• 제목/요약/키워드: coupling 2-form

검색결과 144건 처리시간 0.023초

Post annealing에 따른 PMW-PNN-PZT 세라믹스의 압전 특성 (Piezoelectric Characteristics of PMW-PNN-PZT Ceramics according to Post-Annealing Process)

  • 유경진;류주현;박창엽;이형규;강형원
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.212-213
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    • 2005
  • In this study, in order to develop low temperature sintering piezoelectric actuator, $Pb_{0.985}Bi_{0.01}(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.13}(Zr_{0.50},Ti_{0.50})_{0.84}$ (PMW-PNN-PZT) ceramic systems were fabricated using $CaCO_3-Li_2CO_3$, sintering aid through a post-annealing process. The sinterability of PMW-PNN-PZT ceranics was remarkably enhanced by liquid phase sintering of $CaCO_3$ and $Li_2CO_3$. But, it was confimed form the X-ray diffraction pattern that the secondary phase along grain boundaries, deteriorated the piezoelectric properties. The secondary phase along grain boundaries was significantly removed by annealing after sintering. The 0.2wt% $Li_2CO_3$-0.25wt% $CaCO_3$-added PMW-PNN-PZT ceramics post-annealed at 900$^{\circ}C$ for 90min exhibited the excellent electromechanical coupling factor($k_p$) of 63.3% and piezoelectric constant($d_{33}$) of 452pC/N, respectively, for multilayer piezoelectricactuatorapplication.

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Functional Abnormalities of HERG Mutations in Long QT Syndrome 2 (LQT2)

  • Hiraoka, Masayasu
    • The Korean Journal of Physiology and Pharmacology
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    • 제5권5호
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    • pp.367-371
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    • 2001
  • The chromosome 7-linked long QT syndrome (LQT2) is caused by mutations in the human ether-a- go-go-related gene (HERG) that encodes the rapidly activating delayed rectifier $K^+$ current, $I_{Kr},$ in cardiac myocytes. Different types of mutations have been identified in various locations of HERG channel. One of the mechanisms for the loss of normal channel function is due to membrane trafficking of channel protein. The decreased channel function in some deletion mutants appears to be due to loss of coupling with wild type HERG to form the functional channel as the tetramer. Most of missense mutants with few exceptions could interact with wild type HERG to form functional tetramer and caused dominant negative suppression with co-injection with wild type HERG showing variable effects on current amplitude, voltage dependence, and kinetics of activation and inactivation. Two missense mutants at pore regions of HERG found in Japanese LQT2 (A614V and V630L) showed accentuated inward rectification due to a negative shift in steady-state inactivation and fast inactivation. One mutation in S4 region (R534C) produced a negative shift in current activation, indicating the S4 serving as the voltage sensor and accelerated deactivation. The C-terminus mutation, S818L, could not express the current by mutant alone and did not show dominant negative suppression with co-injection of equal amount of wild type cRNA. Co-injection of excess amount of mutant with wild type produced dominant negative suppression with a shift in voltage dependent activation. Therefore, multiple mechanisms are involved in different mutations and functional abnormality in LQT2. Further characterization with the interactions between various mutants in HERG and the regulatory subunits of the channels (MiRP1 and minK) is to be clarified.

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Synthesis and Characterization of MPEG-b-PDPA Amphiphilic Block Copolymer via Atom Transfer Radical Polymerization and Its pH-Dependent Micellar Behavior

  • Dayananda, Kasala;Kim, Min-Sang;Kim, Bong-Sup;Lee, Doo-Sung
    • Macromolecular Research
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    • 제15권4호
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    • pp.385-391
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    • 2007
  • Block copolymer micelles are generally formed via the self-assembly of amphiphilic block copolymers in an aqueous medium. The hydrophilic and hydrophobic blocks form shell and core micelles, respectively. The block copolymers of methoxy poly(ethylene glycol) (MPEG)-b-poly(2-diisopropylamino)ethyl methacrylate (PDPA) were synthesized via atom transfer radical polymerization, with the macro initiator synthesized by the coupling of 2-bromoisobutyryl bromide with MPEG in the presence of a triethyl amine base catalyst. The atom transfer radical polymerization of 2-diisopropylamino)ethyl methacrylate was performed in conjunction with an N,N,N',N",N"-pentamethyl-diethylenetriamine/copper bromide catalyst system, in DMF, at $70^{\circ}C$. The pH induced micellization/demicellization was studied using fluorescence, with a pyrene probe. Furthermore, the pH dependent micellization was confirmed using the microviscosity method, with a dipyme fluorescence probe. The pH dependant micelle size distribution was studied using dynamic light scattering. The characterization of the synthesized polymers was established using gel permeation chromatography and from the $^1H-nuclear$ magnetic resonance spectroscopy.

