• Title/Summary/Keyword: critical concentration

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Effect of Temperature on the Critical Micelle Concentration of Decylpyridinium Chloride (Decylpyridinium Chloride 용액의 Critical Micelle Concentration에 미치는 온도의 영향)

  • Han Man-Woon;Lee Chong-Man
    • Journal of the Korean Chemical Society
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    • v.16 no.4
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    • pp.201-204
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    • 1972
  • The critical micelle concentrations of decylpyridinium chloride in aqueous solutions have been determined by the electrical conductance measurements in the range of $10^{\circ}C$-$50^{\circ}C$. The temperature variation of the critical micelle concentrations has shown the minimum at the vicinity of $15^{\circ}C$. The Clausius-Clapeyron type equation of log (c.m.c.) versus temperature has been established. The values ${\Delta}Hm$ and the other thermodynamic properties associated with micelle formation have been determined using the above equation and compared with that of dodecylpyridinium chloride and dodecylpyridinium bromide.

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Combinatorial continuous non-stationary critical excitation in M.D.O.F structures using multi-peak envelope functions

  • Ghasemi, S. Hooman;Ashtari, P.
    • Earthquakes and Structures
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    • v.7 no.6
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    • pp.895-908
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    • 2014
  • The main objective of critical excitation methods is to reveal the worst possible response of structures. This goal is accomplished by considering the uncertainties of ground motion, which is subjected to the appropriate constraints, such as earthquake power and intensity limit. The concentration of this current study is on the theoretical optimization aspect, as is the case with the majority of conventional critical excitation methods. However, these previous studies on critical excitation lead to a discontinuous power spectral density (PSD). This paper introduces some critical excitations which contain proper continuity in frequency domain. The main idea for generating such continuous excitations stems from the combination of two continuous functions. On the other hand, in order to provide a non-stationary model, this paper attempts to present an appropriate envelope function, which unlike the previous envelope functions, can properly cover the natural earthquakes' accelerograms based on multi-peak conditions. Finally, the proposed method is developed into the multiple-degree-of-freedom (M.D.O.F) structures.

Evaluation of Residential Radiation Doses from Korean Atomic Power Plants - Effect of Socioenvironmental Inputs (국내 원전주변 주민 방사선 피폭선량 평가 - 입력변수의 영향)

  • 조대철;이갑복
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.223-229
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    • 2003
  • Annual radiation dose of residential individuals near 4 nuclear power plants in Korea was calculated via K-DOSE 60 based on the updated ICRP-60. The critical exposure variables were chosen as radionuclides, exposed organs and intake pathways. From the calculation results, the critical nuclides were found to be $^3$H, $^{133}$ Xe, $^{60}$ Co for Kori plants and $^{14}$ C, $^{41}$ Ar for Wolsung plants. The most critical pathway was 'vegetable intake' for adults and 'milk intake' for infants. However, there was no preference in the effective organs. Sensitivity analyses showed that the chemical composition in a nuclide much more influenced upon the radiation dose than any other input parameters such as food intake, radiation discharge, and transfer/concentration coefficients by more than 10$^2$ factor. The effect of transfer/concentration coefficients on the radiation dose was negligible. All input parameters showed highly estimated correlation with the radiation dose, approxinated to 1.0.

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Effects of the Low Temperature and Low Salt Solution on the Quality Characteristics of Salted Chinese Cabbage (저온-저염 절임기술이 절임배추의 품질 특성에 미치는 영향)

  • Lee, Seog-Won;Cho, Sun-Rae;Han, Sung-Hee;Rhee, Chul
    • The Korean Journal of Food And Nutrition
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    • v.22 no.3
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    • pp.377-386
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    • 2009
  • The principal objective of this study was to evaluate the influence of temperature and salt concentration on the physicochemical properties of salted Chinese cabbage. Salted Chinese cabbage samples were prepared with various concentrations of salt(4, 5, 6 and 7%), and were stored for 10 days at three temperatures(8, 14, and $25^{\circ}C$). The salting ratio of Chinese cabbage evidenced a decreasing trend regardless of the salting temperature and salt concentration, and their decrement appeared relatively high as the salting temperature increased. The period required to achieve a critical salting ratio(85%) decreased with increases in the salt concentration at $25^{\circ}C$, and a similar trend was observed at lower temperatures(8 and $14^{\circ}C$). The salinity of all samples evidenced an increasing trend during the salting period, and at $25^{\circ}C$, in particular, a continuous increment was observed. At salt concentrations of 4%, the critical salinity(2.2%) was not achieved regardless of the temperature and salting period. The pH of salted Chinese cabbage achieved critical pH in 3 days at a salting temperature of $25^{\circ}C$, but the critical pH 5.5 of samples at 8 and $14^{\circ}C$ appeared after a long period of approximately 4 to 10 days. The average hardness values of salted Chinese cabbage at a salting ratio of 85% were approximately 1.49 MPa, 1.87 MPa, and 1.97 MPa, respectively, at three temperatures($25^{\circ}C$, $14^{\circ}C$, and $8^{\circ}C$). The initial reducing sugar content of cabbage juice was 11.8 mg/$m{\ell}$, and this value decreased substantially to 3 to 5 mg/$m{\ell}$ on day 1.

