and 40㎎/l) of ethephon treatments increased the coloring of peel. but they were unfavorable to marketability due to the decrease of firmness, the increase of softening ratio, and the short of marketing critical period of fruits. Low concentration(20㎎/l) of ethephon treatment maintained higher marketability in terms of coloring of peel, firmness, softening ratio, and marketing critical period of fruit.

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The Effect of Salt and Organic Solvents on the Interaction of Thionin-Sodium Dodecyl Sulfate System (Thionin-Sodium Dodecyl Sulfate계의 상호작용에 있어서 염 및 유기용매의 첨가효과에 관한 연구)

  • Kim, Sung-Hyun;Song, Ki-Dong
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.779-785
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    • 1994
  • The interaction between the cationic dye, thionin(Th) and the anionic surfactant, sodium dodecyl sulfate (SDS) has been investigated by absorption spectra. As the temperature of surfactant solution was increased in premicellar range(S/D=10, 80, and 160) which was much lower than the critical micelle concentration(CMC), the increment or decrement of the molar extinction coeffecient ratio appeared. It was found that the most stable temperature range of the oligomer aggregate in Th-SDS system at S/D=160 was below $60^{\circ}C$. With increasing the concentration of inorganic salt and organic solvents in Th-SDS system, ${\alpha}$-band was increased, but ${\gamma}$=band or J-band was decreased. The orders of ${\alpha}$-band increasing power were $Cl^-$>$ClO{_4}{^-}$>$SO{_4}{^{2-}}$>$NO{_3}{^-}$ and 2-propanol>ethanol>methanol>ethylene glycol.

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Synthesis of CaS:Eu2+ Phosphor by using a Sealing Vessel and its Photoluminescence Properties

  • Yoo, Hyoung-Sun;Park, Bong-Je;Kang, Jong-Hyuk;Im, Won-Bin;Jeon, Duk-Young
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.255-259
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    • 2007
  • We have synthesized $CaS:Eu^{2+}$ phosphor by using a sealing vessel and evaluated its photoluminescence properties. The method using a sealing vessel is simple and economical in comparison with other methods reported up to date. As an activator concentration was increased from 0.1 mol% to 4 mol%, the main emission wavelength of the phosphor was increased from 642 nm to 651 nm due to the crystal field splitting of 5d levels of $Eu^{2+}$ ion. Although the same amount of $Eu_2O_3$ was used, the concentration of the activator ions, which were reduced from $Eu^{3+}\;to\;Eu^{2+}$ and substituted $Ca^{2+}$ ions, was increased with increase of firing temperature. Therefore, the main emission wavelength was also. shifted from 645 nm to 651 nm with increase of firing temperature from $1100^{\circ}C\;to\;1300^{\circ}C$. The critical distance($R_{c1}=20.65\;{\AA}$) between $Eu^{2+}$ ions calculated from the critical concentration was well matched with that($R_{c2}=19.17\;{\AA}$) calculated from the Dexter formula.

The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향)

  • Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.33-39
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    • 2001
  • This paper was studied on corrosion behavior of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the various concentration of lithium bromide solution, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze is carried out. And the corrosion behavior of materials forming absorption refrigeration systems is investigated. The main results are as following: 1) As concentration of lithium bromide solution increases, polarization resistance of materials of each kinds is low. And open circuit potential becomes less noble, the corrosion current density is high drained 2) Open circuit potential of SS 400 is less noble than that of Cu and Al-Ni bronze, corrosion current density of SS5 400 is high drained than that of Cu and Al-Ni bronze. 3) Anodic polarization of Cu and Al-Ni bronze in $62\%$ LiBr solution continues the active state. that of Cu and Al-Ni bronze in the natural sea water maintains the active state and the critical current for passivation appears.

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