Application of S-HGMS and chemical coupling technology in river water treatment

  • Zhao, Xin;Li, Su-qin;Han, Shuai-shuai;Zhang, Peng;Jin, Jian-jiang;Guo, Peng-hui
    • 한국초전도ㆍ저온공학회논문지
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    • 제22권2호
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    • pp.12-16
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    • 2020
  • Circulating cooling systems consume a lot of water, and most of the water from river, which contains a large amount of Ca2+, Mg2+, et al, and has the characteristics of high hardness and large turbidity. The water can form scale on the surface of the heat exchanger and the pipes, which would reduce the heat transfer efficiency and affect the heat exchanger's length of service. In this study, the Superconducting High Gradient Magnetic Separation (S-HGMS) technology was used in river water treatment and the effects of agent A, agent B, and S-HGMS on the removal of hardness and turbidity were discussed. The results showed that the hardness removal rate reached 71.3% and the turbidity was decreased to 0.5 NTU.

$NaMnCl_{3}$ 단결정에서 $^{23}Na$ 핵자기공명의 온도 의존성 (Temperature Dependence of $^{23}Na$ NMR in a $NaMnCl_{3}$ Single Crystal)

  • Ae Ran Lim;Ji Eun Kim;Tae Jong Han
    • 한국자기학회지
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    • 제5권3호
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    • pp.175-178
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    • 1995
  • Czochralski 방법에 의해 성장된 $NaMnCl_{3}$ 단결정에서 $^{23}Na$의 핵자기공명의 온도 의존성이 Bruker FT NMR 분광기를 이용하여 연구하였다. $NaMnCl_{3}$에서 $^{23}Na$의 핵 사중극 결합상수는 온도가 증가함에 따라 증가하였다. 140-380 K의 온도 범위에서 $e^{2}qQ/h$의 온도 의존성은 $e^{2}qQ/h=155+0.117(T-T_{r})\;kHz$의 직선방정식으로 나타낼 수 있었다.

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Metal Sequestering by a Poly(ethylenimine)-Sephadex G-25 Conjugate Containing 2,2'-Dihydroxyazobenzene

  • 관원종;유창은;장원석;노영석;서정훈
    • Bulletin of the Korean Chemical Society
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    • 제21권4호
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    • pp.393-400
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    • 2000
  • 2,2¢-Dihydroxyazobenzene (DHAB) was attached to poly(ethylenimine) (PEI) to obtain DHAB-PEI. Spectral titration revealed that uranyl, Fe(III), Cu(II), and Zn(II) ion form 1 : 1-type complexes with DHAB attached to PEI. Formation constants for the metal complexes formed by the DHAB moieties of DHAB-PEI were mea-sured by using various competing ligands. The results indicated thatthe concentrations of uranyl, Fe(III), and Cu(II) ions can be reduced to 10 -16 -10 -23 M at p 8 with DHAB-PEI when the concentration of the DHAB moiety is 1 residue M. By using cyanuric chloride as the coupling reagent, DHAB-PEI was immobilized on Sephadex G-25 resin to obtain DHAB-PEI-Seph. Binding of uranyl,Fe(III), Cu(II), and Zn(II) ion by DHAB-PEI-Seph was characterized by using competing ligands. A new method has been developed for characteriza-tion of metal sequestering ability of a chelating resin. Formation constants and metal-binding capacity of two sets of binding sites on the resin were estimated for each metal ion. DHAB-PI-Seph was applied to recovery of metals such as uranium,Fe, Cu, Zn, Pb, V, Mn, and W from seawater. The uranium recovery from seawaterby DHAB-PEI-Seph does not meet the criterion for economical feasibility partlydue to interference by Fe and Zn ions. The seawater used in the experiment was contaminated by Fe and Zn and, therefore, the efficiency of uranium extractionfrom seawater with DHAB-PEI-Seph could be improved if the experiment is carried out in a cleaner sea.

The Coexistence of OFDM-Based Systems Beyond 3G with Fixed Service Microwave Systems

  • Jo Han-Shin;Yoon Hyun-Goo;Lim Jae-Woo;Chung Woo-Ghee;Yook Jong-Gwan;Park Han-Kyu
    • Journal of Communications and Networks
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    • 제8권2호
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    • pp.187-193
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    • 2006
  • In this paper, we study the coexistence of orthogonal frequency division multiplexing (OFDM)-based systems beyond 3G (B3G) and point-to-point (P-P) fixed service (FS) microwave systems. The advanced general analytical model derived via a power spectral density (PSD) analysis proposed in this paper has two advantages in comparison with the conventional minimum coupling loss (MCL) method. First, the interfering signal power that appears in the band of a victim system can be easily assessed without a spectrum emission mask. Second, when transmit power is not allocated to some subcarriers overlapping the band of the victim system in order to mitigate B3G OFDM-based systems interference with other systems, the general analytical model can successfully assess the interference from the B3G systems into FS systems, whereas the MCL method incorporating the spectrum emission mask cannot be applied in the presence of the same interference condition. The proposed model can be derived in a closed form and is simply implemented with the help of simulation, and thus the solution can be obtained in significantly reduced time. Through application of the proposed model, coexistence results are analyzed in a co-channel and adjacent channel with respect to guard band and minimum separation distance.