The Aggregation State and Hemolytic Activity of Nystatin (니스타틴의 응집 특성 및 용혈 활성)

  • Yu, Bong-G.
    • Journal of Pharmaceutical Investigation
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    • v.31 no.1
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    • pp.1-5
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    • 2001
  • The aggregation behavior of nystatin (NYS) in the presence of pluronic F127, triblock copolymer of poly (ethylene oxide) (PEO) and poly (propylene oxide) (PPO), was measured and correlated with hemolytic activity. Antifungal activity was also studied using Saccharomyces cerevisiae as a model strain. The critical aggregation concentrations (CAC) of the drug were 50.1, 108.0, 134.2, 154.3, and $217.9\;{\mu}M$ at 0.1%, 0.5%, 1.0%, 1.5%, and 2.0% pluronic F127 solution, respectively. The levels of NYS required to start lysis of erythrocytes were about 80, 100, 125, 150, and $200\;{\mu}M$ at 0.1%, 0.5%, 1.0%, 1.5%, and 2.0% pluronic F127 solution, respectively. It was $50\;{\mu}M$ in the absence of the polymer. Minimal inhibitory concentration (MIC) and minimal fungicidal concentration (MFC) of NYS-pluronic F127 lyophilizate were same at $3\;{\mu}g/ml$, while MIC and MFC of pure NYS are $3\;{\mu}g/ml$ and $12\;{\mu}g/ml$, respectively. By modulating the aggregation behavior of NYS, pluronic F127 was able to reduce the toxicity of the drug without compromising the MIC and MFC.

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Iodine Stress Corrosion Cracking of Zircaloy-4 Tubes

  • Moon, Kyung-Jin;Lee, Byung-Ho
    • Nuclear Engineering and Technology
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    • v.10 no.2
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    • pp.65-72
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    • 1978
  • In this paper, it is attempted to investigate the phenomena of iodine stress corrosion cracking of Zircaloy-4 cladding failures in reactor through the results of similar out-of-pile test in iodine vapour. The main result of this experiment is a finding of the relation between the threshold stress which can lead to iodine stress corrosion cracking of Zircaloy-4 tube and the iodine concentration. The values of critical stress and the critical iodine concentration are also obtained. A model which relates failure time of Zircaley-4 tube to failure stress and iodine concentration is suggested as follows: log t$_{F}$ =5.5-(3/2)log$_{c}$-4log $\sigma$ where t$_{F}$ : failure time, minutes c: iodne concentration, mg/㎤ $\sigma$: stress, 10$^4$psi.

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Study on Misfit Dislocations and Critical Thickness in a $Si_xGe_{1-x}$ Epitaxial Film on a Si Substrate (Si 모재 위의 $Si_xGe_{1-x}$ 박막에서 부정합 전위와 임계두께에 관한 연구)

  • Shin, J.H.;Kim, J.H.;Earmme, Y.Y.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.298-303
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    • 2001
  • The critical thickness of an epitaxial film on a substrate in electronic or optoelectronic devices is studied on the basis of equilibrium dislocation analysis. Two geometric models, a single dislocation and an array of dislocations in heteroepitaxial system, are considered respectively to calculate the misfit dislocation formation energy. The isotropic linearly elastic stress fields for the models are obtained by means of complex potential method combined with alternating technique, and are used for calculating the formation energies. As a result, the effect of elastic mismatch between film and substrate on critical thickness is presented and $Si_xGe_{1-x}/Si$ epitaxial structure is analyzed to predict the critical thickness with varying germanium concentration.

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A Study of the Structure and Luminescence Properly of BaMgAl10O17:Eu2+ Blue Phosphor using Scattering Method (Scattering법을 이용한 BaMgAl10O17:Eu2+ 청색형광체의 구조와 발광특성 연구)

  • 김광복;김용일;구경완;천희곤;조동율
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.1
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    • pp.67-74
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    • 2002
  • A phosphor for Plasma Display Panel, BaMgAl$_{10}$ O$_{17}$ :Eu$^{2+}$, showing a blue emission band at about 450nm was prepared by a solid-state reaction using BaCO$_3$, $Al_2$O$_3$, MgO, Eu$_2$O$_3$ as starting materials wish flux AlF$_3$. The study of the behaviour of Eu in BAM phosphor was carried out by the photoluminescence spectra and the Rietveld method with X-ray and neutron powder diffraction data to refine the structural parameters such as lattice constants, the valence state of Eu, the preferential site of Mg atom and the site fraction of each atom. The phenomenon of the concentration quenching was abound 2.25~2.3wt% of Eu due to a decrease in the critical distance for energy transfer of inter-atomic Eu. Through the combined Rietveld refinement, R-factor, R$_{wp}$, was 8.11%, and the occupancy of Eu and Mg was 0.0882 and 0.526 at critical concentration. The critical distance of Eu$^{2+}$ in BAM was 18.8$\AA$ at 2.25% Eu of the concentration quenching. Furthermore, c/a ratio was decreased to 3.0wt% and no more change was observed over that concentration. The maximum entropy electron density was found that the modeling of $\beta$-alumina structure in BaMgAl$_{10}$ O$_{17}$ :Eu$^{2+}$correct coincided showing Ba, Eu, O atoms of z= 1/4 mirror plane.e.ane.e.