Time Domain Response of Random Electromagnetic Signals for Electromagnetic Topology Analysis Technique

  • Han, Jung-hoon
    • 한국컴퓨터정보학회논문지
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    • 제27권2호
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    • pp.135-144
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    • 2022
  • 전자기 토폴로지 기법은 복합적인 전파 환경의 모델링을 효과적으로 수행하기 위하여, 구성되는 전파 환경 단위를 각각 해석하고 네트워크의 형태로 결합하여 재해석하는 방법이다. 일반적인 상용 통신 채널 모델에서는 전파 환경이 복합적이고 예측이 어렵기 때문에 정확도는 낮지만 평균적인 해를 활용하는 확률 모델을 활용한다. 하지만, 상대적으로 높은 정확도의 전자파 전파 특성을 요구하는 전자기 펄스 등 위협 전자파의 전파 및 결합 분석, 전자전, 5G 및 6G 이상의 로컬 통신 채널 모델 등에 사용되는 전파 모델 응용에서는 전자기 토폴로지 기법을 활용한 전파 모델링 기법 등이 활용된다. 본 논문은 주파수 영역에서 해석되는 전자기 토폴로지(EMT) 기법의 효과적인 수행 방안과 알고리즘, 그리고 프로그램 구현에 대하여 설명한다. 또한 주파수 영역의 EMT 해석 결과에 대하여 임의의 인가 신호원에 대한 시간 영역에서의 응답을 도출하는 방안에 대하여 논의한다.

CFD-DEM 연동을 통한 함정용 채프운의 시공간 분포 해석 (Numerical Simulation of Spatiotemporal Distribution of Chaff Clouds for Warship Defense using CFD-DEM Coupling)

  • 정욱진;김문홍;손동우
    • 한국전산구조공학회논문집
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    • 제36권2호
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    • pp.93-103
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    • 2023
  • 수많은 함정용 채프들은 폭발에 의해 확산되어 채프운을 형성하며, 채프운은 허위 레이더 반사 단면적을 생성하여 적의 레이더를 기만한다. 본 논문에서는 전산유체역학-이산요소법 단방향 연동 기법을 기반으로 공기 중에 분포하는 함정용 채프운의 시공간 분포를 해석하는 수치적 프레임워크를 구축하고 바람의 방향과 속도, 채프 카트리지의 초기 각도와 폭발 압력이 채프운 분포에 미치는 영향을 분석하였다. 채프운의 확산은 폭발에 의한 방사형 확산, 난류와 충돌에 의한 전 방향 확산, 낙하 속도 차이에 의한 중력 방향 확산과 같이 세 단계로 구분되는 것을 확인하였다. 바람은 채프운의 평균 위치를 이동시켰으며, 항력에 의한 확산 효과는 나타나지 않았다. 카트리지 초기 각도에 따라 폭발에 의한 방사형 확산 방향이 달라졌으며, 각도가 지면과 수직에 가까울수록 더 넓게 확산되었다. 폭발 압력이 증가할수록 채프운은 더 넓게 확산되었으나 중력 방향으로는 분포 차이가 작았다.

2,4-디메틸이미다졸환을 가지는 아조계 카디온염료의 포토크로미즘 (Photochromism of Cationic Azo Dyes Containing 2,4-Dimethylimidazole)

  • Cho, Myung Lae;Yoon, Nam Sik;Lim, Yong Jin
    • 한국염색가공학회지
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    • 제3권3호
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    • pp.1-5
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    • 1991
  • Cationic azo dyes were synthesized by coupling aniline and its derivatives with 2,4-dimethyl imidazole as a coupler, and their photochromic behavior was investigated. The dyes exhibited little photochromism on wool, but to a considerable degree on Dacron T92(anionic modified polyester), the photochromism being prominent for the dye with electron-releasing substituent on diazo component. Little photochromism on wool can be attributed to a decreased mobility of dye by the various interactions between the dye and wool molecules, which interferes the cis-trans isomeriation of dye. On Dacron T92 there can not be any obstacle for the cis-trans isomerization of dye, hence reversible color change may occur. The electron-releasing substituent on diazo component may be helpful for the photochromism of dye by increasing the n-electron density of phenyl ring, which can stabilize the cis-form of the dye by the interaction with the positive charge of imidazole ring.

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